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Polymer-Mineral Composite Solid Electrolytes

  • Bo Wang (a1)

Abstract

Polymer-mineral composite solid electrolytes have been prepared by hot pressing using lithium ion-exchanged bentonite (LIEB) and mineral derived LATSP (Li1.2Al0.1Ti1.9Si0.1P2.9O12) NASICON materials as solid electrolyte fillers in the polyethylene oxide (PEO) polymer containing LiTFSI salt. The mineral based solid electrolyte fillers not only increase ionic conductivity but also improve thermal stability. The highest ionic conductivities in the PEO-LIEB and PEO-LATSP composites were found to be 9.4×10-5 and 3.1×10-4 S·cm-1 at 40°C, respectively. The flexible, thermal stable and mechanical sturdy polymer-mineral composite solid electrolyte films can be used in the all-solid-state batteries.

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1.Zhang, Z., Shao, Y., Lotsch, B., Hu, Y-S, Li, H., Janek, J., Nazar, L. F., Nan, C-W, Maier, J., Armand, M., Chen, L., Energy Environ. Sci. 11, 1945 (2018).
2.Dunn, B., Kamath, H., Tarascon, J.-M., Science 334, 928 (2011).
3.Vetter, J., Novak, P., Wagner, M., Veit, C., Moller, K.-C., Besenhard, J., Winter, M., Wohlfahrt-Mehrens, M., Vogler, C., Hammouche, A., J. Power Sources 147, 269 (2005).
4.Ren, Y., Chen, K., Chen, R., Liu, T., Zhang, Y., and Nan, C.-W., J. Am. Ceram. Soc. 98, 3603 (2015).
5.Chandrashekar, S., Trease, N. M., Chang, H. J., Du, L.-S., Grey, C. P., Jerschow, A., Nat. Mater. 11, 311 (2012).
6.Xu, W., Wang, J., Ding, F., Chen, X., Nasybulin, E., Zhang, Y., Zhang, J.-G., Energy Environ. Sci. 7, 513 (2014).
7.Cao, C., Li, Z-B., Wang, X.-L., Zhao, X.-B., Han, W.-Q., Front. Energy Res. 2, 25 (2014).
8.Goodenough, J. B., J. Solid State Electrochem. 16, 2019 (2012).
9.Oudenhoven, J. F., Baggetto, L., Notten, P. H., Adv. Energy Mater. 1, 10 (2011).
10.Ohta, N., Takada, K., Sakaguchi, I., Zhang, L., Ma, R., Fukuda, K., Osada, M., Sasaki, T., Electrochem. Commun. 9, 1486 (2007).
11.Ohta, N., Takada, K., Zhang, L., Ma, R., Osada, M., Sasaki, T., Adv. Mater. 18, 2226 (2006).
12.Sakuda, A., Hayashi, A., Ohtomo, T., Hama, S., Tatsumisago, M., J. Power Sources 196, 6735 (2011).
13.Yue, L., Ma, J., Zhang, J., Zhao, J., Dong, S., Liu, Z., Cui, G., Chen, L., Energy Storage Mater. 5, 139 (2016).
14.Xu, K., Chem. Rev. 104, 4303 (2004).
15.Fergus, J. W., J. Power Sources 195, 4554 (2010).
16.Hallinan, D. T., Balsara, N. P., Annu. Rev. Mater. Res. 43, 503 (2013).
17.Zhang, J., Zhao, N., Zhang, M., Li, Y., Chu, P. K., Guo, X., Di, Z., Wang, X., Li, H., Nano Energy 28, 447 (2016).
18.Chen, L., Li, Y., Li, S-P., Fan, L-Z., Nan, C-W., Goodenough, J. B., Nano Energy 46, 176 (2018).
19.Nairn, K., Forsyth, M., Every, H., Greville, M., Macfarlane, D.R., Solid State Ionics 86–88, 589 (1996).
20.Huang, L.Z., Wen, Z.Y., Jin, J., Lou, Y., J. Inorg. Mater. 27, 249 (2012).
21.Bonizzoni, S., Ferrara, C., Berbenni, b V., Anselmi-Tamburini, U., Mustarellib, P., Tealdi, C., Phys. Chem. Chem. Phys. 21, 6142 (2019).
22.Clem, A. G., Doehler, R. W., Clays and Clay Minerals 10, 272 (1961).
23.Wang, B., MRS Advances 3, 1301 (2017).
24.Wang, B., Bates, J. B., Hart, F. X., Sales, B. C., Zuhr, R. A., Robertson, J. D., J. Electrochem. Soc. 143, 3203 (1996).
25.Jackson, R. S., Wine Science: Principles and Applications (Academic Press, 2008) pp 418-519.
26.Kulkarni, V. S., Shaw, C., Essential Chemistry for Formulators of Semisolid and Liquid Dosages (Academic Press, 2016) pp 43-69.
27.Niriella, D., Carnahan, R. P., J. Disp. Sci. and Technol. 27, 123 (2006).

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Polymer-Mineral Composite Solid Electrolytes

  • Bo Wang (a1)

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