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Evaluation of MoS2 Films Fabricated by Metal-Organic Chemical Vapor Deposition Using a Novel Mo Precursor i-Pr2DADMo(CO)3 Under Various Deposition Conditions

Published online by Cambridge University Press:  24 March 2020

K. Yamazaki ,
Y. Hibino ,
Y. Oyanagi ,
Y. Hashimoto ,
N. Sawamoto ,
H. Machida ,
M. Ishikawa ,
H. Sudo ,
H. Wakabayashi  and
A. Ogura
K. Yamazaki*
Affiliation:
Meiji University, Kanagawa 214-8571, Japan
Y. Hibino
Affiliation:
Meiji University, Kanagawa 214-8571, Japan Research Fellow of the Japan Society for the Promotion of Science, Tokyo 102-0083, Japan
Y. Oyanagi
Affiliation:
Meiji University, Kanagawa 214-8571, Japan
Y. Hashimoto
Affiliation:
Meiji University, Kanagawa 214-8571, Japan
N. Sawamoto
Affiliation:
Meiji University, Kanagawa 214-8571, Japan
H. Machida
Affiliation:
Gas-Phase Growth Ltd., Tokyo 184-0012, Japan
M. Ishikawa
Affiliation:
Gas-Phase Growth Ltd., Tokyo 184-0012, Japan
H. Sudo
Affiliation:
Gas-Phase Growth Ltd., Tokyo 184-0012, Japan
H. Wakabayashi
Affiliation:
Tokyo Institute of Technology, Kanagawa 226-8502, Japan
A. Ogura
Affiliation:
Meiji University, Kanagawa 214-8571, Japan
*
*(Email: ce191061@meiji.ac.jp)
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Abstract

Molybdenum disulfide (MoS2) is expected to be applied for devices in various fields owing to its unique characteristics. Establishing a high-productivity manufacturing method which yields high quality films is an important and unresolved issue for the practical applications of MoS2. Among different techniques conducted by researchers all over the world, our approach is cold-wall metal-organic chemical vapor deposition, and we previously reported the deposition of MoS2 with i-Pr2DADMo(CO)3, a novel Mo precursor [S. Ishihara, et al., MRS Advances 3, 379-384 (2018).]. In this study, with the aim of further improving the quality of the MoS2 film using this new Mo precursor, various film formation conditions were controlled and the influence on the film quality was investigated. X-ray photoelectron spectroscopy, atomic force microscopy and Raman spectroscopy were used as evaluation techniques of the samples. As a result, mm-scale uniform film was formed with the deposition time less than 30 min. at temperature as low as 400 °C to 500 °C. It was revealed that maintaining low Mo/S supply ratio (SRMo/S) is crucial in fabricating high quality films.

Keywords

2D materialschemical vapor deposition (CVD) (deposition)
Type
Articles
Information
MRS Advances , Volume 5 , Issue 31-32: Fabrication of Functional Materials and Nanomaterials , 2020 , pp. 1643 - 1652
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Copyright
Copyright © Materials Research Society 2020

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References

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