Skip to main content Accessibility help
×
Home

Energy Dispersive X-ray Diffraction (EDXRD) of Li1.1V3O8 Electrochemical Cell

  • Qing Zhang (a1), Andrea M. Bruck (a2), David C. Bock (a3), Jing Li (a1), Eric A. Stach (a4), Esther S. Takeuchi (a1) (a2) (a3), Kenneth J. Takeuchi (a1) (a2) and Amy C. Marschilok (a1) (a2)...

Abstract

In this study, we conducted the first energy dispersive x-ray diffraction (EDXRD) experiments on Li/Li1.1V3O8 coin cells discharged to different lithiation levels in order to investigate the phase transitions upon electrochemical reduction. The phase transformation from layered Li-poor α to Li-rich α to defect rock-salt β phase was confirmed with cells of different lithiation stages. No spatial localization of phase formation was observed throughout the cathodes under the conditions of this measurement.

    • Send article to Kindle

      To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

      Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

      Find out more about the Kindle Personal Document Service.

      Energy Dispersive X-ray Diffraction (EDXRD) of Li1.1V3O8 Electrochemical Cell
      Available formats
      ×

      Send article to Dropbox

      To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

      Energy Dispersive X-ray Diffraction (EDXRD) of Li1.1V3O8 Electrochemical Cell
      Available formats
      ×

      Send article to Google Drive

      To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

      Energy Dispersive X-ray Diffraction (EDXRD) of Li1.1V3O8 Electrochemical Cell
      Available formats
      ×

Copyright

Corresponding author

References

Hide All
1. Sarkar, S., Bhowmik, A., Dixit Bharadwaj, M. and Mitra, S., J. Electrochem. Soc 161, A14 (2014).
2. Shi, Q., Liu, J. W., Hu, R. Z., Zeng, M. Q., Dai, M. J. and Zhu, M., RSC Adv., 2, 7273 (2012).
3. de Picciotto, L. A., Adendorff, K. T., Liles, D. C. and Thackeray, M. M., Solid State Ion. 62, 297 (1993).
4. Pistoia, G., Panero, S., Tocci, M., Moshtev, R. V. and Manev, V., Solid State Ion. 13, 311 (1984).
5. Kirshenbaum, K., Bock, D. C., Lee, C.-Y., Zhong, Z., Takeuchi, K. J., Marschilok, A. C. and Takeuchi, E. S., Science, 347, 149 (2015).
6. Kirshenbaum, K. C., Bock, D. C., Brady, A. B., Marschilok, A. C., Takeuchi, K. J. and Takeuchi, E. S., Phys. Chem. Chem. Phys. 17, 11204 (2015).
7. Gallaway, J. W., Menard, M., Hertzberg, B., Zhong, Z., Croft, M., Sviridov, L. A., Turney, D. E., Banerjee, S., Steingart, D. A. and Erdonmez, C. K., J. Electrochem. Soc 162, A162 (2015).
8. Liang, G., Croft, M. and Zhong, Z., ECS Trans. 50, 293 (2013).
9. Paxton, W. A., Zhong, Z. and Tsakalakos, T., J. Power Sources 275, 429 (2015).
10. Strobridge, F. C., Orvananos, B., Croft, M., Yu, H.-C., Robert, R., Liu, H., Zhong, Z., Connolley, T., Drakopoulos, M., Thornton, K. and Grey, C. P., Chem. Mater. 27, 2374 (2015).
11. Marschilok, A. C., Schaffer, C. P., Takeuchi, K. J. and Takeuchi, E. S., J. Compos. Mater. 47, 41 (2013).
12. Jouanneau, S., Verbaere, A. and Guyomard, D., J. Solid State Chem. 178, 22 (2005).

Keywords

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed