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The Effect of Electrochemical Modification of the Glass Carbon Surface in Conditions of Chemisorption of Fluorine-Containing Nanogroups on its Electrophysical Properties

Published online by Cambridge University Press:  07 August 2017

Yulia M. Stryuchkova ,
Sergey M. Karabanov ,
Dmitriy V. Suvorov ,
Evgeniy V. Slivkin ,
Gennadiy P. Gololobov  and
Dmitry Yu. Tarabrin
Yulia M. Stryuchkova
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan 390005, Russia
Sergey M. Karabanov*
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan 390005, Russia
Dmitriy V. Suvorov
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan 390005, Russia
Evgeniy V. Slivkin
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan 390005, Russia
Gennadiy P. Gololobov
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan 390005, Russia
Dmitry Yu. Tarabrin
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan 390005, Russia
*
*(Email: pvs.solar@gmail.com)
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Abstract

The electrophysical (donor-acceptor) properties of the of glass carbon (GC) surface before and after its electrochemical modification in conditions of chemisorption of fluorine-containing nanogroups were studied using the methods of scanning probe microscopy. The values of the coefficients characterizing local (for atomic-scale) electrophysical properties of the surface are calculated on the basis of obtained local spectral dependences of the tunneling current on the tunnelling voltage. Fluorination of the GC surface resulted in change of the ratio of its donor-acceptor atomic characteristics, acceleration of electrode processes, and increase of the overall tunneling activity of local places.

Keywords

electrochemical synthesiselectrodepositionnanostructure
Type
Articles
Information
MRS Advances , Volume 2 , Issue 54: Energy Storage and Conversion , 2017 , pp. 3335 - 3339
Copyright
Copyright © Materials Research Society 2017 

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References

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