Skip to main content Accessibility help
×
Home
Hostname: page-component-78dcdb465f-vzs5b Total loading time: 0.334 Render date: 2021-04-16T18:22:33.948Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "metricsAbstractViews": false, "figures": false, "newCiteModal": false, "newCitedByModal": true }

Article contents

One-Step Fabrication of Fe-Si-O/Carbon Nanotube Composite Anode Material with Excellent High-Rate Long-Term Cycling Stability

Published online by Cambridge University Press:  26 January 2017

Yun-Kai Sun
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Xue Bai
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Tao Li
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Gui-Xia Lu
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Yong-Xin Qi
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Ning Lun
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Yun Tian
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Yu-Jun Bai
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Corresponding
Get access

Abstract

The composite Li-ion battery anode material of Fe2SiO4, Fe3O4, Fe3C (Fe-Si-O) and carbon nanotubes was prepared by a simple one-step reaction between ferrocene and tetraethyl orthosilicate. When cycled at 100 mA g-1, this material exhibited ever-increasing capacities and reached 588 mAh g-1 at the 280th cycle. At 500 mA g-1, a reversible capacity of 350 mAh g-1 was retained for 600 cycles. Compared with Fe3O4 materials, the Fe-Si-O/CNT exhibited superior long-term high-rate performance, which could mainly result from its enhanced stability and conductivities by introducing silicates and CNTs during the one-step synthesis.

Type
Articles
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below.

References

Armand, M. and Tarascon, J.-M., Nature, 451 (2008) 652657.CrossRef
Yang, L., Hu, J., Dong, A. and Yang, D., 2014.. Electrochimica Acta, 144, pp.235242.CrossRef
Gao, G., Zhang, Q., Cheng, X. B., Qiu, P., Sun, R., Yin, T. and Cui, D., ACS Appl. Mater. Interfaces, 7 (2014) 340350.CrossRef
He, Y., Huang, L., Cai, J. S., Zheng, X. M. and Sun, S.G., Electrochim. Acta, 55 (2010) 11401144.CrossRef
Keller, T.M., Laskoski, M. and Qadri, S.B., J. Phys. Chem. C, 111 (2007) 25142519.CrossRef
Kim, K.-E., Kim, K.-J., Jung, W.S., Bae, S.Y., Park, J., Choi, J. and Choo, J., Chem. Phys. Lett., 401 (2005) 459464.CrossRef
Zhang, Q., Ge, S., Xue, H., Wang, X., Sun, H. and Li, A., RSC Adv., 4 (2014) 5826058264.CrossRef
Chen, W., Lan, M., Zhu, D., Ji, C., Feng, X., Yang, C., Zhang, J. and Mi, L., J. Mater. Chem. A, 1 (2013) 1091210917.CrossRef
Cheng, W., Rechberger, F., Ilari, G., Ma, H., Lin, W. I. and Niederberger, M., Chem. Sci, 6 (2015) 69086915.CrossRef
Wang, Y.-Y., Li, T., Qi, Y.-X., Bai, R.-L., Yin, L.-W., Li, H., Lun, N. and Bai, Y.-J.. Electrochim. Acta, 186 (2015) 572578.CrossRef
Li, T., Wang, Y.-Y., Tang, R., Qi, Y.-X., Lun, N., Bai, Y.-J. and Fan, R.-H., ACS Appl. Mater. Interfaces, 5 (2013) 94709477.CrossRef
Latorre-Sanchez, M., Primo, A. and Garcia, H., J. Mater. Chem., 22 (2012) 2137321375.CrossRef
Adams, S. and Rao, R.P., Phys. Chem. Chem. Phys., 11 (2009) 32103216.CrossRef
Raistrick, I., Ho, C. and Huggins, R.A., J. Electrochem. Soc, 123 (1976) 14691476.CrossRef
Wang, W., Kumta, P.N., Acs Nano, 4 (2010) 22332241.CrossRef
Zhao, X., Xia, D., Yue, J. and Liu, S., Electrochim. Acta, 116 (2014) 292299.CrossRef
Sun, Y.-K., Bai, X., Li, T., Lu, G.-X., Qi, Y.-X., Lun., N., Tian, Y. and Bai, Y.-J., J. Alloys Compd., 686 (2016) 318325 CrossRef

Full text views

Full text views reflects PDF downloads, PDFs sent to Google Drive, Dropbox and Kindle and HTML full text views.

Total number of HTML views: 0
Total number of PDF views: 23 *
View data table for this chart

* Views captured on Cambridge Core between 26th January 2017 - 16th April 2021. This data will be updated every 24 hours.

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

One-Step Fabrication of Fe-Si-O/Carbon Nanotube Composite Anode Material with Excellent High-Rate Long-Term Cycling Stability
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

One-Step Fabrication of Fe-Si-O/Carbon Nanotube Composite Anode Material with Excellent High-Rate Long-Term Cycling Stability
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

One-Step Fabrication of Fe-Si-O/Carbon Nanotube Composite Anode Material with Excellent High-Rate Long-Term Cycling Stability
Available formats
×
×

Reply to: Submit a response


Your details


Conflicting interests

Do you have any conflicting interests? *