Hostname: page-component-78c5997874-ndw9j Total loading time: 0 Render date: 2024-11-18T21:54:44.069Z Has data issue: false hasContentIssue false
  • English
  • Français

Electrodeposition of Ni-Mo Defect-Free Alloy from Ammonium-Citrate Electrolyte in Pulse Current Mode

Published online by Cambridge University Press:  03 July 2017

Sergey M. Karabanov ,
Yulia M. Stryuchkova ,
Dmitriy V. Suvorov ,
Gennadiy P. Gololobov ,
Dmitry Yu. Tarabrin ,
Nikolay B. Rybin  and
Evgeniy V. Slivkin
Sergey M. Karabanov*
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan390005, Russia
Yulia M. Stryuchkova
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan390005, Russia
Dmitriy V. Suvorov
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan390005, Russia
Gennadiy P. Gololobov
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan390005, Russia
Dmitry Yu. Tarabrin
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan390005, Russia
Nikolay B. Rybin
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan390005, Russia
Evgeniy V. Slivkin
Affiliation:
Ryazan State Radio Engineering University, 59/1 Gagarina St., Ryazan390005, Russia
*
*(Email: pvs.solar@gmail.com)
Get access

Abstract

Electrodeposition in pulse current mode of nickel-molybdenum alloy on a nickel substrate was studied. The range of current density variation from 2 to 9 A/dm2 was investigated. The range of pulse and pause step lengths is from tens to hundreds of milliseconds. SEM-images of applied coatings surfaces are obtained. The method of energy dispersive spectroscopy determined that the molybdenum content in the coating is 21-24 wt%. It was found that under transient pulse mode of electrolysis, with the pulse step corresponding to hundreds of milliseconds, the most rigid and smooth coatings of the electrolytic nickel-molybdenum alloy are obtained from ammonium-citrate electrolyte. It is shown that the percentage of nickel in the alloy does not depend on the electrolysis mode.

Keywords

defectselectrodepositionalloy
Type
Articles
Information
MRS Advances , Volume 2 , Issue 58-59: Nanomaterials , 2017 , pp. 3585 - 3589
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Karabanov, S.M., Maisels, R.M. and Shoffa, V.N., Magnetically controlled reed switches and products on their basis, edited by Shoffa, V.N. (Intellect, Dolgoprudniy, 2011), p.407.Google Scholar
Lewandowski, M. and Sarbak, Z., Applied Catalysis A: General, 168 (1), 179–185 (1998).CrossRefGoogle Scholar
Pushpavanam, M., Electrochimica Acta, 53, 3313–3322 (2008)Google Scholar
Marlot, A., Kern, P. and Landolt, D., Electrochimica Acta, 48, 29–36 (2002).Google Scholar
Vasko, A.T., Electrochemistry of molybdenum and tungsten (Naukovadumka, Kiev, 1977), p. 120.Google Scholar