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Truscottite: composition and ionic substitutions

Published online by Cambridge University Press:  05 July 2018

E. E. Lachowski
Affiliation:
Department of Chemistry, University of Aberdeen, Scotland
L. W. Murray
Affiliation:
Department of Chemistry, University of Aberdeen, Scotland
H. F. W. Taylor
Affiliation:
Department of Chemistry, University of Aberdeen, Scotland

Summary

Eleven specimens of natural or synthetic truscottite or gyrolite-truscottite intergrowth were studied by analytical electron microscopy and X-ray powder diffraction. The results suggest that, in absence of substitution, the formula of truscottite is Ca14 (Si24O58)(OH)8 · ∼ 2H2O. Truscottite can accommodate Al and K in absence of each other to the extents of 1.4 atoms of Al or 0.5 atoms of K in the above formula. Substitution of Al causes a small increase in cell dimensions, which can approach those of reyerite, but substitution of K has negligible effect.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1979

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References

Bezjak, (A.), Jelenić, (I.), and Jernečič, (J.), 1974. Nature, 248, 581.CrossRefGoogle Scholar
Buckner, (D. A.), Roy, (D. M.), and Roy, (R.), 1960. Am. J. Sci. 258, 132.CrossRefGoogle Scholar
Cliff, (G.), Gard, (J. A.), Lorimer, (G. W.), and Taylor, (H. F. W.), 1975. Mineral. Mag. 40, 113.CrossRefGoogle Scholar
Funk, (H.), 1961. Z. anorg. allg. Chemie, 313, 1.CrossRefGoogle Scholar
Gard, (J. A.), Mitsuda, (T.), and Taylor, (H. F. W.), 1975. Mineral. Mag. 40, 325.CrossRefGoogle Scholar
Grutterink, (J. A.), 1925. Verh. Geol.-Mijnb. Genootschap Nederland, Geol. Ser. 8, 197 [M. 3, 271].Google Scholar
Harker, (R. I.), 1964. J. Am. Ceram. Soc. 47, 521.CrossRefGoogle Scholar
Hovig, (P.), 1914. Jaarb. Mijnwezen Ned. Oost-Indie (Batavia), 41(for 1912), 202 [Mineral. Mag. 20, 466].Google Scholar
Kalousek, (G. L.), 1978. Paper presented at Symposium on Relations between Properties of Lime-Sand Products and Formation of Cementing Material, Karlsruhe.Google Scholar
Mackay, (A. L.) and Taylor, (H. F. W.), 1954. Mineral. Mag. 30, 450.Google Scholar
Merlino, (S.), 1972. Nature, 238, 124.Google Scholar
Meyer, (J. W.) and Jaunarajs, (J. L.), 1961. Am. Mineral. 46, 9r3.Google Scholar
Minato, (H.) and Kato, (K.), 1967. Mineral. J. (Japan). 5, 144.CrossRefGoogle Scholar
Strunz, (H.) and Micheelsen, (H.), 1958. Naturwiss. 45, 515.CrossRefGoogle Scholar