Hostname: page-component-848d4c4894-wg55d Total loading time: 0 Render date: 2024-05-04T07:16:52.075Z Has data issue: false hasContentIssue false

A survey of accessory mineral assemblages in peralkaline and more aluminous A-type granites of the southeast coastal area of China

Published online by Cambridge University Press:  05 July 2018

L. Xie
Affiliation:
State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing 210093, P. R. China
R. C. Wang*
Affiliation:
State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing 210093, P. R. China
D. Z. Wang
Affiliation:
State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing 210093, P. R. China
J. S. Qiu
Affiliation:
State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing 210093, P. R. China
*

Abstract

An extensive belt of A-type granite exists along the southeast coast of China. The granites are divided into peralkaline and more aluminous subgroups which differ in mineral assemblages, mineral compositions and textures. In the peralkaline subgroup, primary magmatic Th-rich zircon is typically overgrown by Th-poor zircon containing thorite micro-inclusions. REE minerals in this subgroup are dominated by allanite-(Ce), chevkinite-(Ce), titanite and pyrochlore. Fe-Ti oxides are titanian magnetite and Mn-rich ilmenite. In contrast, in the more aluminous subgroup rocks, zircon is weakly zoned and exhibits very low Th but relatively high U contents. The REE minerals are dominated by Th-rich monazite-(Ce). Titanium-poor magnetite, pyrophanite and rutile are the major Fe-Ti oxides. These occurrences indicate that peralkaline magmas favour the formation of REE silicates, whereas magmas with higher alumina saturation stabilize REE phosphates. Peralkaline granites crystallized at temperatures 50–100°C greater than the more aluminous granites, but under lower oxidation conditions. These differences in formation conditions of the two A-type granite subgroups, deduced by accessory mineralcharacteristics, are inferred to be related to magma derivation at different crustal levels, with peralkaline magma deriving from a deeper crustal level with more mantle input.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bonin, B.L., Azzouni-Sekkal, A., Bussy, F. and Ferrag, S. (1998) Alkali-calcic and alkaline post-orogenic (PO) granite magmatism: petrologic constraints and geodynamic settings. Lithos, 45, 4570.CrossRefGoogle Scholar
Carmichael, I.S.E. (1967) The iron-titanium oxides of salic volcanic rocks and their associated ferromagnesian silicates. Contributions to Mineralogy and Petrology, 14, 3664.CrossRefGoogle Scholar
Casillas, R., Nagy, G., Pantó, G., Bräandle, J. and Fórizs, I. (1995) Occurrence of Th, U, Y, Zr, and REE-bearing accessory minerals in late-Variscan granitic rocks from the Sierra de Guadarrama (Spain). European Journal of Mineralogy, 7, 9891006.CrossRefGoogle Scholar
Cuney, M. and Friedrich, M. (1987) Physicochemical and crystal-chemical controls on accessory mineral paragenesis in granitoids: implications for uranium metallogenesis. Bulletin de Minéralogie, 110, 235247.CrossRefGoogle Scholar
Czamanske, G.K. and Wones, D.R. (1973) Oxidation during magmatic differentiation, Finnmarka Complex, Oslo area, Norway: Part 2, the mafic silicates. Journal of Petrology, 14, 349380.CrossRefGoogle Scholar
Dini, A., Rocchi, S. and Westerman, D.S. (2004) Reaction microtextures of REE-Y-Th-U accessory minerals in the Monte Capanne pluton (Elba Island, Italy): a possible indicator of hybridization processes. Lithos, 78, 101118.CrossRefGoogle Scholar
Farges, F. and Calas, G. (1991) Structural analyses of radiation damage in zircon and thorite: An X-ray absorption spectroscopic study. American Mineralogist, 76, 6073.Google Scholar
Förster, H.J. (1998 a) The chemical composition of REE-Y-Th-U-rich accessory minerals in peraluminous granites of the Erzgebirge-Fichtelgebirge region, Germany, Part I: The monazite-(Ce)-brabantite solid solution series. American Mineralogist, 83, 259272.CrossRefGoogle Scholar
Förster, H.J. (1998 b) The chemical composition of REE-Y-Th-U-rich accessory minerals in peraluminous granites of the Erzgebirge-Fichtelgebirge region, Germany. Part II: Xenotime. American Mineralogist, 83, 13021315.CrossRefGoogle Scholar
Förster, H.J. (2006) Composition and origin of intermediate solid solutions in the system thorite-xenotime-zircon-coffinite. Lithos, 88, 3555.CrossRefGoogle Scholar
Frindt, S., Haapala, I. and Pakkanen, L. (2004) Anorogenic Gross Spitzkoppe granite stock in central western Namibia: Part I. Petrology and geochemistry. American Mineralogist, 89, 841856.CrossRefGoogle Scholar
Frost, B.R. (1991) Introduction to oxygen fugacity and its petrologic importance. Pp. 110 in: Oxide Minerals: Petrologic and Magnetic Significance (Lindsley, D. H., editor). Reviews in Mineralogy, 25, Mineralogical Society of America, Washington, D.C. Google Scholar
Hoskin, P.W.O. (2005) Trace-element composition of hydrothermal zircon and the alteration of Hadean zircon from the Jack Hills, Australia. Geochimica et Cosmochimica Acta, 69, 637648.CrossRefGoogle Scholar
Hoskin, P.W.O. and Schaltegger, U. (2003) The composition of zircon and igneous and metamorphic petrogenesis. Pp. 2762 in: Zircon (Hanchar, J.M. and Hoskin, P.W.O., editors). Reviews in Mineralogy & Geochemistry, 53, Mineralogical Society of America and the Geochemical Society, Washington, D.C. CrossRefGoogle Scholar
Jiang, N. (2006) Hydrothermal alteration of chevkinite-(Ce) in the Shuiquangou syenitic intrusion, northern china. Chemical Geology, 227, 100112.CrossRefGoogle Scholar
Lepage, L.D. (2003) ILMAT: an Excel worksheet for ilmenite – magnetite geothermometry and geobarometry. Computers & Geosciences, 29, 673678.CrossRefGoogle Scholar
Lindsley, D.H. and Spencer, K.J. (1982) Fe-Ti oxide geothermometry: Reducing analyses of coexisting Ti-magnetite (Mt) and ilmenite (Ilm). Abstract AGU Spring Meeting Eos Transactions, American Geophysical Union, 63, 471.Google Scholar
Litvinovsky, B.A., Jahn, B.J., Zanbilevich, A.N., Saunders, A., Poulain, S., Kuzmin, D.B., Reichow, M.K. and Titov, A. V. (2002) Petrogenesis of syenite-granite suites from the Bryansky Complex (Transbaikalia, Russia): implications for the origin of A-type granitoid magmas. Chemical Geology, 189, 105133.CrossRefGoogle Scholar
Marks, M., Vennemann, T., Siebel, W. and Markl, G. (2003) Quantification of magmatic and hydrothermal processes in a peralkaline syenite-alkali granite complex unit of the Ilímaussaq Intrusion, South Greenland, as deduced from phase equilibria. Journal of Petrology, 44, 12471280.CrossRefGoogle Scholar
Martin, H., Bonin, B., Capdevila, R., Jahn, B.M., Lameyre, J. and Wang, Y. (1994) The Kuiqi peralkaline granitic complex (SE China): petrology and geochemistry. Journal of Petrology, 35, 9831015.CrossRefGoogle Scholar
Montel, J.M. (1985) Is monazite guilty? Experimental determination of Ce-monazite solubility in Na2O, K2O, SiO2, A12O3 melts. Terra Cognita, 5, 330.Google Scholar
Mumpton, F.A. and Roy, R. (1961) Hydrothermal stability studies of the zircon-thorite group. Geochimica et Cosmochimica Acta, 21, 217238.CrossRefGoogle Scholar
Pearce, J.A. (1984) Trace element discrimination diagrams for the tectonic interpretation of granitic rocks. Journal of Petrology, 25, 956983.CrossRefGoogle Scholar
Peng, Y.M. and Dong, C.W. (1991) A study on Qingtian alkaline granite, Zhejiang province. Journal of Nanjing University (Earth Sciences), 2, 138147 [Chinese with English abstract].Google Scholar
Qiu, J.S., Wang, D.Z., Peng, Y.M. and Zhou, J.C. (1996) Petrology, geochemistry and genesis of Taohuadao alkali granite in Zhoushan, Zhejiang Province. Journal of Nanjing University (Earth Sciences), 32, 7989 [Chinese with English abstract].Google Scholar
Qiu, J.S., Wang, D.Z., McInnes, B.I.A., Jiang, S.Y., Wang, R.C. and Kanisawa, S. (2004) Two contrasting A-type granites in the coastal area of Zhejiang and Fujian Province, SE China: geochemical constraints on their petrogenesis. Transactions of the Royal Society of Edinburgh – Earth Sciences, 95, 227236.CrossRefGoogle Scholar
Rapp, R.P. and Watson, E.B. (1986) Monazite solubility and dissolution kinetics: implications for the thorium and light rare earth geochemistry of felsic magmas. Contributions to Mineralogy and Petrology, 94, 304316.CrossRefGoogle Scholar
Robinson, D.M. and Miller, C.F. (1999) Record of magma chamber processes preserved in accessory mineral assemblages, Aztec Wash pluton, Nevada. American Mineralogist, 84, 13461353.CrossRefGoogle Scholar
Rubin, J.N., Henry, C.D. and Price, J.G. (1989) Hydrothermal zircons and zircon overgrowths, Sierra Blanca Peaks, Texas. American Mineralogist, 74, 865869.Google Scholar
Suwa, K., Enami, M., Hiraiwa, I. and Yang, T.M. (1987) Zn-Mn ilmenite in the Kuiqi granite from Fuzhou, Fujian Province, East China. Mineralogy and Petrology, 36, 111120.CrossRefGoogle Scholar
Troll, V.R., Sachs, P.M., Schmincke, H.U. and Sumita, M. (2003) The REE-Ti mineral chevkinite in comenditic magmas from Gran Canaria, Spain: a SYXRF-Probe study. Contributions to Mineralogy and Petrology, 145, 730741.CrossRefGoogle Scholar
Tu, G., Zhang, Y. and Zhao, Z. (1982) Preliminary studies on two alkali-rich intrusive belts in south China. Pp. 3351 in: Proceeding of the International Symposium held at Nanjing University, Geology of Granites and their Metallogenetic Relations (Xu, K.Q. and Tu, G.Z., editors). Science Press, Beijing.Google Scholar
Wang, D.Z., Zhao, G.T. and Qiu, J.S. (1995) The tectonic constraint on the late Mesozoic A-type granitoids in eastern China. Geological Journal of China University, 1, 1321 [Chinese with English abstract].Google Scholar
Wang, R.C., Fontan, F., Xu, S.J., Chen, X.M. and Monchoux, P. (1996) Hafnian zircon from the apical part of the Suzhou granite, China. The Canadian Mineralogist, 34, 10011010.Google Scholar
Wang, R.C., Zhao, G.T., Chen, X.M., Lu, J.J., Xu, S.J. and Wang, D.Z. (2000) Chemistry of Hf-rich zircons from the Laoshan I- and A- type granites, Eastern China. Mineralogical Magazine, 64, 867877.CrossRefGoogle Scholar
Wang, R.C., Wang, D.Z., Zhao, G.T., Lu, J.J., Chen, X.M. and Xu, S.J. (2001) Accessory mineral record of magma-fluid interaction in the Laoshan I- and A-type granitic complex, eastern China. Physics and Chemistry of the Earth Part A – Solid Earth and Geodesy, 26, 835849.CrossRefGoogle Scholar
Wang, R.C., Fontan, F., Chen, X.M., Hu, H., Liu, C.S., Xu, S.J. and de Parseval, P. (2003) Accessory minerals in the Xihuashan Y-enriched granitic complex, southern China: A record of magmatic and hydrothermal stages of evolution. The Canadian Mineralogist, 41, 727748.CrossRefGoogle Scholar
Watson, E.B. (1980) Apatite and phosphorus in mantle source regions: an experimental study of apatite/melt equilibria at pressures to 25 kbar. Earth and Planetary Science Letters, 51, 322335.CrossRefGoogle Scholar
Watson, E.B. and Harrison, T.M. (1983) Zircon saturation revisited: temperature and composition effects in a variety of crust magma types. Earth and Planetary Science Letters, 64, 295304.CrossRefGoogle Scholar
Wei, C.S., Zheng, Y.F. and Zhao, Z.F. (2000) Hydrogen and oxygen isotope geochemistry of A-type granites in the continental margins of eastern China. Tectonophysics, 328, 205227.CrossRefGoogle Scholar
Wu, F.Y., Sun, D.Y., Li, H.M., Jahn, B.M. and Wilde, C.S. (2002) A-type granites in northeastern China: age and geochemical constraints on their petrogenesis. Chemical Geology, 187, 143173.CrossRefGoogle Scholar
Xie, L., Wang, R.C., Chen, X.M., Qiu, J.S. and Wang, D.Z. (2005) Th-rich zircon from peralkaline A-type granite: mineralogical features and petrological implications. Chinese Science Bulletin, 50, 809817.Google Scholar
Zhang, A.C., Wang, R.C., Hu, H., Zhang, H., Zhu, J.C. and Chen, C.M. (2004) Chemical evolution of Nb-Ta oxides and zircon from the Koktokay No. 3 granitic pegmatite, Altai, northwestern China. Mineralogical Magazine, 68, 739756.CrossRefGoogle Scholar
Zhao, G.T., Wang, D.Z. and Cao, Q.C. (1997) The geochemistry and genesis of the Laoshan granitoids, Shandong Province. Geological Journal of China Universities, 3, 115 [Chinese with English abstract].Google Scholar
Zhou, X.M. and Li, W.X. (2000) Origin of Late Mesozoic igneous rocks in Southeastern China: implications for lithosphere subduction and under-plating of mafic magmas. Tectonophysics, 326, 269287.CrossRefGoogle Scholar
Zhou, X.R. and Wu, K.L. (1994) Zhangzhou Composite Granite. Science Press, Beijing, China, pp. 153 [Chinese with English abstract].Google Scholar