Hostname: page-component-76fb5796d-9pm4c Total loading time: 0 Render date: 2024-04-25T20:50:43.026Z Has data issue: false hasContentIssue false

Rare-earth element distribution and genesis of manganese ores associated with Tethyan ophiolites, Iran: A review

Published online by Cambridge University Press:  02 January 2018

Alireza Zarasvandi*
Affiliation:
Department of Geology, Shahid Chamran University (SCU), Ahavz, Iran
Mohsen Rezaei
Affiliation:
Department of Geology, Shahid Chamran University (SCU), Ahavz, Iran
Martiya Sadeghi
Affiliation:
Department of Mineral Resources, Geological Survey of Sweden (SGU), Uppsala, Sweden
Houshang Pourkaseb
Affiliation:
Department of Geology, Shahid Chamran University (SCU), Ahavz, Iran
Masoume Sepahvand
Affiliation:
Department of Geology, Shahid Chamran University (SCU), Ahavz, Iran

Abstract

The Zagros orogenic and metallogenic belt is characterized by the widespread occurrence of manganese and ferromanganese deposits. These deposits are spatially associated with radiolarian cherts and basaltic rocks, which cap the ophiolite sequences. The present work provides a review on the rare-earth element (REE) geochemistry coupled with major- and trace-element geochemical characteristics of the Nasirabad and Abadeh Tashk manganese deposits (associated with the Neyriz ophiolite), and Sorkhvand manganese deposit (associated with the Kermanshah ophiolite). These data are used to gain an insight into the primary ore-forming processes that control the deposition of manganese ores. All of the selected manganese deposits have consistently high Ba contents and low concentrations of trace elements (Co, Cu and Ni) with high Mn/Fe ratios typical of hydrothermal activity. A relatively low REE abundance, Lan/Ndn ratios (>3), and position on a Lan/Cen vs. Al2O3/(Al2O3 + Fe2O3) discrimination plot indicate a distal hydrothermal source for almost all of the selected manganese deposits. Most of the deposits are characterized by Ceanom < –0.1 which reflects the prevailing oxidative conditions during the deposition of manganese ores. Importantly, this is consistent with the occurrence of non-sulfide oxic Mn mineralization in all the manganese deposits of the Zagros orogeny. The comparison of the Sorkhvand, Abadeh Tashk and Nasirabad manganese deposits with other manganese deposits elsewhere in the world indicates that major- and trace-element characteristics, as well as the REE composition of the Zagros manganese deposits are analogous to those typical of hydrothermal deposits.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2016

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Alavi, M. (2004) Regional stratigraphy of the Zagros fold-thrust belt of Iran and its proforeland evolution. American Journal of Science, 304,120 CrossRefGoogle Scholar
Babaie, H.A., Ghazi, M.A., Babaie, A., La Tour, T.E. and Hassanipak, A.A. (2001) Geochemistry of arc vol¬canic rocks of the Zagros Crush Zone, Neyriz Iran. Journal of Asian Earth Sciences, 19, 6176. CrossRefGoogle Scholar
Bau, M. and Möller, P. (1991) REE systematics as source of information on minerogenesis. Pp. 1720 in: Source, Transport and Deposition of Metals.(M. Pagel and J.L. Leroy, editors). Balkema, Rotterdam.Google Scholar
Bonatti, E., Kraemer, T. and Rydell, H. (1972) Classification and genesis of submarine iron—manga¬nese deposits. Pp. 473489 in: Ferromanganese Deposits of the Ocean Floor (D.R. Horn, editor). Harriman, Petersfield, UK.Google Scholar
Campbell, K., Ghazi, A.M., LaTour, T. and Hassanipak, A.A. (2000) Geochemistry, petrology and tectonics of the Shahr-e-Babak ophiolite, SE Iran. Geological Society of America Annual Meeting, Abstracts with Programs — southeastern Section, 31, 9.Google Scholar
Chetty, D. and Gutzmer, J. (2012) REE redistribution during hydrothermal alteration of ores of the Kalahari manganese Deposit. Ore Geology Reviews, 47, 126135. CrossRefGoogle Scholar
Choi, J.H. and Hariya, Y (1992) Geochemistry and depositional environment of Mn oxide deposits in the Tokoro Belt, Northeastern Hokkaido, Japan. Economic Geology, 87, 12651274. CrossRefGoogle Scholar
Davoudzadeh, M. (1972) Geology and Petrology of the area North of Nain, Central Iran. Report No. 1. Geological Survey of Iran.Google Scholar
Dubinin, A.V. and Volkov, I.I. (1986) Rare earth elements in metalliferous sediments of the East Pacific Rise [ J ]. Geokhimija, 5, 645.Google Scholar
Evensen, M.N., Hamilton, P. and O'Nions, R.K. (1978) Rare-earth abundances in chondritic meteorites. Geochimica et Cosmochimica Acta, 42, 1199.CrossRefGoogle Scholar
Ghasemi, A. and Talbot, C.J. (2006) A new tectonic scenario for the Sanandaj-Sirjan Zone (Iran). Journal of Asian Earth Sciences, 26, 683693 CrossRefGoogle Scholar
Ghazi, A.M. and Hassanipak, A.A. (1999) Geochemistry and petrology of subalkaline and alkaline extrusives of Kermanshah ophiolite, Zagros Suture Zone, SW Iran. Journal of Asian Earth Sciences, 17, 319332. CrossRefGoogle Scholar
Ghazi, A.M., Chatham, B., Hassanipak, A.A., Mahoney, J.J. and Duncan, R.A. (1999) A petrogenetic investi¬gation of the Khoy ophiolite, NW Iran: implications for Tethyan magmatism and ophiolite genesis. RIDGE Field School: The Troodos Ophiolite and Mid-Ocean Ridge Processes. Abstract and Field School Notes, Larnaca, Cyprus, July 1999. Oregon State University, USA.Google Scholar
Ghorbani, M. (2013) The Economic Geology of Iran: Mineral Deposits and Natural Resources. Springer Geology, 450 pp.CrossRefGoogle Scholar
Hassanipak, A.A. and Ghazi, A.M. (2000) Petrology, geochemistry and tectonic setting of the Khoy ophiolite, Northwest Iran. Journal of Asian Earth Sciences, 18, 109121. CrossRefGoogle Scholar
Hassanipak, A.A., Ghazi, A.M., Duncan, R.A., Pessagno, E.A., Kariminia, S.M. and Mobasher, K. (2002) Spatial and temporal distribution of Paleo- and Neo-Tethys ophiolites in Iran and their tectonomagmatic significance. Geological Society of America Annual Meeting —Abstracts with Programs, 37, 33.Google Scholar
Haynes, S.J. and Reynolds, P.H. (1980) Early develop¬ment of Tethys and Jurassic ophiolite displacement. Nature, 283,561563 CrossRefGoogle Scholar
Jach, R. and Dudek, T. (2005) Origin of a Toarcian manganese carbonate/silicate deposit from the Krízna unit, Tatra Mountains, Poland. Chemical Geology, 224,136152 CrossRefGoogle Scholar
Karakus, A., Yavuz, B. and Koc, S. (2010) Mineralogy and major trace element geochemistry of the Haymana manganese mineralizations, Ankara, Turkey. Geochemistry International, 48, 10141027. CrossRefGoogle Scholar
Maynard, J. (2010) The chemistry of manganese ores through time: a signal of increasing diversity of earth-surface environments. Economic Geology, 105,535552 CrossRefGoogle Scholar
Michard, A., Michard, G., Stuben, D., Stoffers, P., Cheminee, J.L. and Binard, N. (1993) Submarine thermal springs associated with young volcanoes: the Teahitia vents, Society islands Pacific Ocean. Geochimica et Cosmochimica Acta, 57, 49774986 CrossRefGoogle Scholar
Migdisov, A.A. and Williams-Jones, A.E. (2014) Hydrothermal transport and deposition of the rare earth elements by fluorine-bearing aqueous liquids. Mineralium Deposita, DOI 10.1007/s00126-014-0554-zCrossRefGoogle Scholar
Mishra, P.P., Mohapatra, B.K. and Singh, P.P. (2007) Contrasting REE Signatures on Manganese Ore of Iron Ore Group in North Orissa, India. Journal of Rare Earths, 25,749758 CrossRefGoogle Scholar
Mohapatra, B.K., Mishra, P.P. and Singh, P.P. (2009) Manganese ore deposits in Koira- Noamundi province of iron ore group, north Orissa, India: in the light of geochemical signature. Chemie der Erde Geochemistry, 69, 377394. CrossRefGoogle Scholar
Mohseni, S. and Aftabi, A. (2015) Structural, textural, geochemical and isotopic signatures of synglaciogenic Neoproterozoic banded iron formations (BIFs) at Bafq mining district (BMD), Central Iran: The possible Ediacaran missing link of BIFs in Tethyan metallo-geny. Ore Geology Reviews, 71, 215236 CrossRefGoogle Scholar
Mücke, A., Adjimah, K. and Annor, A. (1999) Mineralogy, petrography, geochemistry and genesis of the Paleoproterozoic Birimian manganese-formation of Nsuta/Ghana. Mineralium Deposita, 34,297311 Google Scholar
Murray, R.W. (1994) Chemical criteria to identify the depositional environment of chert: general principles and applications. Sedimentary Geology, 90, 213232 CrossRefGoogle Scholar
Nabatian, Gh. Rastad, E., Neubauer, F., Honarmand, M. and Ghaderi, M. (2015) Iron and Fe—Mn mineraliza¬tion in Iran: implications for Tethyan metallogeny. Australian Journal of Earth Sciences: An International Geoscience Journal of the Geological Society of Australia, 62, 211241. CrossRefGoogle Scholar
Oksuz, N. (2011) Geochemical characteristics of the Eymir (Sorgun-Yozgat) manganese deposit. Journal of Rare Earths, 29, 287–286.CrossRefGoogle Scholar
Polgári, M., Hein, J.R., Vigh, T., Szabó-Drubina, M., Fórizs, I., Bíró, L., Müller, A. and Tóth, A.L. (2012) Microbial processes and the origin of the Úrkút manganese deposit, Hungary. Ore Geology Reviews, 47, 87109. CrossRefGoogle Scholar
Rajabzadeh, M.A. and Zamansani, N. (2012) Mineralization study of manganese deposits from Abadeh Tashk area, Fars Province by using mineral-ogical and geochemical data. 3rd symposium of the Society of Economic geology of Iran, Ahvaz, Iran [In Persian with English abstract].Google Scholar
Rajabzadeh, M.A. and Zamansani, N. (2013) The investigation of manganese mineralization associted with Neyriz ophiolite melange in the Abadeh Tashk region, Fars province; using mineralogical and geochemical studies. Iranian Journal of Economic Geology, 5, 201214. Google Scholar
Rezaei, M. (2012) The Investigation of Geology, Geochemistry and Genesis of Nasirabad Manganese Deposit, Neyriz, Fars province.Unpublished MSc dissertation, Shahid Chamran University, Ahvaz, Iran.Google Scholar
Roy, S. (1981) Manganese Deposits Academic Press 458 pp.Google Scholar
Roy, S. (1992) Environment and processes of manganese deposition. Economic Geology, 87, 12181236. CrossRefGoogle Scholar
Ruhlin, D.E. and Owen, R.M. (1986) The rare earth element geochemistry of hydro-thermal sediments from the East Pacific Rise: examination of a seawater scavenging mechanism. Geochimica et Cosmochimica Acta, 50, 393400. CrossRefGoogle Scholar
Sabatino, N., Neri, R., Bellanca, A., Jenkyns, H.C., Masetti, D. and Scopelliti, G. (2011) Petrography and high-resolution geochemical records of Lower Jurassic manganese-rich deposits from Monte Mangart, Julian Alps. Palaeogeography, Palaeoclimatology Palaeoecology, 299, 97109 CrossRefGoogle Scholar
Saccani, E., Allahyari, Kh., Beccaluva, L. and Bianchini, G. (2013) Geochemistry and petrology of the Kermanshah ophiolites (Iran): Implication for the interaction between passive rifting, oceanic accretion, and OIB-type components in the Southern Neo-Tethys Ocean. Gondwana Research, 24,392411 CrossRefGoogle Scholar
Sarkarinejad, K. (1994) Petrology and tectonic setting of the Neyriz ophiolite, southeast Iran. Pp. 221-234 in: Circum-Pacific Ophiolites.(A. Ishiwatari, A. Malpas and H. Ishizuka, editors). Proceedings, 29th International Geological Congress, Part D. VSP, Utrecht, The Netherlands.Google Scholar
Sepahvand, M. (2015) Geology, geochemistry and genesis of Sorkhvand manganese deposit, SW Harsin, Kermanshah. Unpublished MSc dissertation, Shahid Chamran University, Ahvaz, Iran.Google Scholar
Shah, M.T. and Khan, A. (1999) Geochemistry and origin of Mn-deposits in the Waziristan ophiolite complex, north Waziristan, Pakistan. Mineralium Deposita, 34, 697704. CrossRefGoogle Scholar
Shah, M.T. and Moon, C.J. (2007) Manganese and ferromanganese ores from different tectonic settings in the NW Himalayas, Pakistan. Journal Asian Earth Science, 29, 455465. CrossRefGoogle Scholar
Shahabpour, J. (2002) Economic Geology, 137, 543, Shahid Bahonar University of Kerman Publications [in Persian].Google Scholar
Shahabpour, J. (2005) Tectonic evolution of the orogenic belt in the region located between Kerman and Neyriz. Journal of Asian Earth Science, 24, 405417. CrossRefGoogle Scholar
Stocklin, J. (1974) Possible ancient continental margine in Iran. Pp. 873887 in: The Geology of Continental Margins.(C.A. Burke and C.L. Drake, editors). Springer, New York.CrossRefGoogle Scholar
Tangestani, M., Jaffari, L., Vincent, R. and Maruthi Sridhar, B.B. (2011) Spectral characterization and ASTER-based lithological mapping of an ophiolite complex: A case study from Neyriz ophiolite, SW Iran. Remote Sensing of Environment, 115,22432254 CrossRefGoogle Scholar
Taylor, S.R. and Mclennan, S.M. (1985) The Continental Crustal: Its Composition and Evolution|Blackwell, Oxford 312 pp.Google Scholar
Toth, J.R. (1980) Deposition of submarine crusts rich in manganese and iron. Geological Society of America Bulletin, 91, 4454. 2.0.CO;2>CrossRefGoogle Scholar
Usui, A. and Someya, M. (1997) Distribution and composition of marine hydrogenetic and hydrother-mal manganese deposits in the northwest Pacific. Pp. 177198 in: Manganese Mineralization: Geochemistry and Mineralogy of Terrestrial and Marine Deposits (K. Nicholson J.R. Hein B. Buhn and S. Dasgupta, editors). Geological Society, London, Special Publications, 19.Google Scholar
Varnavas, S.P., Papaioannu, J. and Catani, J. (1988) A hydrothermal manganese deposit from the Eratosthenes Seamount, eastern Mediterranean Sea. Marine Geology, 81, 205214. CrossRefGoogle Scholar
Von Stackelberg, U. (1997) Growth history of manganese nodules and crusts of the Peru basin. Pp. 153176 in: Manganese Mineralization: Geochemistry and Mineralogy of Terrestrial and Marine Deposits (K. Nicholson J.R. Hein B. Bühn and S. Dasgupta, editors). Geological Society, London, Special Publications, 119.CrossRefGoogle Scholar
Williams-Jones, A.E., Samson, I.M. and Olivo, G.R. (2000) The genesis of hydrothermal fluorite-REE deposits in the Gallinas Mountains, New Mexico. Economic Geology, 95, 327341. CrossRefGoogle Scholar
Wright, J. and Holser, W.T. (1987) Paleoredox variations in ancient oceans recorded by rare earth elements in fossil apatite. Geochimica et Cosmochimica Acta, 51, 631644. CrossRefGoogle Scholar
Xie, J., Sun, W., Du, J., Xu, W., Wu, L., Yang, S. and Zhou, S. (2013) Geochemical studies on Permian manganese deposits in Guichi, eastern China: Implications for their origin and formative environ-ments. Journal of Asian Earth Sciences, 74, 155166 CrossRefGoogle Scholar
Zarasvandi, A., Lentz, D., Rezaei, M. and Pourkaseb, H. (2013a) Genesis of the Nasirabad manganese occur¬rence, Fars province, Iran: Geochemical evidences. Chemie der Erde Geochemistry, 73, 495508. CrossRefGoogle Scholar
Zarasvandi, A., Rezaei, M., Pourkaseb, H. and Saki, A. (2013b) Investigation on primary and secondary processes in Nasirabad manganese deposit, south of Neyriz: using mineralogy and Pb isotope geochemistry. Iranian Journal of Economic Geology, 5, 3747. Google Scholar
Zarasvandi, A., Sepahvand, M., Pourkaseb, H. and Rezaei, M. (2014) Mineralogical and textural studies on the Sorkhvand manganese deposit, Harsin: Evidences for ore forming processes. 6th Symposium of the Society of Economic Geology of Iran. Zahedan, Iran.Google Scholar