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Petrography and mineral chemistry of mantle xenoliths in a carbonate-rich melilititic tuff from Mt. Vulture volcano, southern Italy

Published online by Cambridge University Press:  05 July 2018

A. P. Jones*
Affiliation:
Department of Geological Sciences, University College London, Gower Street, London WC1E 6BT, UK
T. Kostoula
Affiliation:
Department of Geological Sciences, University College London, Gower Street, London WC1E 6BT, UK
F. Stoppa
Affiliation:
Dipartimento di Scienze della Terra, Università di Perugia, Perugia, I-06100, Italy
A. R. Woolley
Affiliation:
Department of Mineralogy, Natural History Museum, Cromwell Road, London SW7 5BD, UK

Abstract

We present petrographic and mineralogical data for 21 mantle xenoliths (12 lherzolites, 8 wehrlites and 1 composite) selected from a suite of more than 70 samples collected from the Monticchio Formation, Mt. Vulture volcano, southern Italy. The xenoliths are rounded, coarse- to porphyroclastic-textured, and very fresh, with the following equilibrated mineral assemblages; olivine (Fo90–92), orthopyroxene (∼En89, Wo2.0), clinopyroxene (Mg90–92, 3–6% Al2O3, 1–1.5% Cr2O3), and chrome-spinel (14–20% MgO, ∼30–40% Cr2O3). Many xenoliths contain partial melt glasses and accessory sulphide (pentlandite) Some contain primary mica (phlogopite with ∼4% FeO, 1.8% Cr2O3, 1.4–2.8% TiO2) with slightly zoned rims (Fe-, Ti-, Al-enriched). One contains relics of garnet (pyrope; Mg84). Secondary veins in several xenoliths contain carbonate with significant Sr levels (∼0.5–1.0% SrO), occasional apatite and scarce melanite, all typical of carbonatites and presumably related to the host magma (melilitite/carbonatite). Although amphibole is a common megacryst in the same volcanic units, no primary amphibole was found in the xenoliths themselves. Calculated pressures and temperatures using a range of geothermometers/barometers give values of 14–22 kbar and 1050–1150°C. In particular, the En-Sp and Di-Sp thermo/barometers (Mercier, 1980) show a good positive correlation between P and T. The Monticchio xenoliths lie on the high-T side of an ‘oceanic’ geotherm. The xenolith geotherm is hotter than general heat flow values in this region at the current day (50 mWm−2) but it compares well with the high-pressure end of a typical alkaline continental rift.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2000

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References

Beccaluva, L., Macciotta, G., Piccardo, G.B. and Zeda, O. (1984). Petrology of lherzolitic rocks from the Northern Apennine ophiolites. Lithos, 17, 214–54.CrossRefGoogle Scholar
Brey, G.P. and Kohler, T. (1990) Geothermobarometry in four-phase lherzolites II. New thermobarometers, and practical assessment of existing thermobarometers. J. Petrol., 31, 1353–78.CrossRefGoogle Scholar
Brocchini, D., La Volpe, L., Laurenzi, M.A. and Principe, C. (1994). Storia evolutiva del Monte Vulture. Plinius, 12, 22–5.Google Scholar
Conticelli, S. and Peccerillo, A. (1990). Petrological significance of high-pressure ultramafic xenoliths from ultrapotassic rocks of Central Italy. Lithos, 24, 305–22.CrossRefGoogle Scholar
De Fino, M., La Volpe, L. and Piccareta, G. (1982) Magma evolution at Monte Vulture (Southern Italy). Bull. Volcanol., 45, 115–26.CrossRefGoogle Scholar
De Fino, M., La Volpe, L., Piccareta, G. and Poli, G. (1986) Petrogenesis of Mt. Vulture volcano (Italy): inferences from mineral chemistry, major and trace element data. Contrib. Mineral. Petrol., 92, 135–45.CrossRefGoogle Scholar
Downes, H. (1990) Shear zones in the upper mantle – Relation between geochemical enrinchment and deformation in the upper mantle. Geology, 18, 370–4.2.3.CO;2>CrossRefGoogle Scholar
Draper, D.S. and Green, T.H. (1997) P-T phase of silicic, alkaline, aluminous mantle–xenolith glasses under anhydrous and C-O-H fluid-saturated conditions. J. Petrol., 38, 1187–224.CrossRefGoogle Scholar
Drury, M.R. and Van Roermund, H.L.M. (1989) Fluid assisted recrystallization in upper mantle peridotite xenoliths from kimberlites. J. Petrol., 30, 133–52.CrossRefGoogle Scholar
Eggler, D.H. (1989) Carbonatites, primary melts and mantle dynamics. Pp. 561–79 in: Carbonatites: Genesis and Evolution (Bell, K., editor). Unwin Hyman, London.Google Scholar
Ehrenberg, S.N. (1982) Petrogenesis of garnet lherzolite and megacrystalline nodules from the Thumb, Navajo volcanic field. J. Petrol., 23, 507–47.CrossRefGoogle Scholar
Harte, B. (1977) Ultramafic xenoliths nomenclature classification. J. Petrol., 85, 279–88.Google Scholar
Harte, B. (1983) Mantle peridotites and processes – the kimberlite sample. Pp. 4691 in: Continental Basalts and Mantle Xenoliths (Hawkesworth, C.J. and Norry, M.J., editors). Shiva Geological Series.Google Scholar
Hieke Merlin, O. (1967) I produtti volcanici del Monte Vulture (Lucania). Memoranda of the 1st Geological and Mineralogical Meeting, University of Pavia, XXVI, 367.Google Scholar
Johnson, L. Jones, A.P., Church, A.A. and Taylor, W.R. (1997) Ultramafic xenoliths and megacrysts from a melilitite tuff cone, Deeti, northern Tanzania. J. Afr. Earth Sci., 25, 2942.CrossRefGoogle Scholar
Jones, A.P., Smith, J.V. Dawson, J.B. and Hansen, E.C. (1983 a) Metamorphism, partial melting, and K-metasomatism of garnet-scapolite kyanite granulite xenoliths from Lashaine, Tanzania. J. Geol., 91, 143–65.CrossRefGoogle Scholar
Jones, A.P. Smith, J.V. and Dawson, J.B. (1983 b) Glasses in mantle xenoliths from Olmani, Tanzania. J. Geol., 91, 167–78.CrossRefGoogle Scholar
Kohler, T. and Brey, G.P. (1990) Ca-exchange between olivine and clinopyroxene as a geothermobarometer calibrated from 2 to 60 kbar in primitive natural lherzolites. Geochim. Cosmochim. Acta, 54, 2375–88.CrossRefGoogle Scholar
Lavecchia, G. and Stoppa, F. (1996) The tectonic significance of Italian magmatism: an alternative view to popular interpretation. Terra Nova, 8, 435–46.CrossRefGoogle Scholar
La Volpe, L. and Principe, C. (1991) Comments on “Monte Vulture Volcano (Basilicata, Italy): an analysis of morphology and volcaniclastic facies” by J.E. Guest, A.M. Duncan and D.K. Chester. Bull. Volcanol., 53, 222–7.CrossRefGoogle Scholar
Melluso, L., Morra, V. and Di Girolamo, P. (1996) The Mt. Vulture volcanic complex (Italy): evidence for distinct parental magmas and for residual melts with melilitite. Mineral. Petrol., 56, 225–50.CrossRefGoogle Scholar
Mercier, J.C. (1980) Single-pyroxene thermobarometry. Tectonophysics, 70, 137.CrossRefGoogle Scholar
Mercier, J.C. and Nicolas, A. (1974) Textures and fabrics of upper-mantle peridotites as illustrated by xenoliths from basalts. J. Petrol., 16, 455–87.Google Scholar
Pike Nielson, J.E. and Scharzman, E.G. (1977) Classification of textures in ultramafic xenoliths. J. Petrol., 85, 4961.Google Scholar
Rudnik, R.L., McDonough, W.T. and Chappel, B.W. (1993) Carbonatite metasomatism in the Northern Tanzanian mantle: petrography and geochemical characteristics. Earth Planet. Sci. Lett., 124, 463–75.CrossRefGoogle Scholar
Sachtleben, T.H. and Seck, A.A. (1981) Chemical control of Al-solubility in orthopyroxene and its implications on pyroxene geothermometry. Contrib. Mineral. Petrol., 78, 157–65.CrossRefGoogle Scholar
Simkin, T. and Smith, J.V. (1970) Minor element distribution in olivine. J. Geol., 78, 347–64.CrossRefGoogle Scholar
Stoppa, F. and Lupini, L. (1993) Mineralogy and petrology of the Polino monticellite calciocarbonatite (Central Italy). Mineral. Petrol., 49, 213–31.CrossRefGoogle Scholar
Stoppa, F. and Principe, C. (1994) Caratteristiche litologiche delle piroclastiti associate alla genesi dei maar di Monticchio: prima segnalazione di depositi carbonatitico-melilititici al Mt. Vulture. Plinius, 12, 86–90.Google Scholar
Stoppa, F. and Principe, C. (1997) Eruption style and petrology of a new carbonatitic suite from Mt. Vulture, Southern Italy: the Monticchio Lakes Formation. J. Volcanol. Geotherm. Res., 78, 251–65.CrossRefGoogle Scholar
Stoppa, F. and Woolley, A.R. (1997). The Italian carbonatites: field occurrence, petrology and regional significance. Contrib. Mineral. Petrol., 59, 43–67.CrossRefGoogle Scholar
Wells, P.R.A. (1977) Pyroxene thermometry in simple and complex systems. Contrib. Mineral. Petrol., 62, 129–39.CrossRefGoogle Scholar
Wendlandt, R.F. and Eggler, D.H. (1980) The origin of potassic magmas: Stability of phlogopite in natural spinel lherzolites and in the system KAlSiO4-MgO-SiO2- H2O-CO2 at high pressures and temperatures. Amer. J. Science, 280, 421–50.CrossRefGoogle Scholar
Wood, B.J. and Banno, S. (1973) Garnet-orthopyroxene and orthopyroxene-clinopyroxene relationships in simple and complex systems. Contrib. Mineral. Petrol., 42, 102–24.CrossRefGoogle Scholar