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Light rare earth element redistribution during hydrothermal alteration at the Okorusu carbonatite complex, Namibia

  • Delia Cangelosi (a1), Sam Broom-Fendley (a2), David Banks (a1), Daniel Morgan (a1) and Bruce Yardley (a1)...

Abstract

The Cretaceous Okorusu carbonatite, Namibia, includes diopside-bearing and pegmatitic calcite carbonatites, both exhibiting hydrothermally altered mineral assemblages. In unaltered carbonatite, Sr, Ba and rare earth elements (REE) are hosted principally by calcite and fluorapatite. However, in hydrothermally altered carbonatites, small (<50 µm) parisite-(Ce) grains are the dominant REE host, while Ba and Sr are hosted in baryte, celestine, strontianite and witherite. Hydrothermal calcite has a much lower trace-element content than the original, magmatic calcite. Regardless of the low REE contents of the hydrothermal calcite, the REE patterns are similar to those of parisite-(Ce), magmatic minerals and mafic rocks associated with the carbonatites. These similarities suggest that hydrothermal alteration remobilised REE from magmatic minerals, predominantly calcite, without significant fractionation or addition from an external source. Barium and Sr released during alteration were mainly reprecipitated as sulfates. The breakdown of magmatic pyrite into iron hydroxide is inferred to be the main source of sulfate. The behaviour of sulfur suggests that the hydrothermal fluid was somewhat oxidising and it may have been part of a geothermal circulation system. Late hydrothermal massive fluorite replaced the calcite carbonatites at Okorusu and resulted in extensive chemical change, suggesting continued magmatic contributions to the fluid system.

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Copyright

This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited.

Corresponding author

*Author for correspondence: Delia Cangelosi, Email: ee12dac@leeds.ac.uk

Footnotes

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This paper is part of a thematic set arising from the 3rd International Critical Metals Conference (Edinburgh, May 2019).

Associate Editor: Aniket Chakrabarty

Footnotes

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Light rare earth element redistribution during hydrothermal alteration at the Okorusu carbonatite complex, Namibia

  • Delia Cangelosi (a1), Sam Broom-Fendley (a2), David Banks (a1), Daniel Morgan (a1) and Bruce Yardley (a1)...

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