Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-12-07T13:13:56.690Z Has data issue: false hasContentIssue false

Resolving Nanoscale Heterogeneity in Battery Interphases with Cryo-EM

Published online by Cambridge University Press:  30 July 2020

William Huang
Affiliation:
Stanford University, Palo Alto, California, United States
Hansen Wang
Affiliation:
Stanford University, Stanford, California, United States
David Boyle
Affiliation:
Stanford University, Stanford, California, United States
Yuzhang Li
Affiliation:
Stanford University, Stanford, California, United States
Yi Cui
Affiliation:
Stanford University, Stanford, California, United States

Abstract

Image of the first page of this content. For PDF version, please use the ‘Save PDF’ preceeding this image.'
Type
Energy and Soft Materials and the Development of Cryogenic Techniques for Studying Them
Copyright
Copyright © Microscopy Society of America 2020

References

Chu, S.; Cui, Y.; Liu, N. The Path towards Sustainable Energy. Nat. Mater. 2016, 16 (1), 1622.10.1038/nmat4834CrossRefGoogle ScholarPubMed
Peled, E. The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model. J. Electrochem. Soc. 1979, 126 (12), 2047.10.1149/1.2128859CrossRefGoogle Scholar
Winter, M. The Solid Electrolyte Interphase - The Most Important and the Least Understood Solid Electrolyte in Rechargeable Li Batteries. Zeitschrift fur Phys. Chemie 2009, 223 (10–11), 13951406.10.1524/zpch.2009.6086CrossRefGoogle Scholar
Zachman, M. J.; Tu, Z.; Choudhury, S.; Archer, L. A.; Kourkoutis, L. F. Cryo-STEM Mapping of Solid–Liquid Interfaces and Dendrites in Lithium-Metal Batteries. Nature 2018, 560 (7718), 345349.10.1038/s41586-018-0397-3CrossRefGoogle ScholarPubMed
Li, Y.; Li, Y.; Pei, A.; Yan, K.; Sun, Y.; Wu, C. L.; Joubert, L. M.; Chin, R.; Koh, A. L.; Yu, Y.;, et al. Atomic Structure of Sensitive Battery Materials and Interfaces Revealed by Cryo–Electron Microscopy. Science. 2017, 358 (6362), 506510.10.1126/science.aam6014CrossRefGoogle ScholarPubMed
Wang, X.; Zhang, M.; Alvarado, J.; Wang, S.; Sina, M.; Lu, B.; Bouwer, J.; Xu, W.; Xiao, J.; Zhang, J. G.;, et al. New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM. Nano Lett. 2017, 17 (12), 76067612.10.1021/acs.nanolett.7b03606CrossRefGoogle ScholarPubMed
Fan, X.; Ji, X.; Han, F.; Yue, J.; Chen, J.; Chen, L.; Deng, T.; Jiang, J.; Wang, C. Fluorinated Solid Electrolyte Interphase Enables Highly Reversible Solid-State Li Metal Battery. Sci. Adv. 2018, 4 (12).10.1126/sciadv.aau9245CrossRefGoogle ScholarPubMed