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Oxidation Mechanism of Nickel Oxide/Carbon Nanotube Composite

Published online by Cambridge University Press:  06 August 2013

Tae-Hoon Kim ,
Min-Ho Park ,
Jiho Ryu  and
Cheol-Woong Yang
Tae-Hoon Kim
Affiliation:
School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, Gyeonggi-do 440-746, SouthKorea
Min-Ho Park
Affiliation:
School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, Gyeonggi-do 440-746, SouthKorea
Jiho Ryu
Affiliation:
Department of Automobile Development, Ajou Motor College, Boryeong 355-769, Korea
Cheol-Woong Yang*
Affiliation:
School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, Gyeonggi-do 440-746, SouthKorea
*
*Corresponding author. E-mail: cwyang@skku.edu
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Abstract

The oxidation mechanism and thermal stability of nickel oxide (NiO)/carbon nanotube (CNT) composites were investigated by examining composites with different NiO contents by thermogravimetric analysis and transmission electron microscopy (TEM). NiO acts as a catalyst in the oxidation of CNT in the composite. CNTs can be oxidized, even in a vacuum, by reducing NiO to nickel at temperatures lower than the normal oxidation temperature of CNTs. This phase transition was confirmed directly by in situ heating TEM observations. In air, reduction by CNT occurs simultaneously with reoxidation by gaseous O2 molecules, and NiO maintains its phase. The thermal stability decreased with increasing NiO content because of defects in the CNT generated by the NiO loading.

Keywords

oxidation mechanismNiOCNTcompositein situ heatingTEMTGARaman spectroscopy
Type
Research Article
Information
Microscopy and Microanalysis , Volume 19 , Supplement S5: IUMAS , August 2013 , pp. 202 - 206
Copyright
Copyright © Microscopy Society of America 2013 

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References

Ajayan, P.M., Stephan, O., Redlich, P. & Colliex, C. (1995). Carbon nanotubes as removable templates for metal oxide nanocomposites and nanostructures. Nature 375, 564–567.Google Scholar
Aksel, S. & Eder, D. (2010). Catalytic effect of metal oxides on the oxidation resistance in carbon nanotube-inorganic hybrids. J Mater Chem 20, 9149–9154.Google Scholar
Avouris, P., Chen, Z. & Perebeinos, V. (2007). Carbon-based electronics. Nat Nanotechnol 2, 605–615.Google Scholar
Behler, K., Osswald, S., Ye, H., Dimovski, S. & Gogotsi, Y. (2006). Effect of thermal treatment on the structure of multi-walled carbon nanotubes. J Nanopart Res 8, 615–625.Google Scholar
Brockner, W., Ehrhardt, C. & Gjikaj, M. (2007). Thermal decomposition of nickel nitrate hexahydrate, Ni(NO3)2·6H2O, in comparison to Co(NO3)2·6H2O and Ca(NO3)2·6H2O. Thermochim Acta 456, 64–68.Google Scholar
Brown, S.D.M., Jorio, A., Dresselhaus, M.S. & Dresselhaus, G. (2001). Observation of the D-band feature in the Raman spectra of carbon nanotubes. Phys Rev B 64, 073403.Google Scholar
Ellingham, H.J.T. (1944). Reducibility of oxides and sulfides in metallurgical processes. J Soc Chem Ind 63, 125–133.Google Scholar
He, K.X., Wu, Q.F., Zhang, X.G. & Wang, X.L. (2006). Electrodeposition of nickel and cobalt mixed oxide/carbon nanotube thin films and their charge storage properties. J Electrochem Soc 153(8), 1568–1574.Google Scholar
Iijima, S. (1991). Helical microtubules of graphitic carbon. Nature 354, 56–58.Google Scholar
Lee, Y.I., Park, M.H., Bae, J.H., Lee, S.E., Song, K.W., Kim, T.H., Lee, Y.H. & Yang, C.W. (2011). Loading behavior of Pt nanoparticles on the surface of multiwalled carbon nanotubes having defects formed via microwave treatment. J Nanosci Nanotechnol 11, 479–483.Google Scholar
Li, C., Wang, D., Liang, T., Wang, X., Wu, J., Hu, X. & Liang, J. (2004). Oxidation of multiwalled carbon nanotubes by air: Benefits for electric double layer capacitors. Powder Technol 142, 175–179.Google Scholar
Lota, K., Sierczynska, A. & Lota, G. (2011). Supercapacitors based on nickel oxide/carbon materials composites. Int J Electrochem 2011, 321473.Google Scholar
Mars, P. & Krevelen, D.W. (1954). Oxidations carried out by means of vanadium oxide catalysts. Chem Eng Sci 3, 41–59.Google Scholar
Osswald, S., Flahaut, E., Ye, H. & Gogotsi, Y. (2005). Elimination of D-band in Raman spectra of double-wall carbon nanotubes by oxidation. Chem Phys Lett 402, 422–427.Google Scholar
Osswald, S., Havel, M. & Gogotsi, Y. (2007). Monitoring oxidation of multiwalled carbon nanotubes by Raman spectroscopy. J Raman Spectrosc 38, 728–736.Google Scholar
Park, Y.S., Choi, Y.C., Kim, K.S., Chung, D.S., Bae, D.J., An, K.H., Lim, S.C., Zhu, X.Y. & Lee, Y.H. (2001). High yield purification of multiwalled carbon nanotubes by selective oxidation during thermal annealing. Carbon 39, 655–661.Google Scholar
Singleton, M. & Nash, P. (1989). The C-Ni (carbon-nickel) system. Bulletin of Alloy Phase Diagrams 10(2), 121–126.Google Scholar
Wang, D.W., Li, F. & Cheng, H.M. (2008). Hierarchical porous nickel oxide and carbon as electrode materials for asymmetric supercapacitor. J Power Sources 185(2), 1563–1568.Google Scholar
Xia, X.H., Tu, J.P., Zhang, J., Wang, X.L., Zhang, W.K. & Huang, H. (2008). Electrochromic properties of porous NiO thin films prepared by a chemical bath deposition. Sol Energy Mater Sol Cells 92(6), 628–633.Google Scholar
Zhu, X.Y., Lee, S.M., Lee, Y.H. & Frauenheim, T. (2000). Adsorption and desorption of an O2 molecule on carbon nanotubes. Phys Rev Lett 85(13), 2757–2760.Google Scholar