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Identification of Nanocrystalline Inclusions in Bismuth-Doped Silica Fibers and Preforms

  • Liudmila D. Iskhakova (a1), Filipp O. Milovich (a1) (a2), Valery M. Mashinsky (a1), Alexander S. Zlenko (a1), Sergey E. Borisovsky (a3) and Evgeny M. Dianov (a1)...

Abstract

The nature of nanocrystalline inclusions and dopant distribution in bismuth-doped silicate fibers and preforms are studied by scanning and transmission electron microscopy, and energy and wavelength-dispersive X-ray microanalysis. The core compositions are Bi:SiO2, Bi:Al2O3–SiO2, Bi:GeO2–SiO2, Bi:Al2O3–GeO2–SiO2, and Bi:P2O5–Al2O3–GeO2–SiO2. Nanocrystals of metallic Bi, Bi2O3, SiO2, GeO2, and Bi4(GeO4)3 are observed in these glasses. These inclusions can be the reason for the background optical loss in bismuth-doped optical fibers. The bismuth concentration of 0.0048±0.0006 at% is directly measured in aluminosilicate optical fibers with effective laser generation (slope efficiency of 27% at room temperature).

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* Corresponding author. ldisk@fo.gpi.ru

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Abo-Naf, S.M., Elwan, R.L. & Elkomy, G.M. (2012). Crystallization of bismuth oxide nano-crystallites in a SiO2–PbO–Bi2O3 glass matrix. J Non Cryst Solids 358, 964968.
Abramov, A.N., Yashkov, M.V., Guryanov, A.N., Melkumov, M.A., Dvoretskii, D.A., Bufetov, I.A., Iskhakova, L.D., Koltashev, V.V., Kachenyuk, M.N. & Torsunov, M.F. (2014). Fabrication and optical characterization of silica fibers with a chromium-and alumina-doped core. Inorg Mater 50(12), 12831288.
Biryukov, A.S., Dianov, E.M., Kurkov, A.S., Devyatykh, G.G., Guryanov, A.N. & Kobis, S.V. (1996). Core-cladding interface instability as one of the source of additional losses in high doped optical fibers. Proceedings of the 22th European Conference on Optical Communications, September 15–19, Oslo, Norway, paper TuP.02.
Bohren, C.F. & Huffman, D.R. (2008). Absorption and Scattering of Light by Small Particles. New York, Wiley: John Wiley & Sons.
Bufetov, I.A. & Dianov, E.M. (2009). Bi-doped fiber lasers. Laser Phys Lett 6, 487504.
Dianov, E.M. (2012). Bismuth-doped optical fibers: A challenging active medium for near-IR lasers and optical amplifiers. Light Sci Appl 1, e12e18.
Dianov, E.M. (2013). Amplification in extended transmission bands using bismuth-doped optical fibers. J Lightwave Technol 31(4), 681688.
Dimesso, L., Gnappi, G., Montenero, A., Fabeni, P. & Pazzi, G.P. (1991). The crystallization behaviour of bismuth germinate glasses. J Mater Sci 26, 42154219.
Dvoyrin, V.V., Kir’yanov, A.V., Mashinsky, V.M., Medvedkov, O.I., Umnikov, A.A., Guryanov, A.N. & Dianov, E.M. (2010). Absorption, gain, and laser action in aluminosilicate bismuth-doped optical fibers. IEEE J Quantum Electron 46(2), 182190.
Dvoyrin, V.V., Mashinsky, V.M., Bulatov, L.I., Bufetov, I.A., Shubin, A.V., Melkumov, M.A., Kustov, E.F., Dianov, E.M., Umnikov, A.A., Khopin, V.F., Yashkov, M.V. & Guryanov, A.N. (2006). Bismuth-doped-glass optical fibers—A new active medium for lasers and amplifiers. Opt Lett 31(20), 29662968.
Dvoyrin, V.V., Mashinsky, V.M. & Dianov, E.M. (2008). Efficient bismuth-doped fiber lasers. IEEE J Quantum Electron 44(9), 834840.
Fei, Y.T., Fan, S.J., Sun, R.Y. & Xu, J.Y. (2000). Crystallizing behavior of Bi2O3-SiO2 system. J Mat Sci Lett 19, 893895.
Firstov, S., Alyshev, S., Melkumov, M., Riumkin, K., Shubin, A. & Dianov, E. (2014). Bismuth-doped optical fibers and fiber lasers for a spectral region of 1600–1800 nm. Opt Lett 39(24), 69276930.
Firstov, S.V., Bufetov, I.A., Khopin, V.F., Smirnov, A.M., Iskhakova, L.D., Vechkanov, N.N., Guryanov, A.N. & Dianov, E.M. (2009). 2 W bismuth doped fiber lasers in the wavelength range 1300-1500 nm and variation of Bi-doped fiber parameters with core composition. Laser Phys Lett 6(9), 665670.
Firstov, S.V., Khopin, V.F., Bufetov, I.A., Firstova, E.G., Guryanov, A.N. & Dianov, E.M. (2011). Combined excitation-emission spectroscopy of bismuth active centers in optical fibers. Opt Express 19(20), 1955119561.
Firstov, S.V., Shubin, A.V., Khopin, V.F., Mel’kumov, M.A., Bufetov, I.A., Medvedkov, O.I., Gur’yanov, A.N. & Dianov, E.M. (2011). Bismuth-doped germanosilicate fibre laser with 20-W output power at 1460 nm. Quantum Electron 41(7), 581583.
Firstova, E.G., Bufetov, I.A., Khopin, V.F., Vel’miskin, V.V., Firstov, S.V., Bufetova, G.A., Nishchev, K.N., Gur’yanov, A.N. & Dianov, E.M. (2015). Luminescence properties of IR-emitting bismuth centres in SiO2-based glasses in the UV to near-IR spectral region. Quantum Electron 45(1), 5965.
Fujimoto, Y. (2010). Local structure of the infrared bismuth luminescent center in bismuth-doped silica glass. J Am Ceram Soc 93(2), 581589.
Gibson, B.C., Huntington, S.T., Love, J.D., Ryan, T.G., Cahill, L.W. & Elton, D.M. (2003). Controlled modification and direct characterization of multimode-fiber refractive-index profiles. Appl Opt 42(4), 627633.
Gur’yanov, A.N., Dianov, E.M., Lavrishchev, S.V., Mashinskiĭ, V.M., Neustruev, V.B., Nikolaĭchik, A.V. & Yushin, A.S. (1979). Investigation of the structure of preform materials and fiber-optical waveguides utilizing quartz glass doped with germanium and boron. Soviet J Quantum Electron 9, 12381242.
Haruna, T., Iihara, J. & Onishi, M. (2006). Bismuth-doped silicate glass fiber for ultra-broadband amplification media. Proceedings of the SPIE 6389, Active and Passive Optical Components for Communications VI, October 1, Boston, USA, 638903.
Jiang, X., Su, L., Yu, P., Guo, X., Tang, H., Xu, X., Zheng, L., Li, H. & Xu, J. (2013). Broadband photoluminescence of Bi2O3–GeO2 binary systems: glass, glass-ceramics and crystals. Laser Phys 23, 105812105824.
Khonton, S., Morimoto, S., Arai, Y. & Ohishi, Y. (2009). Redox equilibrium and NIR luminescence of Bi2O3—Containing glasses. Opt Mater 31, 12621268.
Lyytikäinen, K., Huntington, S.T., Carter, A.L.G., McNamara, P., Fleming, S., Abramczyk, J., Kaplin, I. & Schötz, G. (2004). Dopant diffusion during optical fibre drawing. Opt Express 12, 972977.
Malinin, A.A., Zlenko, A.S., Akhmetshin, U.G. & Semjonov, S.L. (2011). Furnace chemical vapor deposition (FCVD) method for special optical fibers fabrication. Proceedings of the SPIE 7934, Optical Components and Materials VIII, 793418.
McNamara, P., Lyytikainen, K.J., Ryan, T., Kaplin, I.J. & Ringer, S.P. (2004). Germanium-rich “starburst” cores in silica-based optical fibres fabricated by modified chemical vapour deposition. Opt Commun 230(1), 4553.
Polosan, S., Nastase, F. & Secu, M. (2011). Structural changes during the crystallization of the Bi4Ge3O12 glasses. J Non Cryst Solids 357, 11101113.
Qui, J. (2015). Bi-doped glass for photonic devices. Int J Appl Glass Sci 6(3), 275286.
Sanz, O., Haro-Poniatowski, E., Gonzalo, J. & Navarro, J.F. (2006). Influence of the melting conditions of heavy metal oxide glasses containing bismuth oxide on their optical absorption. J Non Cryst Solids 352(8), 761768.
Tang, F.Z., McNamara, P., Barton, G.W. & Ringer, S.P. (2006). Nanoscale characterization of silica soots and aluminium solution doping in optical fibre fabrication. J Non Cryst Solids 352(36), 37993807.
Torrengo, S., Paul, M.C., Halder, A., Das, S., Dhar, A., Sahu, J.K., Jain, S., Kir’janov, A.V. & d’Acapito, F. (2015). EXAFS studies of the local structure of bismuth center in multicomponent silica glass based optical fiber performs. J Non Cryst Solids 410, 8287.
Waseda, Y., Matsubara, E. & Shinoda, K. (2011). X-Ray Diffraction Crystallography. Heidelberg: Springer.
Zlenko, A.S., Mashinsky, V.M., Iskhakova, L.D., Ermakov, R.P., Semjonov, S.L. & Koltashev, V.V. (2013). Spectral behaviour of bismuth centres in different steps of the FCVD process. Quantum Electron 43, 656665.
Zlenko, A.S., Mashinsky, V.M., Iskhakova, L.D., Semjonov, S.L., Koltashev, V.V., Karatun, N.M. & Dianov, E.M. (2012). Mechanisms of optical losses in Bi:SiO2 glass fibers. Opt Express 20(21), 2318623200.

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Identification of Nanocrystalline Inclusions in Bismuth-Doped Silica Fibers and Preforms

  • Liudmila D. Iskhakova (a1), Filipp O. Milovich (a1) (a2), Valery M. Mashinsky (a1), Alexander S. Zlenko (a1), Sergey E. Borisovsky (a3) and Evgeny M. Dianov (a1)...

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