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 This work was supported by: L.R.P. National Institutes of Health (NIH) F32 fellowship award F32EB021859, Army Research Office award W911NF-15-1-0189, NSF grant ACI-1053575, Department of Energy (DoE) Contract DE-AC02-05CH11231. A portion of this work was performed using the Environmental Molecular Sciences Laboratory (EMSL), located at Pacific Northwest National Laboratory (PNNL), under EMSL user proposal no. 49590. PNNL is operated by Battelle 454 for DOE under contract DE-AC05-76RL01830. A portion of this work was performed at the EPIC facility at Northwestern University's NUANCE Center supported by NSF awards ECCS-1542205 and DMR-1121262, the International Institute for Nanotechnology (IIN), the Keck Foundation; and the State of Illinois.