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Atomic-scale Insights of Cation Diffusion into Multivalent Battery Cathodes

Published online by Cambridge University Press:  30 July 2021

Prakash Parajuli
Affiliation:
University of Illinois at Chicago, Chicago, Illinois, United States
Bob Jin Kwon
Affiliation:
Argonne National Laboratory, Lement, Illinois, United States
Sanghyeon Kim
Affiliation:
Argonne National Laboratory, Lement, Illinois, United States
Baris Key
Affiliation:
Argonne National Laboratory, Lement, Illinois, United States
John Vaughey
Affiliation:
Argonne National Laboratory, Lement, Illinois, United States
Robert Klie
Affiliation:
University of Illinois at Chicago, Chicago, Illinois, United States

Abstract

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Type
Microscopy & Spectroscopy of Energy Conversion and Storage Materials
Copyright
Copyright © The Author(s), 2021. Published by Cambridge University Press on behalf of the Microscopy Society of America

References

Canepa, P. et al. Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges. Chem. Rev. (2017).Google ScholarPubMed
Kwon, B. J. et al. High Voltage Mg-Ion Battery Cathode via a Solid Solution Cr-Mn Spinel Oxide. Chem. Mater. 32, (2020).CrossRefGoogle Scholar
Kim, S. et al. High-Voltage Phosphate Cathodes for Rechargeable Ca-Ion Batteries. ACS Energy Lett. 5, (2020).CrossRefGoogle Scholar
Okamoto, S. et al. Intercalation and Push-Out Process with Spinel-to-Rocksalt Transition on Mg Insertion into Spinel Oxides in Magnesium Batteries. Adv. Sci. 2, 1500072 (2015).CrossRefGoogle ScholarPubMed
Parajuli, P. et al. Direct Observation of Electron Beam-Induced Phase Transition in MgCrMnO4. Chem. Mater. 32, 1045610462 (2020).CrossRefGoogle Scholar
This work was supported by the Joint Center for Energy Storage Research (JCESR), an Energy Innovation Hub funded by the U.S. Department of Energy, Basic Energy Sciences.Google Scholar