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Atom Probe Study of 1-Octadecanethiol Self-Assembled Monolayers on Platinum (111) and (200) Surfaces

Published online by Cambridge University Press:  07 September 2021

Helena Solodenko*
Institute for Materials Science, Chair of Materials Physics, University of Stuttgart, Heisenbergstr. 3, 70569 Stuttgart, Germany
Patrick Stender
Institute for Materials Science, Chair of Materials Physics, University of Stuttgart, Heisenbergstr. 3, 70569 Stuttgart, Germany
Guido Schmitz
Institute for Materials Science, Chair of Materials Physics, University of Stuttgart, Heisenbergstr. 3, 70569 Stuttgart, Germany
*Corresponding author: Helena Solodenko, E-mail:
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Atom probe tomography measurements of self-assembled monolayers of 1-octadecanethiol on platinum tips were performed and their fragmentation behavior under the influence of different laser powers was investigated. The carbon backbone evaporates in the form of small hydrocarbon fragments consisting of one to four carbon atoms, while sulfur evaporates exclusively as single ions. The carbon molecules evaporate at very low fields of 5.9 V/nm, while S requires a considerably higher evaporation field of 23.4 V/nm. With increasing laser power, a weak, but noticeable trend toward larger fragment sizes is observed. No hydrocarbon fragments containing S are detected, indicating that a strong S–Pt bond has formed. The observed surface coverage of S fits well with literature values and is higher for (111)-oriented samples than for (200).

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Copyright © The Author(s), 2021. Published by Cambridge University Press on behalf of the Microscopy Society of America

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