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Note on the method of molecular orbitals

  • C. A. Coulson (a1) and G. S. Rushbrooke (a1)

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It is shown that the usual molecular orbital treatment for the mobile electrons in unsaturated hydrocarbon molecules is not always satisfactory, since it does not yield a self-consistent field. The conditions under which the field is self-consistent are analysed, and are shown to be satisfied in many cases.

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(1)Lennard-Jones, and Coulson, . Trans. Faraday Soc. 35 (1939), 811.
(2)Hückel, E.Int. Conf. Phys. Physical Society, London (1935), p. 1.
(3)Lennnard-Jones, . Proc. Roy. Soc. A, 158 (1937), 280.
(4)Coulson, . Proc. Roy. Soc. A, 169 (1939), 413.
(5)Wheland, . Proc. Roy. Soc. A, 164 (1938), 397.

Note on the method of molecular orbitals

  • C. A. Coulson (a1) and G. S. Rushbrooke (a1)

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