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Thermochemistry of volatile metal hydroxides and oxyhydroxides at elevated temperatures

Published online by Cambridge University Press:  30 January 2019

Dwight L. Myers Open the ORCID record for Dwight L. Myers [Opens in a new window] ,
Nathan S. Jacobson Open the ORCID record for Nathan S. Jacobson [Opens in a new window] ,
Charles W. Bauschlicher Jr. Open the ORCID record for Charles W. Bauschlicher Jr. [Opens in a new window]  and
Elizabeth J. Opila
Dwight L. Myers
Affiliation:
Department of Chemistry and Physics, East Central University, Ada, Oklahoma 74820, USA
Nathan S. Jacobson*
Affiliation:
Materials and Structures Division, NASA Glenn Research Center, Cleveland, Ohio 44135, USA
Charles W. Bauschlicher Jr.
Affiliation:
Thermal Protection Materials Branch, NASA Ames Research Center, Moffett Field, California 94035, USA
Elizabeth J. Opila
Affiliation:
Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904, USA
*
a)Address all correspondence to this author. e-mail: Nathan.S.Jacobson@nasa.gov
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Abstract

A principal mode of corrosion in combustion or fuel cell environments is the formation of volatile hydroxides and oxyhydroxides from metal or oxide surfaces at high temperatures. It is important to determine the degree of volatility and accurate thermodynamic properties for these hydroxides. Significant gaseous metal hydroxides/oxyhydroxides are discussed, along with available experimental and theoretical methods of characterizing species and determining their thermodynamic properties.

Keywords

oxidewatervapor pressure
Type
Invited Review
Information
Journal of Materials Research , Volume 34 , Issue 3: Focus Issue: Understanding Water-Oxide Interfaces to Harness New Processes and Technologies , 14 February 2019 , pp. 394 - 407
Copyright
Copyright © Materials Research Society 2019 

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Footnotes

This section of Journal of Materials Research is reserved for papers that are reviews of literature in a given area.

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