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Synthesis and properties of Tl–Ba–Ca–Cu–O superconductors

Published online by Cambridge University Press:  31 January 2011

M. P. Siegal ,
E. L. Venturini ,
B. Morosin  and
T. L. Aselage
M. P. Siegal
Affiliation:
Sandia National Laboratories, Albuquerque, New Mexico 87185–1421
E. L. Venturini
Affiliation:
Sandia National Laboratories, Albuquerque, New Mexico 87185–1421
B. Morosin
Affiliation:
Sandia National Laboratories, Albuquerque, New Mexico 87185–1421
T. L. Aselage
Affiliation:
Sandia National Laboratories, Albuquerque, New Mexico 87185–1421
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Abstract

We review the synthesis methods and properties of single crystal, powder, and thin film TlBaCaCuO high-temperature superconducting (Tl-HTS) materials. With transition temperatures ≥ 100 K for several compounds, Tl-HTS materials present real opportunities for applications above 77 K. Experiments using (1) single crystals: determined precise structural parameters and identified the complex Tl1+–Tl3+ equilibrium model; (2) powders: studied the complex thermodynamic phase diagram; and (3) epitaxial films: studied fundamental properties such as electron pair symmetry and the effect of controlled extrinsic defects on flux pinning strength, as well as providing the large-area surfaces required for device applications.

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Journal of Materials Research , Volume 12 , Issue 11 , November 1997 , pp. 2825 - 2854
Copyright
Copyright © Materials Research Society 1997

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