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Synthesis and properties of Tl–Ba–Ca–Cu–O superconductors

  • M. P. Siegal (a1), E. L. Venturini (a1), B. Morosin (a1) and T. L. Aselage (a1)

Abstract

We review the synthesis methods and properties of single crystal, powder, and thin film TlBaCaCuO high-temperature superconducting (Tl-HTS) materials. With transition temperatures ≥ 100 K for several compounds, Tl-HTS materials present real opportunities for applications above 77 K. Experiments using (1) single crystals: determined precise structural parameters and identified the complex Tl1+–Tl3+ equilibrium model; (2) powders: studied the complex thermodynamic phase diagram; and (3) epitaxial films: studied fundamental properties such as electron pair symmetry and the effect of controlled extrinsic defects on flux pinning strength, as well as providing the large-area surfaces required for device applications.

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Synthesis and properties of Tl–Ba–Ca–Cu–O superconductors

  • M. P. Siegal (a1), E. L. Venturini (a1), B. Morosin (a1) and T. L. Aselage (a1)

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