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Synthesis and nitrogen stability of ultrafine titanium carbonitride particles

Published online by Cambridge University Press:  03 March 2011

Dong-Won Lee ,
Jae-Hwan Ahn  and
Hyungsik Chung
Dong-Won Lee*
Affiliation:
Powder Materials Center, Korea Institute of Machinery and Materials (KIMM), Changwon, Kyungnam 641-010, Korea
Jae-Hwan Ahn
Affiliation:
Division of Chemical & Materials Engineering, Ajou University, Suwon, Kyoungki 443-749, Korea
Hyungsik Chung
Affiliation:
Division of Chemical & Materials Engineering, Ajou University, Suwon, Kyoungki 443-749, Korea
*
a) Address all correspondence to this author. e-mail: ldw1623@kmail.kimm.re.kr
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Abstract

The ultrafine titanium carbonitride particles (TiC0.5N0.5) with 100 nm in mean size was successfully synthesized by nitridation treatment at ordinary temperatures, 1373∼1473 K of the nanostructured half-stoichiometric titanium carbide (TiC0.5) particles, which were produced by the magnesium reduction of gaseous TiCl4+1/4C2Cl4. In addition, the nitrogen stability for the produced titanium carbonitride particles at various temperatures and vacuum conditions was investigated experimentally and compared with values calculated by an ideal solution model.

Keywords

Chemical synthesisNanostructurePowder
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 1 , January 2007 , pp. 233 - 237
Copyright
Copyright © Materials Research Society 2007

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References

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