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Synthesis and characterization of a novel layered titanium phosphate

Published online by Cambridge University Press:  31 January 2011

Anatoly I. Bortun ,
Lyudmila Bortun ,
Abraham Clearfield ,
María A. Villa-García ,
José R. García  and
Julio Rodríguez
Anatoly I. Bortun
Affiliation:
Department of Chemistry, Texas A/M University, College Station, Texas 77843
Lyudmila Bortun
Affiliation:
Department of Chemistry, Texas A/M University, College Station, Texas 77843
Abraham Clearfield
Affiliation:
Department of Chemistry, Texas A/M University, College Station, Texas 77843
María A. Villa-García
Affiliation:
Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
José R. García
Affiliation:
Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
Julio Rodríguez
Affiliation:
Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
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Abstract

A novel metastable layered titanium phosphate has been synthesized by the treatment of layered titanates (Na2Ti3O7 and Na4Ti9O20) with 1–2 M phosphoric acid solution at 120–150 °C. Based on the data of 31P MAS NMR and IR spectroscopy, x-ray powder diffraction, and thermal and elemental analysis, the formula Ti2O3(H2PO4)2 · 2H2O was assigned to the novel compound. The layered nature of the compound was confirmed from n-alkylamine intercalation and the ion exchange behavior toward alkali, alkaline earth, and some transition metal ions.

Type
Articles
Information
Journal of Materials Research , Volume 11 , Issue 10 , October 1996 , pp. 2490 - 2498
Copyright
Copyright © Materials Research Society 1996

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