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Structural and optical properties of graphene from green carbon source via thermal chemical vapor deposition

Published online by Cambridge University Press:  14 June 2016

M.J. Salifairus ,
S.B. Abd Hamid ,
T. Soga ,
Salman A.H. Alrokayan ,
Haseeb A. Khan  and
M. Rusop
M.J. Salifairus*
Affiliation:
NANO-SciTech Centre, Institute of Science, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia; Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia; and NANO-ElecTronic Centre, Faculty of Electrical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia
S.B. Abd Hamid
Affiliation:
Nanotechnology & Catalysis Research Centre, University of Malaya, 50603 Kuala Lumpur, Malaysia
T. Soga
Affiliation:
Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, Aichi, 466-8555Japan
Salman A.H. Alrokayan
Affiliation:
Research Chair for Biomedical Applications of Nanomaterials, Department of Biochemistry, College of Science, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
Haseeb A. Khan
Affiliation:
Research Chair for Biomedical Applications of Nanomaterials, Department of Biochemistry, College of Science, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
M. Rusop*
Affiliation:
NANO-SciTech Centre, Institute of Science, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia; and NANO-ElecTronic Centre, Faculty of Electrical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia
*
a)Address all correspondence to these authors. e-mail: salifairus_mj85@yahoo.co.uk
b)e-mail: nanouitm@gmail.com
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Abstract

Graphene is a 2D carbon allotrope that has attracted significant attention because its properties have a wide range of applications. Graphene was deposited on the polycrystalline nickel substrate with a dimension of 0.10 mm × 10 mm × 10 mm via thermal chemical vapor deposition (TCVD). The natural carbon source was obtained from a commercial palm oil as a carbon precursor. The D, G, and 2D bands described the vibration of graphitic layer and overtone of the D band at 1352, 1594, and 2716 cm−1, respectively. The lowest G band full width at half maximum (FWHM) was 38.7 cm−1 at 900 °C deposition temperature. In the x-ray diffraction (XRD) pattern, the FWHM of Ni (200) peak was 0.38°. Raman spectroscopy, UV–vis spectrophotometry, atomic force microscopy, XRD, and field emission scanning electron microscopy characterized the synthesized graphene. Multilayer graphene was successfully synthesized from the palm oil via TCVD.

Keywords

graphenepalm oilchemical vapor deposition (deposition)
Type
Invited Articles
Information
Journal of Materials Research , Volume 31 , Issue 13: Focus Issue: Advances and Challenges in Carbon-based Tribomaterials , 14 July 2016 , pp. 1947 - 1956
Copyright
Copyright © Materials Research Society 2016 

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