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Stability of shear banding process in bulk metallic glasses and composites

  • Yusheng Qin (a1), Xiaoliang Han (a1), Kaikai Song (a1), Li Wang (a1), Yun Cheng (a1), Zequn Zhang (a1), Qisen Xue (a1), Nianzhen Sun (a1), Jianguo Wang (a2), Baoan Sun (a3), Baran Sarac (a4), Florian Spieckermann (a5), Gang Wang (a6), Ivan Kaban (a7) and Jürgen Eckert (a5)...

Abstract

The shear-band propagation in bulk metallic glasses (BMGs) during deformation plays a key role in determining their macroscopic ductility. In this work, the shear band propagation during plastic deformation was investigated in the Cu46Zr46Al8 BMG and its in situ or ex situ prepared BMG composites. Compared with the brittle BMG, both types of ductile BMG composites show a more stable shear banding behavior as revealed by a larger power-law scaling exponent obtained from statistical analysis of serrations recorded in compressive curves. A higher cut-off elastic energy density (δc) linked with the multiplication of shear bands is observed for the in situ prepared BMG composites. However, the ex situ fabricated BMG composites show an almost equivalent or slightly larger δc since the dominant shear band but not multiple shear bands mainly governs their deformation. Such observations imply that the shear banding stability of BMGs during deformation is enhanced not only by inducing multiple shear bands but also by obstructing the movement of the dominant shear band at its driven path.

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a) Address all correspondence to these authors. e-mail: songkaikai8297@gmail.com

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c)

This author was an editor of this journal during the review and decision stage. For the JMR policy on review and publication of manuscripts authored by editors, please refer to http://www.mrs.org/editor-manuscripts/.

Contributing Editor: Mathias Göken

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References

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1. Eckert, J., Das, J., Pauly, S., and Duhamel, C.: Mechanical properties of bulk metallic glasses and composites. J. Mater. Res. 22, 285301 (2007).
2. Cheng, Y.Q. and Ma, E.: Atomic-level structure and structure-property relationship in metallic glasses. Prog. Mater. Sci. 56, 379473 (2011).
3. Thurnheer, P., Maaß, R., Laws, K.J., Pogatscher, S., and Löffler, J.F.: Dynamic properties of major shear bands in Zr–Cu–Al bulk metallic glasses. Acta Mater. 96, 428436 (2015).
4. Johnson, W.L.: Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 24, 4256 (1999).
5. Sun, B.A. and Wang, W.H.: The fracture of bulk metallic glasses. Prog. Mater. Sci. 74, 211307 (2015).
6. Greer, A.L., Cheng, Y.Q., and Ma, E.: Shear bands in metallic glasses. Mater. Sci. Eng., R 74, 71132 (2013).
7. Schuh, C.A., Hufnagel, T.C., and Ramamurty, U.: Mechanical behavior of amorphous alloys. Acta Mater. 55, 40674109 (2007).
8. Lewandowski, J.J., Wang, W.H., and Greer, A.L.: Intrinsic plasticity or brittleness of metallic glasses. Philos. Mag. Lett. 85, 7787 (2005).
9. Tan, J., Zhang, Y., Sun, B.A., Stoica, M., Li, C.J., Song, K.K., Kühn, U., Pan, F.S., and Eckert, J.: Correlation between internal states and plasticity in bulk metallic glass. Appl. Phys. Lett. 98, 151906–151903 (2011).
10. Klaumünzer, D., Maaß, R., and Löffler, J.F.: Stick-slip dynamics and recent insights into shear banding in metallic glasses. J. Mater. Res. 26, 14531463 (2011).
11. Scudino, S., Surreddi, K.B., Wang, G., and Eckert, J.: Enhanced plastic deformation of Zr41.2Ti13.8Cu12.5Ni10Be22.5 bulk metallic glass by the optimization of frictional boundary restraints. Scr. Mater. 62, 750753 (2010).
12. Wu, W.F., Li, Y., and Schuh, C.A.: Strength, plasticity and brittleness of bulk metallic glasses under compression: Statistical and geometric effects. Philos. Mag. 88, 7189 (2008).
13. Li, J.J., Qiao, J.W., Dahmen, K.A., Yang, W.M., Shen, B.L., and Chen, M.W.: Universality of slip avalanches in a ductile Fe-based bulk metallic glass. J. Iron Steel Res. Int. 24, 366371 (2017).
14. Wang, Z., Qiao, J.W., Tian, H., Sun, B.A., Wang, B.C., Xu, B.S., and Chen, M.W.: Composition mediated serration dynamics in Zr-based bulk metallic glasses. Appl. Phys. Lett. 107, 201902 (2015).
15. Thurnheer, P., Haag, F., and Löffler, J.F.: Time-resolved measurement of shear-band temperature during serrated flow in a Zr-based metallic glass. Acta Mater. 115, 468474 (2016).
16. Qu, R.T., Liu, Z.Q., Wang, G., and Zhang, Z.F.: Progressive shear band propagation in metallic glasses under compression. Acta Mater. 91, 1933 (2015).
17. Qiao, J.C., Yao, Y., Pelletier, J.M., and Keer, L.M.: Understanding of micro-alloying on plasticity in Cu46Zr47−x Al7Dy x (0 ≤ x ≤ 8) bulk metallic glasses under compression: Based on mechanical relaxations and theoretical analysis. Int. J. Plast. 82, 6275 (2016).
18. Liu, Y.H., Wang, G., Wang, R.J., Zhao, D.Q., Pan, M.X., and Wang, W.H.: Super plastic bulk metallic glasses at room temperature. Science 315, 13851388 (2007).
19. Sun, B.A., Yu, H.B., Jiao, W., Bai, H.Y., Zhao, D.Q., and Wang, W.H.: Plasticity of ductile metallic glasses: A self-organized critical state. Phys. Rev. Lett. 105, 035501 (2010).
20. Sun, B.A., Pauly, S., Hu, J., Wang, W.H., Kühn, U., and Eckert, J.: Origin of intermittent plastic flow and instability of shear band sliding in bulk metallic glasses. Phys. Rev. Lett. 110, 225501 (2013).
21. Schroers, J. and Johnson, W.L.: Ductile bulk metallic glass. Phys. Rev. Lett. 93, 255506 (2004).
22. Kajiwara, S.: Characteristic features of shape memory effect and related transformation behavior in Fe-based alloys. Mater. Sci. Eng., A 273–275, 6788 (1999).
23. Song, K.K., Pauly, S., Sun, B.A., Tan, J., Stoica, M., Kühn, U., and Eckert, J.: Correlation between the microstructures and the deformation mechanisms of CuZr-based bulk metallic glass composites. AIP Adv. 3, 012116012118 (2013).
24. Pauly, S., Das, J., Bednarčik, J., Mattern, N., Kim, K.B., Kim, D.H., and Eckert, J.: Deformation-induced martensitic transformation in Cu–Zr–(Al,Ti) bulk metallic glass composites. Scr. Mater. 60, 431434 (2009).
25. Qiao, J.W., Jia, H.L., and Liaw, P.K.: Metallic glass matrix composites. Mater. Sci. Eng., R 100, 169 (2016).
26. Todinov, M.T.: Influence of some parameters on the residual stresses from quenching. Modell. Simul. Mater. Sci. Eng. 7, 2541 (1999).
27. Song, K.K., Wu, D.Y., Pauly, S., Peng, C.X., Wang, L., and Eckert, J.: Thermal stability of B2 CuZr phase, microstructural evolution and martensitic transformation in Cu–Zr–Ti alloys. Intermetallics 67, 177184 (2015).
28. Wu, D.Y., Song, K.K., Cao, C.D., Li, R., Wang, G., Wu, Y., Wan, F., Ding, F.L., Shi, Y., Bai, X.J., Kaban, I., and Eckert, J.: Deformation-induced martensitic transformation in Cu–Zr–Zn bulk metallic glass composites. Metals 5, 21342147 (2015).
29. Song, K.K., Pauly, S., Zhang, Y., Li, R., Gorantla, S., Narayanan, N., Kühn, U., Gemming, T., and Eckert, J.: Triple yielding and deformation mechanisms in metastable Cu47.5Zr47.5Al5 composites. Acta Mater. 60, 60006012 (2012).
30. Wang, G., Chan, K.C., Xia, L., Yu, P., Shen, J., and Wang, W.H.: Self-organized intermittent plastic flow in bulk metallic glasses. Acta Mater. 57, 61466155 (2009).
31. Qiao, J.W., Zhang, Y., and Liaw, P.K.: Serrated flow kinetics in a Zr-based bulk metallic glass. Intermetallics 18, 20572064 (2010).
32. Tong, X., Wang, G., Yi, J., Ren, J.L., Pauly, S., Gao, Y.L., Zhai, Q.J., Mattern, N., Dahmen, K.A., Liaw, P.K., and Eckert, J.: Shear avalanches in plastic deformation of a metallic glass composite. Int. J. Plast. 77, 141155 (2016).
33. Pan, X.F., Zhang, H., Zhang, Z.F., Stoica, M., He, G., and Eckert, J.: Vickers hardness and compressive properties of bulk metallic glasses and nanostructure-dendrite composites. J. Mater. Res. 20, 26322638 (2011).
34. Malandro, D.L. and Lacks, D.J.: Relationships of shear-induced changes in the potential energy landscape to the mechanical properties of ductile glasses. J. Chem. Phys. 110, 45934601 (1999).
35. Csikor, F.F., Motz, C., Weygand, D., Zaiser, M., and Zapperi, S.: Dislocation avalanches, strain bursts, and the problem of plastic forming at the micrometer scale. Science 318, 251254 (2007).
36. Zhang, Y., Zuo, T.T., Tang, Z., Gao, M.C., Dahmen, K.A., Liaw, P.K., and Lu, Z.P.: Microstructures and properties of high-entropy alloys. Prog. Mater. Sci. 61, 193 (2014).
37. Argon, A.S.: Plastic deformation in metallic glasses. Acta Metall. 27, 4758 (1979).
38. Spaepen, F.: A microscopic mechanism for steady state inhomogeneous flow in metallic glasses. Acta Metall. 25, 407415 (1977).
39. Falk, M.L. and Langer, J.S.: Dynamics of viscoplastic deformation in amorphous solids. Phys. Rev. E 57, 71927205 (1998).
40. Langer, J.S.: Dynamics of shear-transformation zones in amorphous plasticity: Formulation in terms of an effective disorder temperature. Phys. Rev. E 70, 041502 (2004).
41. Song, S.X., Bei, H., Wadsworth, J., and Nieh, T.G.: Flow serration in a Zr-based bulk metallic glass in compression at low strain rates. Intermetallics 16, 813818 (2008).
42. Chen, M.: Mechanical behavior of metallic glasses: Microscopic understanding of strength and ductility. Annu. Rev. Mater. Res. 38, 445469 (2008).
43. Han, Z. and Li, Y.: Cooperative shear and catastrophic fracture of bulk metallic glasses from a shear-band instability perspective. J. Mater. Res. 24, 36203627 (2011).
44. Liu, Z.Y., Yang, Y., and Liu, C.T.: Critical shear offset of fracture in a Zr-based metallic glass. J. Iron Steel Res. Int. 23, 5356 (2016).
45. Wu, F.F., Zhang, Z.F., and Mao, S.X.: Size-dependent shear fracture and global tensile plasticity of metallic glasses. Acta Mater. 57, 257266 (2009).
46. Dragoi, D., Üstündag, E., Clausen, B., and Bourke, M.A.M.: Investigation of thermal residual stresses in tungsten-fiber/bulk metallic glass matrix composites. Scr. Mater. 45, 245252 (2001).
47. Khaund, A.K., Krstic, V.D., and Nicholson, P.S.: Influence of elastic and thermal mismatch on the local crack-driving force in brittle composites. J. Mater. Sci. 12, 22692273 (1977).
48. Khaund, A.K. and Nicholson, P.S.: Fracture of a brittle composite: Influence of elastic mismatch and interfacial bonding. J. Mater. Sci. 15, 177187 (1980).
49. Fitzpatrick, M.E., Hutchings, M.T., and Withers, P.J.: Separation of macroscopic, elastic mismatch and thermal expansion misfit stresses in metal matrix composite quenched plates from neutron diffraction measurements. Acta Mater. 45, 48674876 (1997).
50. Liu, Z., Li, R., Wang, G., Wu, S., Lu, X., and Zhang, T.: Quasi phase transition model of shear bands in metallic glasses. Acta Mater. 59, 74167424 (2011).
51. Dalla Torre, F.H., Dubach, A., Schällibaum, J., and Löffler, J.F.: Shear striations and deformation kinetics in highly deformed Zr-based bulk metallic glasses. Acta Mater. 56, 46354646 (2008).
52. Lewandowski, J.J. and Greer, A.L.: Temperature rise at shear bands in metallic glasses. Nat. Mater. 5, 1518 (2006).
53. Sun, B.A., Pauly, S., Tan, J., Stoica, M., Wang, W.H., Kühn, U., and Eckert, J.: Serrated flow and stick-slip deformation dynamics in the presence of shear-band interactions for a Zr-based metallic glass. Acta Mater. 60, 41604171 (2012).
54. Koval, Y.N., Firstov, G.S., and Kotko, A.V.: Martensitic-transformation and shape memory effect in ZrCu intermetallic compound. Scr. Metall. Mater. 27, 16111616 (1992).
55. Gunkelmann, N., Bringa, E.M., Kang, K., Ackland, G.J., Ruestes, C.J., and Urbassek, H.M.: Polycrystalline iron under compression: Plasticity and phase transitions. Phys. Rev. B 86, 27332737 (2012).
56. Ahlers, M., Pascual, R., Rapacioli, R., and Arneodo, W.: Transformation hardening and energy dissipation in martensitic β-brass. Mater. Sci. Eng. 27, 4955 (1977).
57. Planes, A., Macqueron, J.L., and Ortín, J.: Energy contributions in the martensitic transformation of shape-memory alloys. Philos. Mag. Lett. 57, 291298 (1988).
58. Boyd, J.G. and Lagoudas, D.C.: A thermodynamical constitutive model for shape memory materials. Part I. The monolithic shape memory alloy. Int. J. Plast. 12, 805842 (1996).
59. Sun, B.A., Chen, S.H., Lu, Y.M., Zhu, Z.G., Zhao, Y.L., Yang, Y., Chan, K.C., and Liu, C.T.: Origin of shear stability and compressive ductility enhancement of metallic glasses by metal coating. Sci. Rep. 6, 27852 (2016).
60. Qiu, K.Q., Wang, A.M., Zhang, H.F., Ding, B.Z., and Hu, Z.Q.: Mechanical properties of tungsten fiber reinforced ZrAlNiCuSi metallic glass matrix composite. Intermetallics 10, 12831288 (2002).
61. Conner, R.D., Dandliker, R.B., and Johnson, W.L.: Mechanical properties of tungsten and steel fiber reinforced Zr41.25Ti13.75Cu12.5Ni10Be22.5 metallic glass matrix composites. Acta Mater. 46, 60896102 (1998).
62. Lee, S.Y., Clausen, B., Üstündag, E., Choi-Yim, H., Aydiner, C.C., and Bourke, M.A.M.: Compressive behavior of wire reinforced bulk metallic glass matrix composites. Mater. Sci. Eng., A 399, 128133 (2005).

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