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Self-propagating high-temperature synthesis of nano-sized titanium carbide powder

Published online by Cambridge University Press:  31 January 2011

H. H. Nersisyan ,
J. H. Lee  and
C. W. Won
H. H. Nersisyan
Affiliation:
Rapidly Solidified Materials Research Center (RASOM), Chungnam National University, Yuseong, Daejeon, 305–764, South Korea
J. H. Lee
Affiliation:
Rapidly Solidified Materials Research Center (RASOM), Chungnam National University, Yuseong, Daejeon, 305–764, South Korea
C. W. Won
Affiliation:
Rapidly Solidified Materials Research Center (RASOM), Chungnam National University, Yuseong, Daejeon, 305–764, South Korea
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Abstract

The combustion process of a titanium–carbon system with sodium chloride as an inert diluent was investigated. The combustion laws and microstructure of final products according to diluent content were obtained. It was shown that sodium chloride not only decreases combustion temperature but also makes effective protective shells around primary carbide crystals and keeps this ultrafine structure up to the end of combustion. As a result, nano-sized titanium carbide powders were successfully obtained.

Type
Articles
Information
Journal of Materials Research , Volume 17 , Issue 11 , November 2002 , pp. 2859 - 2864
Copyright
Copyright © Materials Research Society 2002

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References

REFERENCES

1.Storms, E., Refractory Carbides (Atomizdat, Moscow, USSR, 1970).Google Scholar
2.Merzhanov, A.G., in Combustion and Plasma Synthesis of High-Temperature Materials, edited by Munir, Z.A. and Holt, J.B. (VCH, New York, 1990), pp. 1–53.Google Scholar
3.Merzhanov, A.G., Int. J. SHS 4, 323 (1995).Google Scholar
4.Hlavacek, V., Am. Ceram. Soc. Bull. 69, 537 (1990).Google Scholar
5.Munir, Z.A. and Anselmi, U.-Tamburini, Mater. Sci. Reports 69, 277 (1989).CrossRefGoogle Scholar
6.Holt, J.B. and Dunmead, S.D., Annual. Rev. Mater. Sci. 21, 305 (1991).CrossRefGoogle Scholar
7.Miyamoto, Y., J. Mineral. Soc. Jpn. 18, 383 (1988).Google Scholar
8.Moore, J.J. and Feng, H.J., Progr. Mater. Sci. 39, 243 (1995).CrossRefGoogle Scholar
9.Shkiro, V.M. and Borovinskaya, I.P., in Combustion Processes in Chemical Technology and Metallurgy (Chernogolovka, 1975), pp. 253–258.Google Scholar
10.Shkiro, V.M. and Borovinskaya, I.P., Fizika Goreniya i Vzriva 12, 945 (1976).Google Scholar
11.Halverson, D.C., Ewald, K.H., and Munir, Z.A., J. Mater. Sci. 28, 4583 (1993).CrossRefGoogle Scholar
12.Halverson, D.C., Ewald, K.H., and Munir, Z.A., J. Mater. Sci. 30, 3697 (1995).CrossRefGoogle Scholar
13.Merzhanov, A.G. and Rogachev, A.S., Pure Appl. Chem. 64, 941 (1992).CrossRefGoogle Scholar
14.Nersisyan, H.H. and Kharatyan, S.L., Int. J. SHS 4, 159 (1995).Google Scholar
15.Kharatyan, S.L. and Nersisyan, H.H., in Progress of SHS Facing a New Millenium (1st Sino-Russian Workshop on SHS, Beijing, China, 2000), p. 96.Google Scholar
16.Shiryaev, A.A., Int. J. SHS 4, 351 (1995).Google Scholar