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Second harmonic generation from CsLiB6O10-containing glass-ceramics

  • Yoshitsugu Yamamoto (a1), Tomohiro Hashimoto (a1), Hiroyuki Nasu (a1), Tadanori Hashimoto (a1) and Kanichi Kamiya (a1)...

Abstract

Glass-ceramics containing ferroelectric CsLiB6O10 crystals were prepared by heat treating Cs2O–Li2O–B2O3 glasses. Second harmonic generation (SHG) was observed from samples prepared by two-step heat treatment (nucleation and growth); however, the intensity was rather weak. On the other hand, one-step heat treatment by the addition of a small amount of TiO2 to the glass resulted in the glass-ceramics containing small single crystal-like CsLiB6O10 particles. The strongest SHG observed was comparable with that of Y-cut quartz. The preferred orientation of precipitated CsLiB6O10 crystals was attributed to the occurrence of SHG from the glass-ceramics.

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a)Address all correspondence to this author.glass@chem.mie-u.ac.jp

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Second harmonic generation from CsLiB6O10-containing glass-ceramics

  • Yoshitsugu Yamamoto (a1), Tomohiro Hashimoto (a1), Hiroyuki Nasu (a1), Tadanori Hashimoto (a1) and Kanichi Kamiya (a1)...

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