Hostname: page-component-8448b6f56d-gtxcr Total loading time: 0 Render date: 2024-04-18T22:50:19.357Z Has data issue: false hasContentIssue false

Reactive-infiltration processing of SiC-metal and SiC-intermetallic composites

Published online by Cambridge University Press:  31 January 2011

Leszek Hozer
Affiliation:
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
Yet-Ming Chiang
Affiliation:
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
Get access

Abstract

Liquid-phase reactive infiltration is a rapid and net-shape method of synthesizing silicon carbide composites. We use reactive infiltration of carbon with Si–A1 and Si–Cu melts to prepare composites consisting of interpenetrating networks of β–SiC and a secondary phase assemblage containing ductile metal (A1–Si) or a metal silicide (Si–Cu). The mechanisms of phase formation have been characterized. It is shown that a rapid initial reaction upon infiltration forms a largely stationary SiC network, within which the secondary phase constitution evolves due to solute rejection and liquid phase diffusion processes. Both homogeneous composites and those with controlled composition gradients have been synthesized.

Type
Articles
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Hozer, L., Lee, J-R., and Chiang, Y-M., Mater. Sci. Eng. A 195, 131 (1995).CrossRefGoogle Scholar
2.Popper, P., in Special Ceramics (Heywood, London, 1960), p. 209.Google Scholar
3.Forrest, C. W., Kennedy, P., and Shennan, J. V., in Special Ceramics, edited by Popper, P. (British Ceramic Research Association, Stoke-on-Trent, 1972), Vol. 5, p. 99.Google Scholar
4.Hillig, W. B., Mehan, R. L., Morelock, C. R., DeCarlo, V. J., and Laskow, W., Am. Ceram. Soc. Bull. 54, 1054 (1975).Google Scholar
5.Hucke, E. E., U.S. Patent No. 3 235 346, Feb. 15 (1966).Google Scholar
6.Hucke, E. E., AMMRC Tech. Rept. TR 83-5 (U.S. Army Materials and Mechanics Research Center, January 1983).Google Scholar
7.Messner, R. P. and Chiang, Y-M., Ceram. Eng. Sci. Proc. 9, 1052 (1988).Google Scholar
8.Messner, R. P. and Chiang, Y-M., J. Am. Ceram. Soc. 73. 1193 (1990).CrossRefGoogle Scholar
9.Chiang, Y-M., Messner, R. P., Terwilliger, C. D., and Behrendt, D. R., Mater. Sci. Eng. A 144, 63 (1991).CrossRefGoogle Scholar
10.Hozer, L., Lee, J-R., and Chiang, Y-M., in Advanced Synthesis and Processing of Composites and Advanced Ceramics, edited by Logan, K. V., Munir, Z. A., and Spriggs, R. M. (Ceram. Trans. 56, The American Ceramic Society, Westerville, OH, 1995), p. 158.Google Scholar
11.Handwerker, C. A., Vaudin, M. D., Kattner, U. R., and Lee, D-J., in Metal-Ceramic Interfaces, edited by Ruhle, M., Evans, A. G., Ashby, M. F., and Hirth, J. P. (Acta-Scripta Metall. Proc. Series 4, Pergamon Press, Oxford, 1989), and private communication.Google Scholar
12.Warren, R. and Andersson, C-H., Composites 15, 101 (1984).CrossRefGoogle Scholar
13.Zweben, C., JOM 44 (July), 15 (1992).CrossRefGoogle Scholar
14.Shen, Y-L., Needleman, A., and Suresh, S., Metall. Mater. Trans. A 25, 839 (1994).CrossRefGoogle Scholar
15.Constant, K., Lee, J-R., and Chiang, Y-M., J. Mater. Res. 11, 2338 (1996).CrossRefGoogle Scholar
16.Binary alloy phase diagrams, 2nd ed., Massalski, T. B. (editor in chief), (ASM INTERNATIONAL, Materials Park, OH, 1990), pp. 212 (A1–Si) and 1478 (Cu–Si).Google Scholar
17.Delannay, F., Froyen, L., and Deruyttere, A., J. Mater. Sci. 22, 1 (1987).CrossRefGoogle Scholar
18.Mori, N., Sorano, H., Kitahara, A., Ogi, K., and Matsuda, K., J. Jpn. Metal. 47, 1132 (1983).Google Scholar
19.Nakae, H., Yamamoto, K., and Sato, K., Mater. Trans. JIM 32, 531 (1991).CrossRefGoogle Scholar
20.Naidich, J. V., Prog. Surf. 14, 353 (1981).CrossRefGoogle Scholar
21.Li, J. G., J. Mater. Sci. Lett. 11, 1551 (1992).CrossRefGoogle Scholar
22.Humenik, M. and Kinergy, W.D., J. Am. Ceram. Soc. 37, 18 (1954).CrossRefGoogle Scholar
23.Nogi, K. and Ogino, K., Trans. Jpn. Inst. Metals 29, 742 (1988).CrossRefGoogle Scholar
24.Li, J. G. and Hausner, H., Mater. Lett. 14, 329 (1992).CrossRefGoogle Scholar
25.Phase equilibria diagrams, Phase diagrams for ceramists, Vol. X, Borides, Carbides, and Nitrides, edited by McHale, A. E. (The American Ceramic Society, Westerville, OH, 1994).Google Scholar