Hostname: page-component-7bb8b95d7b-cx56b Total loading time: 0 Render date: 2024-09-20T16:26:39.806Z Has data issue: false hasContentIssue false

Pentacene transistors with polymer gate dielectrics on metallized optical fibers

Published online by Cambridge University Press:  01 December 2004

Jimmy Granstrom
Affiliation:
Bell Laboratories, Lucent Technologies, Murray Hill, New Jersey 07974
Howard E. Katz*
Affiliation:
Bell Laboratories, Lucent Technologies, Murray Hill, New Jersey 07974
*
a)Address all correspondence to this author.e-mail: hek@lucent.com
Get access

Abstract

It is difficult to deposit a very thin polymer layer onto a fiber-shaped substrate from solution because the high interfacial energy can lead to dewetting. This difficulty presents itself when attempting to apply a gate dielectric to conductive fiber substrates during the fabrication of fiber transistors for use in applications such as “electrotextiles” and optical switches. In this article, we present a dip coating process that applies a gate dielectric to metal-coated optical fibers with high uniformity and reproducibility, resulting in pentacene field-effect transistors with excellent transistor characteristics including mobilities up to 0.4 cm2/Vs and on/off ratios up to 7000. In one case, a memory effect was demonstrated. Several gate dielectrics were successfully applied to the optical fibers, suggesting a baseline set of suitable materials for this purpose. A thorough study of the dip coating conditions is presented, including proposed explanations of the effects of different coating procedures and solution physical properties. Finally, alternative architectures that would provide much higher W/L ratios and on-currents are described.

Type
Articles
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Gamota, D.R., Brazis, P., Kalyanasundaram, K. and Zhang, J.: Printed Organic and Molecular Electronics (Kluwer, New York, NY, 2003)Google Scholar
2Kagan, C.R. and Andry, P.: Thin Film Transistors (Marcel Dekker, New York, NY, 2003)CrossRefGoogle Scholar
3Shur, M.S. in Electronics on Unconventional Substrates– Electrotextiles and Giant-Area Flexible Circuits, edited by Shur, M.S., Wilson, P.M., and Urban, D. (Mater. Res. Soc. Symp. Proc. 736, Warrendale, PA, 2003)Google Scholar
4Etheridge, E. and Urban, D.: Electrotextiles (World Scientific Publishing, River Edge, NJ, 2002)CrossRefGoogle Scholar
5Bonderover, E., Wagner, S., and Suo, Z.: Amorphous silicon thin film transistors on kapton fibers, in Electronics on Unconventional Substrates—Electrotextiles and Giant-Area Flexible Circuits, edited by Shur, M.S., Wilson, P.M., and Urban, D. (Mater. Res. Soc. Symp. Proc. 736, Warrendale, PA, 2003), p. 109.Google Scholar
6Lee, J.B. and Subramanian, V.Organic Transistors on Fiber: A first step toward electronic textiles, IEEE IEDM Proceedings (2003). http://organics.eecs.berkeley.edu/pdf/IEDM03.PDFGoogle Scholar
7Eldada, L.: Optical comunication components. Rev. Sci. Instrum. 75, 575 (2004).CrossRefGoogle Scholar
8Hsieh, J., Mach, P., Cattaneo, F., Yang, S., Krupenkine, T., Baldwin, K. and Rogers, J.A.: Tunable microfluidic optical fiber devices based on electrowetting pumps and plastic microchannels. IEEE Photonics Technol. Lett. 15, 81 (2003).CrossRefGoogle Scholar
9Acharya, B.R., Krupenkin, T., Ramachandran, S., Wang, Z., Huang, C.C. and Rogers, J.A.: Tunable optical fiber devices based on broadband long-pieroid gratings and pumped microfluidics. Appl. Phys. Lett. 83, 4912 (2003).CrossRefGoogle Scholar
10Jeong, Y., Kim, H.R., Baek, S., Kim, Y., Lee, Y.W., Lee, S.D. and Lee, B.: Polarization-isolated optical modulation of an etched long-period fiber grating with an outer liquid crystal cladding. Opt. Eng. 42, 964 (2003).CrossRefGoogle Scholar
11Jaroszewicz, L.R., Klosowicz, S.J., Czuprynski, K., Kiezun, A., Nowinowski-Kruszelnicki, E. and Niedziela, T.: Tunable liquid crystal fiber-optical polarizer and related elements. Molecular Cryst. Liquid Cryst. 368, 3785 (2001).CrossRefGoogle Scholar
12Lyons, E.R. and Lee, H.P.: An electrically tunable all-fiber polarization controller based on thin film microheaters. IEEE Photon. Technol. Lett. 14, 1318 (2002).CrossRefGoogle Scholar
13Li, L., Geng, R.X., Zhao, L., Chen, G., Chen, G.T., Fang, Z.J. and Lam, C.F.: Response characteristics of thin-film-heated tunable fiber bragg gratings. IEEE Photon. Technol. Lett. 15, 545 (2003).Google Scholar
14Katz, H.E., Hong, X.M., Dodabalapur, A. and Sarpeshkar, R.: Organic field-effect transistors with polarizable gate insulators. J. Appl. Phys. 91, 1572 (2001).CrossRefGoogle Scholar
15Mushrush, M., Facchetti, A., Lefenfeld, M., Katz, H.E. and Marks, T.J.: Easily processed phenylene-thiophene-based organic field-effect transistors and solution-fabricated nonvolatile transistor memory elements. J. Am. Chem. Soc. 125, 9414 (2003).CrossRefGoogle Scholar
16Knipp, D., Street, R.A. and Volkel, A.R.: Morphology and electronic transport of polycrystalline pentacene thin-film transistors. Appl. Phys. Lett. 82, 3907 (2003).CrossRefGoogle Scholar