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Oxygen semi-permeation properties of La1−xSrxFeO3−δ perovskite membranes under high oxygen gradient

Published online by Cambridge University Press:  28 August 2020

Eva Deronzier ,
Thierry Chartier  and
Pierre-Marie Geffroy
Eva Deronzier*
Affiliation:
IRCER, CNRS, Université de Limoges, CEC, 12 Rue Atlantis, 87068Limoges, France
Thierry Chartier
Affiliation:
IRCER, CNRS, Université de Limoges, CEC, 12 Rue Atlantis, 87068Limoges, France
Pierre-Marie Geffroy
Affiliation:
IRCER, CNRS, Université de Limoges, CEC, 12 Rue Atlantis, 87068Limoges, France
*
a)Address all correspondence to this author. e-mail: eva.deronzier@unilim.fr
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Abstract

This work is focused on the evaluation of oxygen semi-permeation and electrochemical performances under high oxygen gradient of free cobalt perovskite membrane materials; La1−xSrxFeO3−δ perovskite. For a better understanding of oxygen transport through La1−xSrxFeO3−δ perovskite membranes, the oxygen diffusion, oxygen incorporation, and desorption coefficients were determined under high oxygen gradient in relation to the temperature for La1−xSrxFeO3−δ (with x = 0.1, 0.3, 0.5, and 0.7) by a specific method based on oxygen semi-permeation. The best electrochemical performances were obtained for La0.3Sr0.7FeO3−δ (LSF37) and La0.5Sr0.5FeO3−δ (LSF55) perovskite membranes with oxygen fluxes of 1.7 × 10−3 and 1.2 × 10−3 mol/m2 s at 900 °C, respectively. The oxygen incorporation and desorption coefficients of LSF55 were two times lower than those of LSF37 and similar to those of La0.5Sr0.5Fe0.7Ga0.3O3−δ. The values of these coefficients are discussed and compared with the data reported in the literature by isotopic exchange for the similar material compositions.

Keywords

LSF perovskiteoxygen diffusionoxygen desorption coefficient
Type
Article
Information
Journal of Materials Research , Volume 35 , Issue 18 , 28 September 2020 , pp. 2506 - 2515
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Copyright © Materials Research Society 2020

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