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Novel method for the synthesis of thin film coatings on particulate materials

  • J. M. Fitz-Gerald (a1), R. K. Singh (a2), H. Gao (a2), D. Wright (a2), M. Ollinger (a2), J. W. Marcinka (a3) and S. J. Pennycook (a4)...


In this paper, we show the feasibility of the pulsed-laser ablation technique to grow 20–30-nm-thick, discrete and continuous coatings on particulate material systems so that the properties of the core particles can be suitably modified. Experiments were conducted with a pulsed excimer laser (λ = 248 nm, pulse duration = 25 ns) to deposit nanoparticle coatings on Al2O3 and SiO2 core particles by irradiation of Ag and Y2O3–Eu3+ sputtering targets. Structural characterization was performed with scanning electron microscopy, wavelength dispersive x-ray mapping, transmission electron microscopy, and scanning transmission electron microscopy with z-contrast.



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1.Forester, T., The Materials Revolution (MIT Press, Cambridge, 1988).
2.Materials Science & Engineering for the 1990s (National Academy Press, Washington, DC, 1990).
3.US Department of Commerce Annual Report (National Institute of Standards and Technology, Information Technology Laboratory, Gaithersburg, MD, 1992).
4.Ewen, J.A., Scientific American, May, 38 (1997).
5.Glieter, H., Adv. Mater. 4, 474 (1992).
6.Seigel, R.W., Nanostruct. Mater. 4, 121 (1994).
7.Surface-Controlled Nanoscale Materials for High-Added-Value Applications, edited by K.E. Gonsalves, M-I. Baraton, R. Singh, H. Hoffman, J.X. Chen, and J.A. Akkara (Mater. Res. Soc. Symp. Proc. 501, Warrendale, PA, 1998), pp. 1412.
8.Singh, R.K., Ata, A., Fitz-Gerald, J.M., Rabinovich, Y., and Hendrickson, W., Kona, , J. Powder Sci. Technol. 15, 121 (1997).
9.Fitz-Gerald, J., Singh, R.K., Trottier, T. and Holloway, P.H., Appl. Phys. Lett. 72, 15 (1998).
10.Darolia, R., Lahrman, D.F., Field, R.D., and Freeman, A.J., in High Temperature Ordered Intermetallic Alloys III, edited by Liu, C.T., Taub, A.I., Stoloff, N.S. and Koch, C.C. (Mater. Res. Soc. Symp. Proc. 133, Pittsburgh, PA, 1989), p. 113.
11.Kousaka, Y., Endo, Y., Alonso, M., Ichitoubo, H., and Fukui, A., Adv. Powder Technol. 6, 11 (1995).
12.Saito, I. and Senna, M., Kona 13, 191 (1993).
13.Higashitani, K., Yamamura, T., Ishiki, Y., Kage, A., Kondo, A., Kona 12, 119 (1994).
14.Jin, S., Tifel, T.H., McCormack, M., Fastnatch, R.A., Romish, R., and Chen, L.H., Science 264, 413 (1994).
15.Advanced Laser Processing of Materials: Fundamentals and Applications, edited by R.K. Singh, D. Norton, L.D. Laude, J. Narayan, and J. Cheung (Mater. Res. Soc. Proc. 397, Pittsburgh, PA, 1996), pp. 1666.
16.Singh, R.K. and Narayan, J., Phys. Rev. B, 43, 8843 (1990).
17.Singh, R.K., Jagannadham, K., and Narayan, J., Mater. Sci. Eng. B, Solid State Mater. Adv. Technol. 7, 287 (1991).
18.Singh, R.K. and Kumar, D., Mater. Sci. Eng. Rep. R22(4), 113 (1998).
19.Geohegan, D.B., Puretzky, A.A., Duscher, G., Pennycook, S.J., in Advances in Laser Ablation of Materials, edited by Singh, R.K., Lowndes, D.H., Chrisey, D.B., Fogarassy, E., and Narayan, J. (Mater. Res. Soc. Symp. Proc. 526, Warrendale, PA, 1998) p. 47.
20.Rinnen, K.D., Kolenbrander, K.D., De Santolo, A.M., and Mandich, M.L., J. Chem. Phys. 96, 4088 (1992).
21.Ohkoshi, M., Yoshitake, T., and Tsushima, K., Appl. Phys. Lett. 64, 3340 (1994).
22.Yoshida, T., Takeyama, S., Yamada, Y., Mutoh, K., Appl. Phys. Lett. 68, 1772 (1996).
23.Lowdnes, D.L., Geohegan, D.B., Puretsky, A.A., Norton, D.P. and Rouleau, C.M., Science 273, 898 (1996).
24.Singh, R.K., Ata, A., Fitz-Gerald, J., Rabinovich, Y., Hendrickson, W., Kona 15, 121 (1997).
25.Lide, D.R., in Handbook of Chemistry and Physics, edited by Frederikse, H.P.R (Chemical Rubber Publishing Company Press, Boca Raton, 1995), p. 1155.
26.Geohegan, D.B., in Surface Chemistry and Beam-Solid Interactions, edited by Atwater, H.A., Houle, F.A., and Lowndes, D.H. (Mater. Res. Soc. Symp. Proc. 201, Pittsburgh, PA, 1990), p. 557.
27.Geohegan, D.B., Thin Solid Film 220, 138 (1992).
28.Geohegan, D.B., Appl. Phys. Lett. 62, 1463 (1993).
29.Geohegan, D.B., Puretzky, A.A., Duscher, G., Pennycook, S.J., in Advances in Laser Ablation of Materials, edited by Singh, R.K., Lowndes, D.H., Chrisey, D.B., Fogarassy, E., and Narayan, J. (Mater. Res. Soc. Symp. Proc. 526, Warrendale, PA, 1998) p. 47.
30.Schaffer, J.P., Saxena, A., Antolovich, S.D., Sanders, T.H., Warner, S.B., The Science and Engineering of Materials (Irwin, Press, Chicago, (1995), p. 301.
31.Browning, N.D., Chisholm, M.F., and Pennycook, S.J., Nature 366, 143 (1993).
32.McGibbon, A.J., Pennycook, S.J., and Angelo, J.E., Science 269, 519 1995.
33.Forest, H. and Ban, G., J. Electrochem. Soc. 116, 474 (1969).


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