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New mechanochemical effects in the poly(N-vinylcaprolactam)—Nano-titanium oxides(IV) system

Published online by Cambridge University Press:  10 April 2018

Olesya Timaeva ,
Irina Chihacheva ,
Galina Kuzmicheva ,
Natalia Ivanovskaya  and
Andrey Dorohov
Olesya Timaeva*
Affiliation:
Moscow Technological University, Institute of Fine Chemical Technologies, Moscow 119571, Russia
Irina Chihacheva
Affiliation:
Moscow Technological University, Institute of Fine Chemical Technologies, Moscow 119571, Russia
Galina Kuzmicheva
Affiliation:
Moscow Technological University, Institute of Fine Chemical Technologies, Moscow 119571, Russia
Natalia Ivanovskaya
Affiliation:
Shubnikov Institute of Crystallography of Federal Scientific Research Centre “Crystallography and Photonics”, Russian Academy of Sciences, Moscow 119333, Russia
Andrey Dorohov
Affiliation:
Moscow Technological University, Institute of Fine Chemical Technologies, Moscow 119571, Russia
*
a)Address all correspondence to this author. e-mail: timaeva@mirea.ru
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Abstract

Nanocomposites based on the poly(N-vinylcaprolactam) (PVCL) fabricated from PVCL solutions at different drying temperatures (PVCL25 at 25 °C, PVCL40 at 40 °C) and titanium oxides(IV) nanoparticles (TNPs) were produced for the first time by dry mixing and grinding and mechanical milling in a planetary ball mill using different PVCL:TNP ratios. New effects in initial PVCL (hydration) and TNP [decomposition of η-phase; appearance of hydrated titanium dioxide (HTD)] samples, as well as in PVCL [(de)hydration, disordering of the heterocycles] and TNP (amorphization, dehydration of η-phase, partial crystallization of Hombifine N with anatase), involved as components in PVCL/TNP nanocomposites, were found. The different role of each type of treatments and its conditions in the specific of the effects observed was shown. Only high-frequency mechanical milling leads to the appearance of HTD and the complete disappearance of the second peak of PVCL (disordering of the heterocycles) in PVCL/TNP nanocomposites.

Keywords

compositepolymerphase transformation
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 10 , 28 May 2018 , pp. 1475 - 1485
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Copyright
Copyright © Materials Research Society 2018 

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Footnotes

Contributing Editor: Sarah Morgan

References

REFERENCES

Su, S.J. and Kuramoto, N.: Processable polyaniline-titanium dioxide nanocomposites: Effect of titanium dioxide on the conductivity. Synth. Met. 114, 147 (2000).Google Scholar
Chau, J.L.H., Tung, C.T., Lin, Y.M., and Li, A.K.: Preparation and optical properties of titania/epoxy nanocomposite coatings. Mater. Lett. 62, 3416 (2008).Google Scholar
Kirsh, Y.E.: Water Soluble Poly-N-vinylamides. Synthesis and Physicochemical Properties (John Wiley and Sons, Chichester, 1998).Google Scholar
Sun, S. and Wu, P.: Infrared spectroscopic insight into hydration behavior of poly(N-vinylcaprolactam) in water. J. Phys. Chem. B 115, 11609 (2011).CrossRefGoogle ScholarPubMed
Sibileva, M.A., Sibilev, A.I., and Klyubin, V.V.: Study of the temperature behavior of hydrodynamic dimensions of poly(N-vinylcaprolactam) polymer coils in light and heavy water. Polym. Sci., Ser. A 43, 751 (2001).Google Scholar
Ismagilov, Z.R., Shikina, N.V., Bessudnova, E.V., Korneev, D.V., Ishchenko, A.V., Chesalov, Y.A., Vladimirova, A.V., and Ryabchikova, E.I.: The effect of chemical treatment conditions of titanium dioxide sols on their dispersion and cytotoxic properties. Chem. Eng. Trans. 27, 241 (2012).Google Scholar
Gnaser, H., Huber, B., and Ziegler, Ch.: Nanocrystalline TiO2 for photocatalysis. In Encyclopedia of Nanoscience and Nanotechnology, Vol. 6, Nalwa, H.S., ed. (American Scientific Publishers, Los-Angeles, 2004); p. 505.Google Scholar
Hanemann, T. and Szabó, D.V.: Polymer-nanoparticle composites: From synthesis to modern applications. Materials 3, 3468 (2010).Google Scholar
Gorrasi, G. and Sorrentino, A.: Mechanical milling as a technology to produce structural and functional bio-nanocomposites. Green Chem. 17, 2610 (2015).Google Scholar
Tham, W.L., Chow, W.S., and Ishak, Z.A.M.: Flexural and morphological properties of poly(methyl methacrylate)/hydroxyapatite composites: Effects of planetary ball mill grinding time. J. Reinf. Plast. Compos. 13, 2065 (2010).Google Scholar
Suwa, Y., Inagaki, M., and Naka, S.: Polymorphic transformation of titanium dioxide by mechanical grinding. J. Mater. Sci. 5, 1397 (1984).Google Scholar
Ren, R., Yang, Z., and Shaw, L.L.: Polymorphic transformation and powder characteristics of TiO2 during high energy milling. J. Mater. Sci. 35, 6015 (2000).Google Scholar
Baláž, P., Achimovičová, M., Baláž, M., Billik, P., Cherkezova-Zheleva, Z., Manuel Criado, J., Delogu, F., Dutková, E., Gaffet, E., José Gotor, F., Kumar, R., Mitov, I., Rojac, T., Senna, M., Streletskii, A., and Wieczorek-Ciurowa, K.: Hallmarks of mechanochemistry: From nanoparticles to technology. Chem. Soc. Rev. 42, 7571 (2013).Google Scholar
Kaneniwa, N. and Ikekawa, A.: Influence of ball-milling atmosphere on decrease of molecular weight of polyvinylpirrolidone powders. Chem. Pharm. Bull. 7, 1536 (1972).Google Scholar
Beyer, M.K. and Clausen-Schaumann, H.: Mechanochemistry: The mechanical activation of covalent bonds. Chem. Rev. 8, 2921 (2005).Google Scholar
Font, J., Muntasell, J., and Cesari, E.: Amorphization of organic compounds by ball milling. Mater. Res. Bull. 12, 1691 (1997).Google Scholar
Dadachov, M.: Novel titanium dioxide, process of making and method of using same. U.S. Patent Application Publication 20060171877, 2006.Google Scholar
Savinkina, E.V., Obolenskaya, L.N., Kuz’micheva, G.M., Dorokhov, A.V., and Tsivadze, A.Y.: A new η-titania based photocatalyst. Dokl. Phys. Chem. 1, 224 (2011).Google Scholar
Kuzmicheva, G.M., Domoroshchina, E.N., Savinkina, E.V., and Obolenskaya, L.N.: Nanosized titania with anatase structure: Synthesis, characterization, applications and environmental effects. In Titanium Dioxide, Brown, J., ed. (Nova Science Publishers, New York, 2014); pp. 177–226.Google Scholar
Kuzmicheva, G.M.: Nanosized phases with titanium(IV) oxides. Prepararion, characterization, and properties. Fine Chem. Technol. 6, 5 (2015).Google Scholar
Vasilyeva, I., Kuzmicheva, G., Pochtar, A., Gainanova, A., Timaeva, O., Dorokhov, A., and Podbel’skiy, V.: On the nature of the phase “η-TiO2”. New J. Chem. 40, 151 (2016).Google Scholar
Chihacheva, I.P., Timaeva, O.I., Kuzґmicheva, G.M., Dorohov, A.V., Lobanova, N.A., Amarantov, S.V., Podbel’skiy, V.V., Serousov, V.E., and Sadovskaya, N.V.: Specific physical and chemical properties of two modifications of poly(N-vinylcaprolatam). Crystallogr. Rep. 61, 421 (2016).Google Scholar
Efanov, E.V., Podbel’skiy, V.V., and Kuzmicheva, G.M.: Program for processing of diffraction patterns with the possibility of correction source data, federal service for intellectual property, certificate on state registration of computer program, No. 201561765, 2015.Google Scholar
Kuzmicheva, G.M., Podbel’skiy, V.V., Stepanov, A.N., and Gainanova, A.A.: Program for processing of diffraction patterns of nanosized and amorphous substances and calculation of the substructure, No. 2017610699, 2017.Google Scholar
Obolenskaya, L.N., Kuzmicheva, G.M., Savinkina, E.V., Zhilkina, A.V., Sadovskaya, N.V., Prokudina, N.A., and Chernyshev, V.V.: Influence of sulphate method on the characteristics of the samples with nanosized anatase modification. Izv. Akad. Nauk, Ser. Khim. 11, 2032 (2012).Google Scholar
Gregg, S.J. and Sing, K.S.W.: Adsorption, Surface Area and Porosity (Academic Press, London, U.K., 1982).Google Scholar
Busselez, R., Arbe, A., Cerveny, S., Capponi, S., Colmenero, J., and Frick, B.: Component dynamics in polyvinylpyrrolidone concentrated aqueous solutions. J. Chem. Phys. 137, 084902 (2012).Google Scholar
Perreux, L. and Loupy, A.A.: Tentative rationalization of microwave effects in organic synthesis according to the reaction medium, and mechanism considerations. Tetrahedron 57, 9199 (2001).Google Scholar
Vasilakos, N.P. and Magalhaes, F.: Microwave drying of polymers. J. Microwave Power 2, 135 (1984).Google Scholar
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