- Cited by 18
Kim, Yong-Il Ryu, Kwon-Sang and Heo, Kyoung-Chan 2007. Thermal degradation of blue-colour emitting CaMgSi2O6 : Eu2+phosphor. Journal of Physics D: Applied Physics, Vol. 40, Issue. 19, p. 5860.
Yoo, Hyoung-Sun Park, Bong-Je Kang, Jong-Hyuk Im, Won-Bin and Jeon, Duk-Young 2007. Synthesis of CaS:Eu2+Phosphor by using a Sealing Vessel and its Photoluminescence Properties. Transactions on Electrical and Electronic Materials, Vol. 8, Issue. 6, p. 255.
Toda, Kenji Hosoume, Masafumi Sato, Kenji Uematsu, Kazuyoshi Sato, Mineo Watanabe, Akira and Fukui, Takehisa 2008. Morphology Control of High Luminance Phosphors. Key Engineering Materials, Vol. 388, Issue. , p. 107.
Jung, Kyeong Youl Kim, Joo Hyun and Kang, Yun Chan 2009. Luminescence enhancement of Eu-doped calcium magnesium silicate blue phosphor for UV-LED application. Journal of Luminescence, Vol. 129, Issue. 6, p. 615.
Yoo, Hyoung Sun Vaidyanathan, Sivakumar Kim, Sung Wook and Jeon, Duk Young 2009. Synthesis and photoluminescence properties of Yb2+ doped Ba5(PO4)3Cl phosphor for white light-emitting diodes. Optical Materials, Vol. 31, Issue. 11, p. 1555.
Ishida, M Imanari, Y Isobe, T Kuze, S Ezuhara, T Umeda, T Ohno, K and Miyazaki, S 2010. First-principles study of blue silicate phosphors. Journal of Physics: Condensed Matter, Vol. 22, Issue. 38, p. 384202.
Xia, Zhiguo Du, Peng Liao, Libing Li, Guowu and Jin, Shuai 2010. Synthesis and color-tunable luminescence properties of novel calcium aluminate silicate chloride phosphors. Current Applied Physics, Vol. 10, Issue. 4, p. 1087.
Kuo, Te-Wen Liu, Wei-Ren and Chen, Teng-Ming 2010. Emission color variation of (Ba,Sr)_3BP_3O_12:Eu^2+ phosphors for white light LEDs. Optics Express, Vol. 18, Issue. 3, p. 1888.
Kuo, Te-Wen Huang, Chien-Hao and Chen, Teng-Ming 2010. Novel yellowish-orange Sr_8Al_12O_24S_2:Eu^2+ phosphor for application in blue light-emitting diode based white LED. Optics Express, Vol. 18, Issue. S2, p. A231.
Kuo, Te-Wen Huang, Chien-Hao and Chen, Teng-Ming 2010. Intense violet-blue-emitting Ba_2AlB_4O_9Cl:Eu^2+ phosphors for applications in fluorescent lamps and ultraviolet-light-emitting diodes. Applied Optics, Vol. 49, Issue. 22, p. 4202.
Salimi, R. Sameie, H. Alvani, A. A. Sabbagh Sarabi, A. A. Khorasani, M. Farsi, M. A. Mokhtari Ebrahimi, Y. and Tahriri, M. 2011. Optical characterization of the novel nanostructure Eu-doped phosphor for potential application in LEDs. p. 1234.
Xia, Zhiguo Li, Qiang Li, Guowu Xiong, Ming and Liao, Libing 2011. Crystal growth of Ca3SiO4Br2: New photoluminescence bromosilicate host. Journal of Crystal Growth, Vol. 318, Issue. 1, p. 958.
Salimi, R. Sameie, H. Sabbagh Alvani, A. A. Sarabi, A. A. Moztarzadeh, F. Eivaz Mohammadloo, H. Nargesian, F. and Tahriri, M. 2012. Sol–gel synthesis, structural and optical characteristics of Sr1−x Zn2Si2yO7+δ: xEu2+ as a potential nanocrystalline phosphor for near-ultraviolet white light-emitting diodes. Journal of Materials Science, Vol. 47, Issue. 6, p. 2658.
Brgoch, Jakoah Borg, Christopher K. H. Denault, Kristin A. Mikhailovsky, Alexander DenBaars, Steven P. and Seshadri, Ram 2013. An Efficient, Thermally Stable Cerium-Based Silicate Phosphor for Solid State White Lighting. Inorganic Chemistry, Vol. 52, Issue. 14, p. 8010.
Ishida, M Imanari, Y Isobe, T Kuze, S Ezuhara, T Umeda, T Ohno, K and Miyazaki, S 2013. Density functional study for optical properties of blue silicate phosphor: BaCa2MgSi2O8. Journal of Physics: Conference Series, Vol. 454, Issue. , p. 012062.
Terraschke, Huayna and Wickleder, Claudia 2015. UV, Blue, Green, Yellow, Red, and Small: Newest Developments on Eu2+-Doped Nanophosphors. Chemical Reviews, Vol. 115, Issue. 20, p. 11352.
Annadurai, G. Kennedy, S. Masilla Moses and Sivakumar, V. 2016. Luminescence properties of a novel green emitting Ba 2 CaZn 2 Si 6 O 17 :Eu 2+ phosphor for white light – Emitting diodes applications. Superlattices and Microstructures, Vol. 93, Issue. , p. 57.
Ha, Jungmin Wang, Zhenbin Novitskaya, Ekaterina Hirata, Gustavo A. Graeve, Olivia A. Ong, Shyue Ping and McKittrick, Joanna 2016. An integrated first principles and experimental investigation of the relationship between structural rigidity and quantum efficiency in phosphors for solid state lighting. Journal of Luminescence, Vol. 179, Issue. , p. 297.
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We optimized synthesis conditions of blue-emitting CaMgSi2O6:Eu2+ (CMS:Eu2+) with conventional solid-state reaction and successfully determined structure parameters by Rietveld refinement method with neutron powder diffraction data. The final weighted R-factor Rwp was 6.42% and the goodness-of-fit indicator S (= Rwp/Re) was 1.34. The refined lattice parameters of CMS:Eu2+ were a = 9.7472(3) Å, b = 8.9394(2) Å, and c = 5.2484(1) Å. The β angle was 105.87(1)°. The concentration quenching process was observed, and the critical quenching concentration of Eu2+ in CMS:Eu2+ was about 0.01 mol and critical transfer distance was calculated as 12 Å. With the help of the Rietveld refinement and Dexter theory, the critical transfer distance was also calculated as 27 Å. In addition, the dominant multipolar interaction of CMS:Eu2+ was investigated from the relationship between the emission intensity per activator concentration and activator concentration. The dipole–dipole interaction was a dominant energy transfer mechanism of electric multipolar character of CMS:Eu2+.
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