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Mesoporous crystalline SnO2 of large surface area

  • Chien-Yueh Tung (a1), Nae-Lih Wu (a1) and I.A. Rusakova (a2)

Abstract

Mesoporous crystalline SnO2 was synthesized by using templating process with cetyltrimethylammonium bromide as the template, combined with a pretreatment process of hexamethyldisilazane vapor prior to thermal crystallization. The combined process resulted in crystalline SnO2 exhibiting large pore volumes and surface areas that cannot be achieved by either of the processes alone, or by the conventional sol-gel process. Fully crystallized SnO2 powder with a pore volume of approximately 0.2 cc/g, a surface area of 220 m2/g, and mesopores mainly of 5 nm in diameter were obtained after heat treatment at 500°C.

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1.Fuller, M.J. and Warwick, M.E., J. Catal. 29, 441 (1973).
2.Sala, F. and Trifiro, F., J. Catal. 34, 68 (1974).
3.Harrison, P.G. and Harris, P.J.F., U.S. Patent No. 5 051 393, September 24, 1991.
4.Seiyama, T., Kato, A., Fujishi, K., and Nagatani, M., Anal. Chem. 34, 1502 (1962).
5.Takahata, K., in Chemical Sensor Technology, edited by Seiyama, T. (Kodansha, Tokyo, Japan, and Elsevier, Amsterdam, The Netherlands, 1988), Vol. 1, p. 39.
6.Camanzi, A. and Sberveglierri, G., U.S. Patent No. 5 185 130, February 9, 1993.
7.Wu, N-L., Hwang, J.Y., Liu, P.Y., Han, C.Y., Kuo, S.L., Liao, K.H., Lee, M.H., and Wang, S.Y., J. Electrochem. Soc. 148, 550 (2001).
8.Wu, N-L., Han, C.Y., and Kuo, S.L., J. Power Sources 109, 418 (2002).
9.Wu, N-L., Kuo, S.L., Electrochem. Solid-State Lett. 6, A85 (2003).
10.Ferrere, S., Zaban, A., Gregg, B.A., J. Phys. Chem. B 101, 4490 (1997).
11.Gratzel, M., Pure Appl. Chem. 73, 459 (2001).
12.Chopra, K.L., Major, S., and Pandya, D.K., Thin Solid Films 102, 1 (1983).
13.Wu, N.L., Wu, L.F., Yang, Y.C., and Huang, S.J., J. Mater. Res. 11, 813 (1996).
14.Wu, N.L. and Wu, L.F., Republic of China Patent No. 78288, April 11, 1996.
15.Goodman, J.F. and Gregg, S.J., J. Chem. Soc. 237, 1162 (1960).
16.Hiratsuka, R.S., Pulcinelli, S.H., and Santilli, C.V., J. Non-Cryst. Solids 121, 76 (1990).
17.Kobayashi, Y., Okamoto, M., and Tomita, A., J. Mater. Sci. 31, 6125 (1996).
18.Yoo, D.J., Tamaki, J., Park, S.J., Miura, N., and Yamazoe, N., J. Am. Ceram. Soc. 79, 2201 (1996).
19.Gulliver, E.A., Garvey, J.W., Wark, T.A., Hampden-Smith, M.J., and Datye, A., J. Am. Ceram. Soc. 74, 1091 (1991).
20.Hampden-Smith, M.J., Wark, T.A., and Brinker, C.J., Coord. Chem. Rev. 112, 81 (1992).
21.Wu, N.L., Wu, L.F., Rusakova, I.A., Hamed, A., and Litvinchuk, A.P., J. Am. Ceram. Soc. 82, 67 (1999).
22.Wu, N.L. and Wang, S.Y., J. Mater. Science 34, 2807 (1999).
23.Huo, Q., Margolese, D.I., Ciesla, U., Demuth, D.G., Feng, P., Gier, T.E., Sieger, P., Firouzi, A., Chmelka, B.F., Schuth, F., and Stucky, G.D., Chem. Mater. 6, 1176 (1994).
24.Ulagappan, N. and Rao, C.N.R., Chem. Commun. 1685 (1966).
25.Severin, K.G., Abdel-Fattah, T.M., and Pinnavania, T.J., Chem. Commun. 1471 (1998).
26.Chen, F. and Liu, M., Chem. Commun., 1829 (1999).
27.Yang, P., Zhao, D., Margolese, D.I., Chmelka, B.F., and Stucky, G.D., Chem. Mater. 11, 2813 (1999).
28.Srivastava, D.N., Chappel, S., Palchik, O., Zaban, A., and Gedanken, A., Langmuir 18, 4160 (2002).
29.Grosso, D., Illia, G.J. de A.A. Soler, Crepaldi, E.L., Charleux, B., and Sanchez, C., Adv. Funct. Mater. 13, 37 (2003).
30.Wang, Y.D., Ma, C.L., Sun, X.D., and Li, H.D., Inorg. Chem. Commun. 4, 223 (2001).
31.Wu, N.L., Wang, S.Y., and Rusakova, I.A., Science 285, 1375 (1999).

Mesoporous crystalline SnO2 of large surface area

  • Chien-Yueh Tung (a1), Nae-Lih Wu (a1) and I.A. Rusakova (a2)

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