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Liquidus projection of the ternary Ag–Sn–Ni system
-
- DOI: https://doi.org/10.1557/JMR.2004.0295
- Published online by Cambridge University Press: 03 March 2011
Abstract
The liquidus projection of the ternary Sn–Ag–Ni system at the Sn-rich side was determined experimentally. No ternary compound was found, and the ζ–Ag4Sn, Ag3Sn, and Sn existed as the primary solidification phases only in very small compositional portions of the ternary Sn–Ag–Ni system. In more than half of the compositional regime of the ternary system, the Ni3Sn2 phase was the primary solidification phase. The differential thermal analysis technique was used to determine the reaction temperatures and solidification sequences of various Sn-rich Sn–Ag–Ni alloys. Three invariant reactions were found: L = Sn + Ni3Sn4 + Ag3Sn, L + ζ–Ag4Sn = Ni3Sn4 + Ag3Sn and L + Ni3Sn2 = ζ–Ag4Sn + Ni3Sn4. Their reaction temperatures have been determined to be 219, 488, and 516.5 °C, respectively.
Copyright
COPYRIGHT: © Materials Research Society 2004
Corresponding author
a) Address all correspondence to this author. e-mail: swchen@che.nthu.edu.tw
References
Keywords
- Cited by 12
-
Cited byCrossref Citations
This article has been cited by the following publications. This list is generated based on data provided by CrossRef.
Chiu, Chen-nan Huang, Yu-chih Zi, An-ren and Chen, Sinn-wen 2005. Isoplethal Sections of the Liquidus Projection and the 250°C Phase Equilibria of the Sn–Ag–Cu–Ni Quaternary System at the Sn-Rich Corner. MATERIALS TRANSACTIONS, Vol. 46, Issue. 11, p. 2426.
Chang, Cheng-An Chen, Sinn-Wen Chiu, Chen-Nan and Huang, Yu-Chih 2005. Primary solidification phases of the Sn-rich Sn-Ag-Cu-Ni quaternary system. Journal of Electronic Materials, Vol. 34, Issue. 8, p. 1135.
Chen, Sinn-Wen Wang, Chao-Hong Lin, Shih-Kang and Chiu, Chen-Nan 2006. Phase Diagrams of Pb-Free Solders and their Related Materials Systems. Journal of Materials Science: Materials in Electronics, Vol. 18, Issue. 1-3, p. 19.
Chen, Sinn-Wen Chen, Po-Yin and Wang, Chao-Hong 2006. Lowering of Sn−Sb alloy melting points caused by substrate dissolution. Journal of Electronic Materials, Vol. 35, Issue. 11, p. 1982.
Schmetterer, Clemens Flandorfer, Hans Richter, Klaus W. and Ipser, Herbert 2007. Phase Equilibria in the Ag-Ni-Sn System: Isothermal Sections. Journal of Electronic Materials, Vol. 36, Issue. 11, p. 1415.
Liu, X. J. Wang, C. P. Gao, F. Ohnuma, I. and Ishida, K. 2007. Thermodynamic Calculation of Phase Equilibria in the Sn-Ag-Cu-Ni-Au System. Journal of Electronic Materials, Vol. 36, Issue. 11, p. 1429.
Gollas, Bernhard Albering, Jörg H. Schmut, Katharina Pointner, Volker Herber, Ralph and Etzkorn, Johannes 2008. Thin layer in situ XRD of electrodeposited Ag/Sn and Ag/In for low-temperature isothermal diffusion soldering. Intermetallics, Vol. 16, Issue. 8, p. 962.
Gao, F. Wang, C.P. Liu, X.J. and Ishida, K. 2008. Thermodynamic Assessment of Phase Equilibria in the Sn-Ag-Ni System with Key Experimental Verification. Journal of Electronic Materials, Vol. 37, Issue. 3, p. 279.
Lin, Shih-Kang Yang, Ching-Feng Wu, Shyr-Harn and Chen, Sinn-Wen 2008. Liquidus Projection and Solidification of the Sn-In-Cu Ternary Alloys. Journal of Electronic Materials, Vol. 37, Issue. 4, p. 498.
Wu, Hsin-jay Foo, Wei-jian Gierlotka, Wojciech Chen, Sinn-wen and Snyder, G. Jeffrey 2013. The microstructure, liquidus projection and thermodynamic modeling of thermoelectric Ag–Pb–Te system. Materials Chemistry and Physics, Vol. 141, Issue. 2-3, p. 758.
Chen, Sinn-wen Chen, Tung-Kai Hsu, Chia-ming Chang, Jui-shen and Pan, Kevin 2014. Liquidus Projections of Sn-Co-Ni and Sn-Rich Sn-Ag-Co-Ni Systems. Journal of Electronic Materials, Vol. 43, Issue. 7, p. 2487.
Chiu, Wan-ting Chen, Sinn-wen and Tseng, Ssu-ming 2015. Liquidus projection of Cu–In–Se photovoltaic material system. Solar Energy Materials and Solar Cells, Vol. 141, Issue. , p. 187.
Liquidus projection of the ternary Ag–Sn–Ni system
-
- DOI: https://doi.org/10.1557/JMR.2004.0295
- Published online by Cambridge University Press: 03 March 2011
