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Irradiation-induced defect clustering and amorphization in silicon carbide

Published online by Cambridge University Press:  31 January 2011

William J. Weber*
Affiliation:
Department of Materials Science & Engineering, University of Tennessee, Knoxville, Tennessee 37996; and Materials Science & Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
Fei Gao
Affiliation:
Pacific Northwest National Laboratory, Richland, Washington 99352
*
a)Address all correspondence to this author. e-mail: wjweber@utk.edu This author was an editor of this journal during the review and decision stage. For the JMR policy on review and publication of manuscripts authored by editors, please refer to http://www.mrs.org/jmr_policy
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Abstract

Previous computer simulations of multiple 10 keV Si cascades in 3C–SiC demonstrated that many damage-state properties exhibit relatively smooth, but noticeably different, dose dependencies. A more recent analysis of these damage-state properties, which includes additional data at low and intermediate doses, reveals more complex relationships between system energy, swelling, energy per defect, relative disorder, elastic modulus, and elastic constant, C11. These relationships provide evidence for the onset of both defect clustering and solid-state amorphization, which appear to be driven by local energy and elastic instabilities from the accumulation of defects. The results provide guidance on experimental approaches to reveal the onset of these processes.

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Articles
Copyright
Copyright © Materials Research Society 2010

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References

REFERENCES

1.Eddy, C.R. Jr., Gaskill, D.K.: Silicon carbide as a platform for power electronics. Science 324, 1398 (2009)CrossRefGoogle ScholarPubMed
2.Sumakeris, J.J., Jenny, J.R., Powell, A.R.: Bulk crystal growth, epitaxy, and defect reduction in silicon carbide materials for microwave and power devices. MRS Bull. 30, 280 (2005)Google Scholar
3.Jones, R.H., Giancarli, L., Hasegawa, A., Katoh, Y., Kohyama, A., Riccardi, B., Snead, L.L., Weber, W.J.: Promise and challenges of SiCf/SiC composites for fusion energy applications. J. Nucl. Mater. 307–311, 1057 (2002)CrossRefGoogle Scholar
4.Snead, L.L., Nozawa, T., Katoh, Y., Byun, T-S., Kondo, S., Petti, D.A.: Handbook of SiC properties for fuel performance modeling. J. Nucl. Mater. 371, 329 (2007)CrossRefGoogle Scholar
5.Inui, H., Mori, H., Fujita, H.: Electron-irradiation-induced crystalline to amorphous transition in α-SiC single crystals. Philos. Mag. B 61, 107 (1990)Google Scholar
6.Inui, H., Mori, H., Sakata, T., Fujita, H.: Electron-irradiation-induced crystalline-to-amorphous transition in β-SiC single crystals. Philos. Mag. B 65, 1 (1992)Google Scholar
7.Wendler, E., Heft, A., Wesch, W.: Ion-beam induced damage and annealing behaviour in SiC. Nucl. Instrum. Methods Phys. Res., Sect. B 141, 105 (1998)CrossRefGoogle Scholar
8.Zhang, Y., Gao, F., Jiang, W., McCready, D.E., Weber, W.J.: Damage accumulation and defect relaxation in 4H–SiC. Phys. Rev. B 70, 125203 (2004)CrossRefGoogle Scholar
9.Jiang, W., Wang, H., Kim, I., Bae, I-T., Li, G., Nachimuthu, P., Zhu, Z., Zhang, Y., Weber, W.J.: Response of nanocrystalline 3C silicon carbide to heavy-ion irradiation. Phys. Rev. B 80, 161301 (2009)CrossRefGoogle Scholar
10.Snead, L.L., Hay, J.C.: Neutron irradiation induced amorphization of silicon carbide. J. Nucl. Mater. 273, 213 (1999)Google Scholar
11.Devanathan, R., Weber, W.J., Gao, F.: Atomic scale simulation of defect production in irradiated 3C–SiC. J. Appl. Phys. 90, 2303 (2001)CrossRefGoogle Scholar
12.Farrell, D.E., Bernstein, N., Liu, W.K.: Thermal Effects in 10 keV Si PKA cascades in 3C–SiC. J. Nucl. Mater. 385, 572 (2009)CrossRefGoogle Scholar
13.Swaminathan, N., Kamenski, P.J., Morgan, D., Szlufarska, I.: Effects of grain size and grain boundaries on defect production in nanocrystalline 3C–SiC. Acta Mater. 58, 2843 (2010)Google Scholar
14.Gao, F., Chen, D., Hu, W., Weber, W.J.: Energy dissipation and defect generation in nanocrystalline silicon carbide. Phys. Rev. B 81, 184101 (2010)CrossRefGoogle Scholar
15.Malerba, L., Perlado, J.M.: Molecular dynamics simulation of irradiation-induced amorphization of cubic silicon carbide. J. Nucl. Mater. 289, 57 (2001)Google Scholar
16.Weber, W.J., Wang, L.M., Yu, N., Hess, N.J.: Structure and properties of ion-beam-modified (6H) silicon carbide. Mater. Sci. Eng., A 253, 62 (1998)Google Scholar
17.Gao, F., Weber, W.J.: Atomic-scale simulations of multiple ion–solid interactions and structural evolution in silicon carbide. J. Mater. Res. 17, 259 (2002)CrossRefGoogle Scholar
18.Gao, F., Weber, W.J.: Cascade overlap and amorphization in 3C–SiC: Defect accumulation, topological features, and disorder. Phys. Rev. B 66, 024106 (2002)CrossRefGoogle Scholar
19.Gao, F., Weber, W.J., Devanathan, R.: Defect production, multiple ion–solid interactions and amorphization in SiC. Nucl. Instrum. Methods Phys. Res., Sect. B 191, 487 (2002)CrossRefGoogle Scholar
20.Gao, F., Weber, W.J.: Atomic-scale simulations of cascade overlap and damage evolution in silicon carbide. J. Mater. Res. 18, 1877 (2003)Google Scholar
21.Gao, F., Weber, W.J.: Mechanical properties and elastic constants due to damage accumulation and amorphization is SiC. Phys. Rev. B 69, 224108 (2004)CrossRefGoogle Scholar
22.Crocombette, J-P., Dumazer, G., Hoang, N.Q., Gao, F., Weber, W.J.: Molecular dynamics modeling of the thermal conductivity of SiC as a function of cascade overlap. J. Appl. Phys. 101, 023527 (2007)Google Scholar
23.Lam, N.Q., Okamoto, P.R., Li, M.: Disorder-driven amorphization. J. Nucl. Mater. 251, 89 (1997)Google Scholar
24.Devanathan, R., Weber, W.J., de la Rubia, T. Diaz: Computer simulation of a 10 keV Si displacement cascade in SiC. Nucl. Instrum. Methods Phys. Res., Sect. B 141, 118 (1998)Google Scholar
25.Gao, F., Bylaska, E.J., Weber, W.J., Corrales, L.R.: Native defect properties in β-SiC: Ab initio and empirical potential calculations. Nucl. Instrum. Methods Phys. Res., Sect. B 180, 286 (2001)Google Scholar
26.Devanathan, R., Weber, W.J.: Displacement energy surface in 3C and 6H SiC. J. Nucl. Mater. 278, 258 (2000)CrossRefGoogle Scholar
27.Gao, F., Weber, W.J.: Atomic-scale simulation of 50 keV Si displacement cascades in β-SiC. Phys. Rev. B 63, 054101 (2000)CrossRefGoogle Scholar
28.Gao, F., Weber, W.J., Jiang, W.: Primary damage states produced by Si and Au recoils in SiC: A molecular dynamics and experimental investigation. Phys. Rev. B 63, 214106 (2001)Google Scholar
29.Cahn, R.W., Johnson, W.L.: Review: The nucleation of disorder. J. Mater. Res. 1, 724 (1986)CrossRefGoogle Scholar
30.Wolf, D., Okomoto, P.R., Yip, S., Lutsko, J.F., Kluge, M.: Thermodynamic parallels between solid-state amorphization and melting. J. Mater. Res. 5, 286 (1990)CrossRefGoogle Scholar