Hostname: page-component-8448b6f56d-tj2md Total loading time: 0 Render date: 2024-04-25T00:34:04.968Z Has data issue: false hasContentIssue false
  • English
  • Français

Impact of low viscosity ionic liquid on PMMA–PVC–LiTFSI polymer electrolytes based on AC -impedance, dielectric behavior, and HATR–FTIR characteristics

Published online by Cambridge University Press:  30 October 2012

Chiam-Wen Liew ,
S. Ramesh  and
R. Durairaj
Chiam-Wen Liew
Affiliation:
Department of Physics, Centre for Ionics University Malaya, Faculty of Science, University of Malaya, Lembah Pantai, 50603 Kuala Lumpur, Malaysia
S. Ramesh*
Affiliation:
Department of Physics, Centre for Ionics University Malaya, Faculty of Science, University of Malaya, Lembah Pantai, 50603 Kuala Lumpur, Malaysia
R. Durairaj
Affiliation:
Department of Mechanical and Material Engineering, Faculty of Engineering & Science, Universiti Tunku Abdul Rahman, Setapak, 53300 Kuala Lumpur, Malaysia
*
a)Address all correspondence to this author. e-mail: rameshtsubra@gmail.com
Get access

Abstract

The preparation of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BmImTFSI)-based poly(methyl methacrylate)–poly(vinyl chloride), PMMA–PVC, gel polymer electrolytes was done by solution casting technique. The ionic conductivity of gel polymer electrolytes was increased, up to a maximum value of (1.64 ± 0.01) × 10−4S/cm by adding 60 wt% of BmImTFSI. Conductivity–frequency dependence, dielectric relaxation, and dielectric moduli formalism were also further analyzed. These studies assert the ionic transportation mechanisms in the polymer matrix. Occurrence of polarization electrode–electrolyte interface is also observed. This leads to the formation of electrical double layer and hence indicates the non-Debye characteristic of the polymer matrix in the dielectric studies. Based on the changes in shift, changes in intensity, changes in shape, and existence of new peaks, attenuated total reflectance–Fourier transform infrared divulged the complexation between PMMA, PVC, lithium bis(trifluoromethanesulfonyl)imide, and BmImTFSI, as shown in the infrared spectra.

Keywords

ionic conductordielectric propertiesstructural
Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 23 , 14 December 2012 , pp. 2996 - 3004
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Ramesh, S. and Liew, C-W.: Tailor-made fumed silica-based nano-composite polymer electrolytes consisting of BmImTFSI ionic liquid. Iran. Polym. J. 21, 273–281 (2012).CrossRefGoogle Scholar
Sirisopanaporn, C., Fernicola, A., and Scrosati, B.: New, ionic liquid-based membranes for lithium battery application. J. Power Sources 186, 490–495 (2009).CrossRefGoogle Scholar
Vioux, A., Viau, L., Volland, S., and Bideau, J.L.: Use of ionic liquid in sol–gel; ionogels and applications. C.R. Chim. 13, 242–255 (2010).CrossRefGoogle Scholar
Ramesh, S., Liew, C-W., and Ramesh, K.: Evaluation and investigation on the effect of ionic liquid onto PMMA-PVC gel polymer blend electrolytes. J. Non-Cryst. Solids 357, 2132–2138 (2011).CrossRefGoogle Scholar
Cheng, H., Zhu, C., Huang, B., Lu, M., and Yang, Y.: Synthesis and electrochemical characterization of PEO-based polymer electrolytes with room temperature ionic liquids. Electrochim. Acta 52, 5789–5794 (2007).CrossRefGoogle Scholar
Sekhon, S.S., Krishnan, P., Singh, B., Yamada, K., and Kim, C.S.: Proton conducting membrane containing room temperature ionic liquid. Electrochim. Acta 52, 1639–1644 (2006).CrossRefGoogle Scholar
Marcilla, R., Alcaide, F., Sardon, H., Pomposo, J.A., Gonzalo, C.P., and Mecerreyes, D.: Tailor-made polymer electrolytes based upon ionic liquids and their application in all-phase electrochromic devices. Electrochem. Commun. 8, 482–488 (2006).CrossRefGoogle Scholar
Jain, N., Kumar, A., Chauhan, S., and Chauhan, S.M.S.: Chemical and biochemical transformations in ionic liquids. Tetrahedron 61, 1015–1060 (2005).CrossRefGoogle Scholar
Kim, K.S., Park, S.Y., Choi, S., and Lee, H.: Ionic liquid–polymer gel electrolytes based on morpholinium salt and PVdF(HFP) copolymer. J. Power Sources 155, 385–390 (2006).CrossRefGoogle Scholar
Reiter, J., Vondrak, J., Michalek, J., and Micka, Z.: Ternary polymer electrolytes with 1-methylimidazole based ionic liquids and aprotic solvents. Electrochim. Acta 52, 1389–1408 (2006).CrossRefGoogle Scholar
Shin, J.H., Henderson, W.A., and Passerini, S.: Ionic liquids to the rescue? Overcoming the ionic conductivity limitations of polymer electrolytes. Electrochem. Commun. 5, 1016–1020 (2003).CrossRefGoogle Scholar
Singh, P.K., Kim, K.W., Park, N.G., and Rhee, H.W.: Mesoporous nanocrystalline TiO2 electrode with ionic liquid-based solid polymer electrolyte for dye-sensitized solar cell application. Synth. Met. 158, 590–593 (2008).CrossRefGoogle Scholar
Ramesh, S., Liew, C-W., and Arof, A.K.: Ion conducting corn starch biopolymer electrolytes doped with ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate. J. Non-Cryst. Solids 357, 3654–3660 (2011).CrossRefGoogle Scholar
Almond, D.P., West, A.R., and Grant, R.J.: Temperature dependence of the A.C. conductivity of Na β-alumina. Solid State Commun. 44, 1277–1280 (1982).CrossRefGoogle Scholar
Khiar, A.S.A., Puteh, R., and Arof, A.K.: Conductivity studies of a chitosan-based polymer electrolyte. J. Phys. Condens. Matter 373, 23–27 (2006).Google Scholar
Ramesh, S. and Liew, C-W.: Exploration on nano-composite fumed silica-based composite polymer electrolytes with doping of ionic liquid. J. Non-Cryst. Solids 358, 931–940 (2012).CrossRefGoogle Scholar
Mehta, N., Kumar, D., Kumar, S., and Kumar, A.: Applicability of CBH model in the A.C. conductivity study of glassy Se100-xInx alloys. Chalcogenide Lett. 2, 103–109 (2005).Google Scholar
Rajendran, S., Sivakumar, M., and Subadevi, R.: Investigations on the effect of the various plasticizers in PVA–PMMA solid polymer blend electrolytes. Mater. Lett. 58, 641–649 (2004).CrossRefGoogle Scholar
Baskaran, R., Selvasekarapandian, S., Kuwata, N., Kawamura, J., and Hattori, T.: Ac impedance, DSC and FT–IR investigations on (x)PVAc-(1-x)PVdF blends with LiClO4. Mater. Chem. Phys. 98, 55–61 (2006).CrossRefGoogle Scholar
Eliasson, H., Albinsson, I., and Mellander, B-E.: Conductivity and dielectric properties of AgCF3SO3-PPG. Mater. Res. Bull. 35, 1053–1065 (2000).CrossRefGoogle Scholar
Ramesh, S. and Chai, M.F.: Conductivity, dielectric behavior and FTIR studies of high molecular weight poly(vinyl chloride)–lithium triflate polymer electrolytes. Mater. Sci. Eng., B 139, 240–245 (2007).CrossRefGoogle Scholar
Shastry, M.C.R. and Rao, K.J.: Ac conductivity and dielectric relaxation studies in AgI-based fast ion conducting glasses. Solid State Ionics 44, 187–198 (1991).CrossRefGoogle Scholar
Suthanthiraraj, S.A., Sheeba, D.J., and Paul, B.J.: Impact of ethylene carbonate on ion transport characteristics of PVdF–AgCF3SO3 polymer electrolyte system. Mater. Res. Bull. 44, 1534–1539 (2009).CrossRefGoogle Scholar
Rajendran, S., Mahendran, O., and Kannan, R.: Characterisation of [(1–x) PMMA–x PVdF] polymer blend electrolyte with Li+ ion. Fuel 81, 1077–1081 (2002).CrossRefGoogle Scholar
Achari, V.B., Reddy, T.J.R., Sharma, A.K., and Rao, V.V.R.N.: Electrical, optical, and structural characterization of polymer blend (PVC/PMMA) electrolyte films. Ionics 13, 349–354 (2007).CrossRefGoogle Scholar
Jiang, J., Gao, D., Li, Z., and Su, G.: Gel polymer electrolytes prepared by in situ polymerization of vinyl monomers in room-temperature ionic liquids. React. Funct. Polym. 66, 1141–1148 (2006).CrossRefGoogle Scholar
Rajendran, S. and Sivakumar, P.: An investigation of PVdF/PVC-based blend electrolytes with EC/PC as plasticizers in lithium battery applications. J. Phys. Condens. Matter 403, 509–516 (2008).Google Scholar
Ahmad, S., Deepa, M., and Agnihotry, S.A.: Effect of salts on the fumed silica-based composite polymer electrolytes. Sol. Energy Mater. Sol. Cells 92, 184–189 (2008).CrossRefGoogle Scholar
Bazito, F.F.C., Silveira, L.T., Torresi, R.M., and Torresi, S.T.C.: Spectroelectrochemical study of a soluble derivative of poly(aniline) in a room temperature ionic liquid. Electrochim. Acta 53, 1217–1224 (2007).CrossRefGoogle Scholar
Ramesh, S. and Lu, S-C.: Effect of nanosized silica in poly(methyl methacrylate)–lithium bis(trifluoromethanesulfonyl)imide based polymer electrolytes. J. Power Sources 185 1439–1443 (2008).CrossRefGoogle Scholar
Li, W., Yuan, M., and Yang, M.: Dual-phase polymer electrolyte with enhanced phase compatibility based on Poly(MMA-g-PVC)/PMMA. Eur. Polym. J. 42, 1396–1402 (2006).CrossRefGoogle Scholar