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Growth of KTiOPO4 Films on KTi1-xGexOPO4 Substrates by Liquid-phase Epitaxy

  • R. Solé (a1), V. Nikolov (a2), A. Vilalta (a1), J. J. Carvajal (a1), J. Massons (a1), Jna. Gavaldà (a1), M. Aguiló (a1) and F. Díaz (a1)...

Abstract

The epitaxial growth of KTiOPO4 (KTP) films on different natural faces of KTi1-xGexOPO4 substrates was studied. The growth on faces (100) and (201) is generally of high quality, irrespective of the growth time or concentration of germanium in the substrates. On the other hand, the epitaxial growth on the face (101) is always of poor quality, and the defects are pyramids, even when the germanium content in the substrate is low and the growth time is short. The films on faces (011) and (110) generally have small hillocks as defects and for high concentrations of Ge in the crystals some cracks begin to appear. The film thickness, depending on the growth time and the face considered was measured by scanning electron microscopy (SEM) using backscattered electrons. The diffusion of germanium from the substrate to the film is very low, as demonstrated by electron probe microanalysis measurements and SEM observations. The difference in the refractive indices ny and nz of KTP and KTi0.92Ge0.08OPO4 are on the order of 0.01, which could be enough to produce wave guides. Finally, it was observed that the second harmonic generation response of KTP substituted with Ge decreases as the Ge content in the crystal increases.

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Liu, Y.S., Deutz, D., and Belt, R., Opt. Lett. 9, 76 (1984).
Cheng, L.K., Cheng, L.T., Galperin, J., Hotsenpiller, P.A. Morris, and Bierlein, J.D., J. Cryst. Growth 137, 107 (1994).
Hagerman, M.E. and Poppelmeier, K.R., Chem. Mater. 7, 602 (1995).
Bierlein, J.D. and Vanherzeele, H., J. Opt. Soc. Am. 6, 622 (1989).
Bierlein, J.D., Ferretti, A., Brixner, L.H., and Hsu, W.Y., Appl. Phys. Lett. 50, 1216 (1987).
Jacco, J.C., Loiacono, G.M., Jaso, M., Mizell, G., and Greenberg, B., J. Cryst. Growth 70, 484 (1984).
Laudise, R.A., Cava, R.J., and Caporaso, A.J., J. Cryst. Growth 74, 275 (1986).
Shi, L.P., Pun, E.Y., and Chung, P.S., Cryst. Res. Tech. 32, 597 (1997).
Cheng, L.K., Bierlein, J.D., Foris, C.M., and Ballman, A.A., J. Cryst. Growth 112, 309 (1991).
Raizman, A., Eger, D., and Oron, M., J. Cryst. Growth 187, 259 (1998).
Haussühl, S., Shi, L., Wang, B., Wang, J., Liebertz, J., Wostrack, A., and Fink, Ch., Cryst. Res. Technol. 29, 583 (1994).
Shumov, D.P., Nikolov, V.S., Iliev, K.N., and Aleksandrovskii, A.L., Cryst. Res. Technol. 25, 1245 (1990).
Rodríguez-Carvajal, J., Reference Guide for the Computer Program Fullprof (Lab. León Brillouin, CEA-CNRS, Saclay, France, 1996).
Solé, R., Ruiz, X., Cabré, R., Gavaldà, Jna., Aguiló, M., Díaz, F., Nikolov, V., and Solans, X., J. Cryst. Growth 167, 681 (1996).
Fan, T.Y., Huang, C.E., Hu, B.Q., Eckardt, R.C., Fan, Y.X., Byer, R.L., and Feigelson, R.S., Appl. Optics 26, 2390 (1997).
Kurtz, S.K. and Perry, T.T., J. Appl. Phys. 39, 3798 (1968).
Solé, R., Nikolov, V., Massons, J., Gavaldà, Jna., Aguiló, M., and Díaz, F.. (unpublished).
Shannon, R.D., Acta Crystallogr. A32, 751 (1976).
Stucky, G.D., Phillips, M.L.F., and Gier, T.E., Chem. Mater. 1, 492 (1989).
Phillips, M.L.F., Harrison, W.T.A., and Stucky, G.D., Proc. SPIE Int. Soc. Opt. Eng. 1561, 84 (1991).
Tordjman, I., Masse, R., and Guitel, J.C., Z. Kristallogr. B, 139, 103 (1974).
Sorokina, N.I., Voronkova, V.I., Yanovskii, V.K., Verin, I.A., and Simonov, V.I., Crystallogr. Reports 41, 432 (1996).

Growth of KTiOPO4 Films on KTi1-xGexOPO4 Substrates by Liquid-phase Epitaxy

  • R. Solé (a1), V. Nikolov (a2), A. Vilalta (a1), J. J. Carvajal (a1), J. Massons (a1), Jna. Gavaldà (a1), M. Aguiló (a1) and F. Díaz (a1)...

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