- Cited by 32
Choi, Jae-Man Kim, Hyoun-Ee and Lee, In-Seop 2000. Ion-beam-assisted deposition (IBAD) of hydroxyapatite coating layer on Ti-based metal substrate. Biomaterials, Vol. 21, Issue. 5, p. 469.
Pham, M. T. Matz, W. Grambole, D. Herrmann, F. Reuther, H. Richter, E. and Steiner, G. 2002. Solution deposition of hydroxyapatite on titanium pretreated with a sodium ion implantation. Journal of Biomedical Materials Research, Vol. 59, Issue. 4, p. 716.
Lee, In-Seop Kim, Dong-Hwan Kim, Hyoun-Ee Jung, Young-Chul and Han, Chong-Hyun 2002. Biological performance of calcium phosphate films formed on commercially pure Ti by electron-beam evaporation. Biomaterials, Vol. 23, Issue. 2, p. 609.
Kong, Young-Min Kim, Dong-Hwan Kim, Hyoun-Ee Heo, Seong-Joo and Koak, Jai-Young 2002. Hydroxyapatite-based composite for dental implants: Anin vivo removal torque experiment. Journal of Biomedical Materials Research, Vol. 63, Issue. 6, p. 714.
Lee, I.-S. Whang, C.-N. Lee, G.H. Cui, F.-Z. and Ito, A. 2003. Effects of ion beam assist on the formation of calcium phosphate film. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 206, Issue. , p. 522.
Kim, Dong-Hwan Kong, Young-Min Lee, Su-Hee Lee, In-Seop Kim, Hyoun-Ee Heo, Seong-Joo and Koak, Jai-Young 2003. Composition and Crystallization of Hydroxyapatite Coating Layer Formed by Electron Beam Deposition. Journal of the American Ceramic Society, Vol. 86, Issue. 1, p. 186.
Lee, In-Seop Park, Jong-Chul and Lee, Young-Hee 2003. Plasma processing of materials for medical applications. Surface and Coatings Technology, Vol. 171, Issue. 1-3, p. 252.
Lee, In Seop Park, Jong Chul Kim, Soo Ryong Seo, Won Seon Cho, S.B. and Jung, Young Chul 2003. Variation in Biological Properties of Thin Calcium Phosphate Films Formed by e-Beam Evaporation. Key Engineering Materials, Vol. 240-242, Issue. , p. 291.
Kim, Hae-Won Kong, Young-Min Bae, Chang-Jun Noh, Yoon-Jung and Kim, Hyoun-Ee 2004. Sol–gel derived fluor-hydroxyapatite biocoatings on zirconia substrate. Biomaterials, Vol. 25, Issue. 15, p. 2919.
Li, S.J. Niinomi, M. Akahori, T. Kasuga, T. Yang, R. and Hao, Y.L. 2004. Fatigue characteristics of bioactive glass-ceramic-coated Ti–29Nb–13Ta–4.6Zr for biomedical application. Biomaterials, Vol. 25, Issue. 17, p. 3369.
Kim, Hae-Won Kim, Hyoun-Ee and Knowles, Jonathan C. 2004. Hard-tissue-engineered zirconia porous scaffolds with hydroxyapatite sol-gel and slurry coatings. Journal of Biomedical Materials Research, Vol. 70B, Issue. 2, p. 270.
Rabiei, Afsaneh and Thomas, Brent 2004. Processing and Development of Nano-Scale HA coatings for Biomedical Application. MRS Proceedings, Vol. 845, Issue. ,
Kim, Hae-Won Georgiou, George Knowles, Jonathan C. Koh, Young-Hag and Kim, Hyoun-Ee 2004. Calcium phosphates and glass composite coatings on zirconia for enhanced biocompatibility. Biomaterials, Vol. 25, Issue. 18, p. 4203.
Li, S.J Yang, R Niinomi, M Hao, Y.L and Cui, Y.Y 2004. Formation and growth of calcium phosphate on the surface of oxidized Ti–29Nb–13Ta–4.6Zr alloy. Biomaterials, Vol. 25, Issue. 13, p. 2525.
Kim, Hae-Won Kim, Hyoun-Ee Salih, Vehid and Knowles, Jonathan C. 2005. Sol-gel-modified titanium with hydroxyapatite thin films and effect on osteoblast-like cell responses. Journal of Biomedical Materials Research Part A, Vol. 74A, Issue. 3, p. 294.
Kim, Hae-Won Kim, Hyoun-Ee Salih, Vehid and Knowles, Jonathan C. 2005. Hydroxyapatite and titania sol-gel composite coatings on titanium for hard tissue implants; Mechanical andin vitro biological performance. Journal of Biomedical Materials Research, Vol. 72B, Issue. 1, p. 1.
Kim, Hae-Won Yoon, Byung-Ho Koh, Young-Hag and Kim, Hyoun-Ee 2006. Processing and Performance of Hydroxyapatite/Fluorapatite Double Layer Coating on Zirconia by the Powder Slurry Method. Journal of the American Ceramic Society, Vol. 89, Issue. 8, p. 2466.
Lee, Su-Hee Kim, Hae-Won Lee, Eun-Jung Li, Long-Hao and Kim, Hyoun-Ee 2006. Hydroxyapatite-TiO2 Hybrid Coating on Ti Implants. Journal of Biomaterials Applications, Vol. 20, Issue. 3, p. 195.
Lee, In-Seop Zhao, Baohong Lee, Gun-Hwan Choi, Seong-Ho and Chung, Sung-Min 2007. Industrial application of ion beam assisted deposition on medical implants. Surface and Coatings Technology, Vol. 201, Issue. 9-11, p. 5132.
Kamitakahara, Masanobu Ohtsuki, Chikara and Miyazaki, Toshiki 2007. Coating of bone-like apatite for development of bioactive materials for bone reconstruction. Biomedical Materials, Vol. 2, Issue. 4, p. R17.
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A hydroxyapatite [HAp; Ca10(PO4)6(OH)2] coating layer was formed on a Ti-based alloy by the electron-beam deposition method. When pure HAp was used as a target for the deposition, an amorphous layer was formed on the metal substrate. By heat treatment in a vacuum at 630 °C, the layer was crystallized into tricalcium phosphate [Ca3(PO4)2]. The crystallization improved the dissolution rate of the layer remarkably; however, at the same time, it deteriorated the bond strength with the substrate. When extra CaO (up to 25 wt%) was added to the target and processed under the same conditions, a layer compositionally close to crystalline HAp was deposited. Before the heat treatment, even though the layer was in amorphous state, the dissolution rate in the physiological solution was extremely low. Furthermore, the bond strength increased remarkably compared to the layer formed by the pure HAp target. Compositional and structural resemblance of the layer with the crystalline HAp was attributed to these improvements in properties.
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