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Efficient visible light degradation of dyes in wastewater by nickel–phosphorus plating–titanium dioxide complex electroless plating fabric

  • Xiaodong Ding (a1), Wei Wang (a2), Ao Zhang (a2), Lishan Zhang (a3) and Dan Yu (a1)...


Dyeing wastewater has caused serious environmental problems nowadays. In this work, nickel–phosphorus plating–titanium dioxide (Ni-P-TiO2) electroless plating polyimide (PI) fabric was fabricated as an excellent visible light response composite. First, polyaniline (PANI) was in situ polymerized on the surface of the PI fabric. Second, PANI reduced palladium ions to be active seeds for initiating electroless plating of Ni-P-TiO2 layer. Finally, the Ni-P-TiO2/PANI/PI fabric with all-in-one structure was prepared, which can effectively overcome the drawbacks of poor loading fastness and insensitivity to visible light response. It was characterized by scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, thermogravimetric analysis, and ultraviolet–visible diffuse reflectance spectroscopy. The photocatalytic activity was evaluated by degrading reactive blue 19, methylene blue, and reactive red (M-3BE) under visible light irradiation. The results show that the degradation rates of the all three dyes were over 91% with robust cycle stability for repeated 5 cycles of use. The possible photocatalytic degradation mechanism of fabrics was also proposed based on free radical and hole removal experiments.


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1.Chowdhury, S. and Saha, P.: Adsorption kinetic modeling of safranin onto rice husk biomatrix using pseudo-first-and pseudo-second-order kinetic models: Comparison of linear and non-linear methods. Clean: Soil, Air, Water 39, 274 (2011).
2.Hayat, H., Mahmood, Q., Pervez, A., Bhatti, Z.A., and Baig, S.A.: Comparative decolorization of dyes in textile wastewater using biological and chemical treatment. Sep. Purif. Technol. 154, 149 (2015).
3.Liang, C-Z., Sun, S-P., Li, F-Y., Ong, Y-K., and Chung, T-S.: Treatment of highly concentrated wastewater containing multiple synthetic dyes by a combined process of coagulation/flocculation and nanofiltration. J. Membr. Sci. 469, 306 (2014).
4.Labanda, J., Sabate, J., and Llorens, J.: Experimental and modeling study of the adsorption of single and binary dye solutions with an ion-exchange membrane adsorber. Chem. Eng. J. 166, 536 (2011).
5.Ramirez, G., Javier Recio, F., Herrasti, P., Ponce-de-Leon, C., and Sires, I.: Effect of RVC porosity on the performance of PbO2 composite coatings with titanate nanotubes for the electrochemical oxidation of azo dyes. Electrochim. Acta 204, 9 (2016).
6.Hu, F., Fang, C., Wang, Z., Liu, C., Zhu, B., and Zhu, L.: Poly(N-vinyl imidazole) gel composite porous membranes for rapid separation of dyes through permeating adsorption. Sep. Purif. Technol. 188, 1 (2017).
7.Wang, A., Wang, Y., Yu, W., Huang, Z., Fang, Y., Long, L., Song, Y., Cifuentes, M.P., Humphrey, M.G., Zhang, L., Shao, J., and Zhang, C.: TiO2-multi-walled carbon nanotube nanocomposites: Hydrothermal synthesis and temporally-dependent optical properties. RSC Adv. 6, 20120 (2016).
8.Li, X., Xie, J., Jiang, C., Yu, J., and Zhang, P.: Review on design and evaluation of environmental photocatalysts. Front. Environ. Sci. Eng. 12, 44 (2018).
9.Liu, S., Wang, Y., Ma, L., and Zhang, H.: Ni2P/ZnS (CdS) core/shell composites with their photocatalytic performance. J. Mater. Res. 33, 3580 (2018).
10.Pham, T-T., Nguyen-Huy, C., and Shin, E.W.: Facile one-pot synthesis of nickel-incorporated titanium dioxide/graphene oxide composites: Enhancement of photodegradation under visible-irradiation. Appl. Surf. Sci. 377, 301 (2016).
11.Liu, S., Chen, J., Xu, D., Zhang, X., and Shen, M.: Enhanced photocatalytic activity of direct Z-scheme Bi2O3/g-C3N4 composites via facile one-step fabrication. J. Mater. Res. 33, 1391 (2018).
12.Wang, M., Fang, M., Tang, C., Zhang, L., Huang, Z., Liu, Y.g., and Wu, X.: A C3N4/Bi2WO6 organic-inorganic hybrid photocatalyst with a high visible-light-driven photocatalytic activity. J. Mater. Res. 31, 713 (2016).
13.Yu, H., Liu, W., Wang, X., and Wang, F.: Promoting the interfacial H2-evolution reaction of metallic Ag by Ag2S cocatalyst: A case study of TiO2/Ag-Ag2S photocatalyst. Appl. Catal., B 225, 415 (2018).
14.Fujishima, A. and Honda, K.: Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37 (1972).
15.Liu, J. and Zhang, J.: Photocatalytic activity enhancement of TiO2 nanocrystalline thin film with surface modification of poly-3-hexylthiophene by in situ polymerization. J. Mater. Res. 31, 1448 (2016).
16.Wen, J., Li, X., Liu, W., Fang, Y., Xie, J., and Xu, Y.: Photocatalysis fundamentals and surface modification of TiO2 nanomaterials. Chin. J. Catal. 36, 2049 (2015).
17.Savinkina, E.V., Obolenskaya, L.N., Kuzmicheva, G.M., Morozov, I.D., and Chumakov, R.G.: Effects of peroxo precursors and annealing temperature on properties and photocatalytic activity of nanoscale titania. J. Mater. Res. 33, 1422 (2018).
18.Abid, M., Bouattour, S., Ferraria, A.M., Conceicao, D.S., Carapeto, A.P., Vieira Ferreira, L.F., Botelho do Rego, A.M., Rei Vilar, M., and Boufi, S.: Functionalization of cotton fabrics with plasmonic photo-active nanostructured Au-TiO2 layer. Carbohydr. Polym. 176, 336 (2017).
19.Pan, Y., Shen, Y., Jin, Q., and Zhu, S.: Promotional effect of Ba additives on MnCeOx/TiO2 catalysts for NH3-SCR of NO at low temperature. J. Mater. Res. 33, 2414 (2018).
20.Zhang, W., Wang, C., Liu, X., and Li, J.: Enhanced photocatalytic activity in porphyrin-sensitized TiO2 nanorods. J. Mater. Res. 32, 2773 (2017).
21.Yang, J., Yan, H., Wang, X., Wen, F., Wang, Z., Fan, D., Shi, J., and Li, C.: Roles of cocatalysts in Pt-PdS/CdS with exceptionally high quantum efficiency for photocatalytic hydrogen production. J. Catal. 290, 151 (2012).
22.Zhang, G., Miao, H., Hu, X., Mu, J., Liu, X., Han, T., Fan, J., Liu, E., Yin, Y., and Wan, J.: A facile strategy to fabricate Au/TiO2 nanotubes photoelectrode with excellent photoelectrocatalytic properties. Appl. Surf. Sci. 391, 345 (2017).
23.Chen, F., An, W., Li, Y., Liang, Y., and Cui, W.: Fabricating 3D porous PANI/TiO2-graphene hydrogel for the enhanced UV-light photocatalytic degradation of BPA. Appl. Surf. Sci. 427, 123 (2018).
24.Liu, F., Yan, X., Chen, X., Tian, L., Xia, Q., and Chen, X.: Mesoporous TiO2 nanoparticles terminated with carbonate-like groups: Amorphous/crystalline structure and visible-light photocatalytic activity. Catal. Today 264, 243 (2016).
25.Li, Y., Song, X., Wei, Z., Zhang, J., Qin, L., and Ye, S.: Preparation and property of Mo-doped visible-light response titaniumdioxide photocatalyst. J. Spectrosc. 2014, 15 (2014).
26.Xu, Y. and Xu, R.: Nickel-based cocatalysts for photocatalytic hydrogen production. Appl. Surf. Sci. 351, 779 (2015).
27.Wada, N., Yokomizo, Y., Yogi, C., Katayama, M., Tanaka, A., Kojima, K., Inada, Y., and Ozutsumi, K.: Effect of adding Au nanoparticles to TiO2 films on crystallization, phase transformation, and photocatalysis. J. Mater. Res. 33, 467 (2018).
28.Komatsuda, S., Asakura, Y., Vequizo, J.J.M., Yamakata, A., and Yin, S.: Enhanced photocatalytic NO, decomposition of visible-light responsive F-TiO2/(N,C)-TiO2 by charge transfer between F-TiO2 and (N,C)-TiO2 through their doping levels. Appl. Catal., B 238, 358 (2018).
29.Mishra, G., Parida, K.M., and Singh, S.K.: Facile fabrication of S-TiO2/β-SiC nanocomposite photocatalyst for hydrogen evolution under visible light irradiation. ACS Sustainable Chem. Eng. 3, 245 (2015).
30.Jing, H., Cheng, Q., Weller, J.M., Chu, X.S., Wang, Q.H., and Chan, C.K.: Synthesis of TiO2 nanosheet photocatalysts from exfoliation of TiS2 and hydrothermal treatment. J. Mater. Res. 33, 3540 (2018).
31.Song, Y., Li, J., and Wang, C.: Modification of porphyrin/dipyridine metal complexes on the surface of TiO2 nanotubes with enhanced photocatalytic activity for photoreduction of CO2 into methanol. J. Mater. Res. 33, 2612 (2018).
32.Huang, Y., Ho, W., Ai, Z., Song, X., Zhang, L., and Lee, S.: Aerosol-assisted flow synthesis of B-doped, Ni-doped and B–Ni-codoped TiO2 solid and hollow microspheres for photocatalytic removal of NO. Appl. Catal., B 89, 398 (2009).
33.Zou, M.M., Feng, L., Ganeshraja, A.S., Xiong, F.Q., and Yang, M.H.: Defect induced nickel, nitrogen-codoped mesoporous TiO2 microspheres with enhanced visible light photocatalytic activity. Solid State Sci. 60, 1 (2016).
34.Pelaez, M., Nolan, N.T., Pillai, S.C., Seery, M.K., Falaras, P., Kontos, A.G., Dunlop, P.S.M., Hamilton, J.W.J., Byrne, J.A., O’Shea, K., Entezari, M.H., and Dionysiou, D.D.: A review on the visible light active titanium dioxide photocatalysts for environmental applications. Appl. Catal., B 125, 331 (2012).
35.Yang, L., Gao, Y., Wang, F., Liu, P., and Hu, S.: Enhanced photocatalytic performance of cementitious material with TiO2@Ag modified fly ash micro-aggregates. Chin. J. Catal. 38, 357 (2017).
36.Rodríguez-González, V., Ruiz-Gomez, M.A., Torres-Martinez, L.M., and Gomez, R.: Photocatalytic decomposition of synthetic alizarin red S by nickel doped TiO2. Top. Catal. 54, 490 (2011).
37.Li, X., Wu, Y., Shen, Y., Sun, Y., Yang, Y., and Xie, A.: A novel bifunctional Ni-doped TiO2 inverse opal with enhanced SERS performance and excellent photocatalytic activity. Appl. Surf. Sci. 427, 739 (2018).
38.Akti, F.: Photocatalytic degradation of remazol yellow using polyaniline-doped tin oxide hybrid photocatalysts with diatomite support. Appl. Surf. Sci. 455, 931 (2018).
39.Yan, Y., Chen, T., Zou, Y., and Wang, Y.: Biotemplated synthesis of Au loaded Sn-doped TiO2 hierarchical nanorods using nanocrystalline cellulose and their applications in photocatalysis. J. Mater. Res. 31, 1383 (2016).
40.Hao, Z., Ruilong, Z., Jincai, Z., and Yongfa, Z.: Dramatic visible photocatalytic degradation performances due to synergetic effect of TiO2 with PANI. Environ. Sci. Technol. 42, 3803 (2008).
41.Li, Q., Zhang, C., and Li, J.: Photocatalysis and wave-absorbing properties of polyaniline/TiO2 microbelts composite by in situ polymerization method. Appl. Surf. Sci. 257, 944 (2010).
42.Jiang, L., Syed, J.A., Gao, Y., Lu, H., and Meng, X.: Electrodeposition of Ni(OH)2 reinforced polyaniline coating for corrosion protection of 304 stainless steel. Appl. Surf. Sci. 440, 1011 (2018).
43.Qiu, H., Han, X., Qiu, F., and Yang, J.: Facile route to covalently-jointed graphene/polyaniline composite and it’s enhanced electrochemical performances for supercapacitors. Appl. Surf. Sci. 376, 261 (2016).
44.Wu, W., Zhang, W., Long, Y., Qin, J., Wen, H., and Ma, J.: Ni modified Pd nanoparticles immobilized on hollow nitrogen doped carbon spheres for the simehydrogenation of phenylacetylene. J. Colloid Interface Sci. 531, 642 (2018).
45.Chen, J., Liu, R., Guo, Y., Chen, L., and Gao, H.: Selective hydrogenation of biomass-based 5-hydroxymethylfurfural over catalyst of palladium immobilized on amine-functionalized metal–organic frameworks. ACS Catal. 5, 722 (2014).
46.Xu, L., Yang, L., Johansson, E.M.J., Wang, Y., and Jin, P.: Photocatalytic activity and mechanism of bisphenol a removal over TiO2–x/rGO nanocomposite driven by visible light. Chem. Eng. J. 350, 1043 (2018).
47.Bahgat Radwan, A., Ali, K., Shakoor, R.A., Mohammed, H., Alsalama, T., Kahraman, R., Yusuf, M.M., Abdullah, A.M., Fatima Montemor, M., and Helal, M.: Properties enhancement of Ni-P electrodeposited coatings by the incorporation of nanoscale Y2O3 particles. Appl. Surf. Sci. 457, 956 (2018).
48.Cao, M., Wang, P., Ao, Y., Wang, C., Hou, J., and Qian, J.: Photocatalytic degradation of tetrabromobisphenol A by a magnetically separable graphene–TiO2 composite photocatalyst: Mechanism and intermediates analysis. Chem. Eng. J. 264, 113 (2015).
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Journal of Materials Research
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