Skip to main content Accessibility help

We use cookies to distinguish you from other users and to provide you with a better experience on our websites. Close this message to accept cookies or find out how to manage your cookie settings.

Close cookie message
×
Home
  • Home
Hostname: page-component-559fc8cf4f-s5ss2 Total loading time: 0.913 Render date: 2021-03-01T06:19:27.389Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "metricsAbstractViews": false, "figures": false, "newCiteModal": false, "newCitedByModal": true }
EnglishFrançais
Journal of Materials Research Journal of Materials Research

Article contents

Yttria-stabilized hafnia: Thermochemistry of formation and hydration of nanoparticles

Published online by Cambridge University Press:  02 March 2012

Wei Zhou ,
Sergey V. Ushakov  and
Alexandra Navrotsky
Wei Zhou
Affiliation:
Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California–Davis, Davis, California 95616
Sergey V. Ushakov
Affiliation:
Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California–Davis, Davis, California 95616
Alexandra Navrotsky
Affiliation:
Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California–Davis, Davis, California 95616
Corresponding
E-mail address:
anavrotsky@ucdavis.edu
Get access

Abstract

The surface enthalpy of yttria-stabilized hafnia (YSH) (YxHf1 − xO2 − x/2) with different compositions was directly measured by a combination of high-temperature oxide-melt solution calorimetry and water adsorption calorimetry. The surface enthalpies for hydrated surfaces are 0.27 ± 0.06 J/m2 for x = 0.1, 0.77 ± 0.09 J/m2 for x = 0.17, and 1.30 ± 0.09 J/m2 for x = 0.24; and those for anhydrous surfaces are 0.51 ± 0.06, 1.08 ± 0.13, and 1.76 ± 0.09 J/m2 respectively. The enthalpies of both hydrated and anhydrous surfaces increase approximately linearly (R2 > 0.93) with increasing yttrium concentration. The surface enthalpies of Y0.1Hf0.9O1.95 were used to approximate those for pure anhydrous cubic hafnia. Combining the data relating to surface energies for monoclinic hafnia from our previous work and estimated data for tetragonal hafnia, a tentative stability map of HfO2 polymorphs as a function of surface area (SA) was constructed.

Keywords

yttria-stabilized hafnia surface enthalpy calorimetry
Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 7 , 14 April 2012 , pp. 1022 - 1028
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below.
If you should have access and can't see this content please contact technical support.

References

1.Luo, X., Zhou, W., Ushakov, S.V., Navrotsky, A., and Demkov, A.A.: Monoclinic to tetragonal transformations in hafnia and zirconia: A combined calorimetric and density functional study. Phys. Rev. B 80, 134119 (2009).CrossRefGoogle Scholar
2.Wang, C., Zinkevich, M., and Aldinger, F.: The zirconia-hafnia system: DTA measurements and thermodynamic calculations. J. Am. Ceram. Soc. 89, 3751 (2006).CrossRefGoogle Scholar
3.Curtis, C.E., Doney, L.M., and Johnson, J.R.: Some properties of hafnium oxide, hafnium silicate, calcium hafnate, and hafnium carbide. J. Am. Ceram. Soc. 37, 458 (1954).CrossRefGoogle Scholar
4.Stacy, D.W. and Wilder, D.R.: The yttria-hafnia system. J. Am. Ceram. Soc. 58, 285 (1975).CrossRefGoogle Scholar
5.Luo, X., Demkov, A.A., Triyoso, D., Fejes, P., Gregory, R., and Zollner, S.: Combined experimental and theoretical study of thin hafnia films. Phys. Rev. B 78, 245314 (2008).CrossRefGoogle Scholar
6.Kim, H., McIntyre, P.C., and Saraswat, K.C.: Effects of crystallization on the electrical properties of ultrathin HfO2 dielectrics grown by atomic layer deposition. Appl. Phys. Lett. 82, 106 (2003).CrossRefGoogle Scholar
7.Aarik, J., Aidla, A., Mandar, H., Uustare, T., Kukli, K., and Schuisky, M.: Phase transformations in hafnium dioxide thin films grown by atomic layer deposition at high temperatures. Appl. Surf. Sci. 173, 15 (2001).CrossRefGoogle Scholar
8.Shandalov, M. and McIntyre, P.C.: Size-dependent polymorphism in HfO2 nanotubes and nanoscale thin films. J. Appl. Phys. 106, 084322 (2009).CrossRefGoogle Scholar
9.Aarik, J., Aidla, A., Mandar, H., Sammelselg, V., and Uustare, T.: Texture development in nanocrystalline hafnium dioxide thin films grown by atomic layer deposition. J. Cryst. Growth 220, 105 (2000).CrossRefGoogle Scholar
10.Ranade, M.R., Navrotsky, A., Zhang, H.Z., Banfield, J.F., Elder, S.H., Zaban, A., Borse, P.H., Kulkarni, S.K., Doran, G.S., and Whitfield, H.J.: Energetics of nanocrystalline TiO2. Proc. Natl. Acad. Sci. U.S.A. 99, 6476 (2002).CrossRefGoogle ScholarPubMed
11.Levchenko, A.A., Li, G.S., Boerio-Goates, J., Woodfield, B.F., and Navrotsky, A.: TiO2 stability landscape: Polymorphism, surface energy, and bound water energetics. Chem. Mater. 18, 6324 (2006).CrossRefGoogle Scholar
12.McHale, J.M., Auroux, A., Perrotta, A.J., and Navrotsky, A.: Surface energies and thermodynamic phase stability in nanocrystalline aluminas. Science 277, 788 (1997).CrossRefGoogle Scholar
13.McHale, J.M., Navrotsky, A., and Perrotta, A.J.: Effects of increased surface area and chemisorbed H2O on the relative stability of nanocrystalline gamma-Al2O3 and alpha-Al2O3. J. Phys. Chem. B 101, 603 (1997).CrossRefGoogle Scholar
14.Bomati-Miguel, O., Mazeina, L., Navrotsky, A., and Veintemillas-Verdaguer, S.: Calorimetric study of maghemite nanoparticles synthesized by laser-induced pyrolysis. Chem. Mater. 20, 591 (2008).CrossRefGoogle Scholar
15.Mazeina, L. and Navrotsky, A.: Surface enthalpy of goethite. Clays Clay Miner. 53, 113 (2005).CrossRefGoogle Scholar
16.Pitcher, M.W., Ushakov, S.V., Navrotsky, A., Woodfield, B.F., Li, G.S., Boerio-Goates, J., and Tissue, B.M.: Energy crossovers in nanocrystalline zirconia. J. Am. Ceram. Soc. 88, 160 (2005).CrossRefGoogle Scholar
17.Radha, A.V., Bomati-Miguel, O., Ushakov, S.V., Navrotsky, A., and Tartaj, P.: Surface enthalpy, enthalpy of water adsorption, and phase stability in nanocrystalline monoclinic zirconia. J. Am. Ceram. Soc. 92, 133 (2009).CrossRefGoogle Scholar
18.Navrotsky, A.: Progress and new directions in high temperature calorimetry revisited. Phys. Chem. Miner. 24, 222 (1997).CrossRefGoogle Scholar
19.Zhou, W., Ushakov, S.V., Wang, T., Ekerdt, J.G., Demkov, A.A., and Navrotsky, A.: Hafnia: Energetics of thin films and nanoparticles. J. Appl. Phys. 107, 123514 (2010).CrossRefGoogle Scholar
20.Ushakov, S.V. and Navrotsky, A.: Direct measurements of water adsorption enthalpy on hafnia and zirconia. Appl. Phys. Lett. 87, 3 (2005).CrossRefGoogle Scholar
21.Lee, T.A. and Navrotsky, A.: Enthalpy of formation of cubic yttria-stabilized hafnia. J. Mater. Res. 19, 1855 (2004).CrossRefGoogle Scholar
22.Ushakov, S.V., Brown, C.E., and Navrotsky, A.: Effect of La and Y on crystallization temperatures of hafnia and zirconia. J. Mater. Res. 19, 693 (2004).CrossRefGoogle Scholar
23.Brunauer, S., Emmett, P.H., and Teller, E.: Adsorption of gases in multimolecular layers. J. Am. Chem. Soc. 60, 309 (1938).CrossRefGoogle Scholar
24.Costa, G.C., Ushakov, S.V., Castro, R.H., Navrotsky, A., and Muccillo, R.: Calorimetric measurement of surface and interface enthalpies of yttria stabilized zirconia (YSZ). Chem. Mater. 22, 2937 (2010).CrossRefGoogle Scholar
25.Shvareva, T.Y., Ushakov, S.V., Navrotsky, A., Libera, J.A., and Elam, J.W.: Thermochemistry of nanoparticles on a substrate: Zinc oxide on amorphous silica. J. Mater. Res. 23, 1907 (2008).CrossRefGoogle Scholar
26.Robie, R.A., Hemingway, B.S., and Fisher, J.R.: Thermodynamic Properties of Minerals and Related Substances at 298.15 K and 1 Bar Pressure and at Higher Temperatures. (U.S. Geol. Surv. Bull. 1452, Washington, DC, 1978) p. 172.Google Scholar
27.Wu, K. and Jin, Z.: Thermodynamic assessment of the HfO2-YO1.5, quasibinary system. Calphad 21, 421 (1997).CrossRefGoogle Scholar
28.Zhang, P., Navrotsky, A., Guo, B., Kennedy, I., Clark, A.N., Charles, L., and Liu, Q.: Energetics of cubic and monoclinic yttrium oxide polymorphs: Phase transitions, surface enthalpies, and stability at the nanoscale. J. Phys. Chem. C 112, 932 (2008).CrossRefGoogle Scholar
29.Murase, Y. and Kato, E.: Phase transformation of zirconia by Ball-Milling. J. Am. Ceram. Soc. 62, 527 (1979).CrossRefGoogle Scholar
30.Murase, Y. and Kato, E.: Role of water vapor in crystallite growth and tetragonal-monoclinic phase transformation of zirconia. J. Am. Ceram. Soc. 66, 196 (1983).CrossRefGoogle Scholar

Full text views

Full text views reflects PDF downloads, PDFs sent to Google Drive, Dropbox and Kindle and HTML full text views.

Total number of HTML views: 43
Total number of PDF views: 74 *
View data table for this chart

* Views captured on Cambridge Core between September 2016 - 1st March 2021. This data will be updated every 24 hours.

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Yttria-stabilized hafnia: Thermochemistry of formation and hydration of nanoparticles
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

Yttria-stabilized hafnia: Thermochemistry of formation and hydration of nanoparticles
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

Yttria-stabilized hafnia: Thermochemistry of formation and hydration of nanoparticles
Available formats
×
×

Reply to: Submit a response

Your details

Conflicting interests

Do you have any conflicting interests? *