Skip to main content Accessibility help
×
Home
Hostname: page-component-5bf98f6d76-sglwb Total loading time: 0.317 Render date: 2021-04-20T16:22:57.686Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "metricsAbstractViews": false, "figures": false, "newCiteModal": false, "newCitedByModal": true }

Solvothermal synthesis and electromagnetic absorption properties of pyramidal Ni superstructures

Published online by Cambridge University Press:  15 July 2014

Biao Zhao
Affiliation:
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, Henan 450001, People's Republic of China
Gang Shao
Affiliation:
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, Henan 450001, People's Republic of China
Bingbing Fan
Affiliation:
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, Henan 450001, People's Republic of China
Yajun Xie
Affiliation:
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, Henan 450001, People's Republic of China
Binbin Wang
Affiliation:
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, Henan 450001, People's Republic of China
Rui Zhang
Affiliation:
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, Henan 450001, People's Republic of China; and Zhengzhou Aeronautical Institute of Industry Management, Zhengzhou, Henan 450046, People's Republic of China
Corresponding
E-mail address:
Get access

Abstract

The submicrometer Ni cones have been successfully prepared through a simple solvothermal method in glycerol. The as-prepared products were extensively characterized by x-ray diffraction, field emission scanning electron microscopy, energy-dispersive x-ray spectroscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis. The effects of the volume ratios of glycerol to water, and the concentration of alkali on morphologies of Ni samples were investigated. The electromagnetic wave absorption properties of Ni cones were evaluated based on the relative complex permeability (μr) and permittivity (εr). A minimum reflection loss (RL) of −41.6 dB was observed at 4.7 GHz with the thickness of 3.8 mm and the RL values below −10 dB were obtained in the range of 3.9–15.0 GHz with the corresponding thickness of 1.8–3.8 mm. The excellent wave absorption properties of the obtained products are due to the synergic effect of dielectric loss and magnetic loss, geometry effect and unique morphology.

Type
Articles
Copyright
Copyright © Materials Research Society 2014 

Access options

Get access to the full version of this content by using one of the access options below.

References

Tong, G., Wu, W., Qiao, R., Yuan, J., Guan, J., and Qian, H.: Morphology dependence of static magnetic and microwave electromagnetic characteristics of polymorphic Fe3O4 nanomaterials. J. Mater. Res. 26, 1639 (2011).CrossRefGoogle Scholar
Tong, G., Ma, J., Wu, W., Hua, Q., Qiao, R., and Qian, H.: Grinding speed dependence of microstructure, conductivity, and microwave electromagnetic and absorbing characteristics of the flaked Fe particles. J. Mater. Res. 26, 682 (2011).CrossRefGoogle Scholar
Gong, Y-X., Zhen, L., Jiang, J-T., Xu, C-Y., Wang, W-S., and Shao, W-Z.: Synthesis of Fe-ferrite composite nanotubes with excellent microwave absorption performance. CrystEngComm 13, 6839 (2011).CrossRefGoogle Scholar
Du, L., Du, Y., Li, Y., Wang, J., Wang, C., Wang, X., Xu, P., and Han, X.: Surfactant-assisted solvothermal synthesis of Ba(CoTi)xFe12−2xO19 nanoparticles and enhancement in microwave absorption properties of polyaniline. J. Phys. Chem. C 114, 19600 (2010).CrossRefGoogle Scholar
Hu, Q., Tong, G., Wu, W., Liu, F., Qian, H., and Hong, D.: Selective preparation and enhanced microwave electromagnetic characteristics of polymorphous ZnO architectures made from a facile one-step ethanediamine-assisted hydrothermal approach. CrystEngComm 15, 1314 (2013).CrossRefGoogle Scholar
Du, F., Tong, G., Tong, C., Liu, Y., and Tao, J.: Selective synthesis and shape-dependent microwave electromagnetic properties of polymorphous ZnO complex architectures. J. Mater. Res. 29, 649 (2014).CrossRefGoogle Scholar
He, C., Qiu, S., Wang, X., Liu, J., Luan, L., Liu, W., Itoh, M., and Machida, K-i.: Facile synthesis of hollow porous cobalt spheres and their enhanced electromagnetic properties. J. Mater. Chem. 22, 22160 (2012).CrossRefGoogle Scholar
Gong, C., Zhang, J., Zhang, X., Yu, L., Zhang, P., Wu, Z., and Zhang, Z.: Strategy for ultrafine Ni fibers and investigation of the electromagnetic characteristics. J. Phys. Chem. C 114(22), 10101 (2010).CrossRefGoogle Scholar
Yu, Z., Yao, Z., Zhang, N., Wang, Z., Li, C., Han, X., Wu, X., and Jiang, Z.: Electric field-induced synthesis of dendritic nanostructured α-Fe for electromagnetic absorption application. J. Mater. Chem. A 1, 4571 (2013).CrossRefGoogle Scholar
Wu, J. and Kong, L.: High microwave permittivity of multiwalled carbon nanotube composites. Appl. Phys. Lett. 84, 4956 (2004).CrossRefGoogle Scholar
Wang, Z., Wu, L., Zhou, J., Cai, W., Shen, B., and Jiang, Z.: Magnetite nanocrystals on multiwalled carbon nanotubes as a synergistic microwave absorber. J. Phys. Chem. C 117, 5446 (2013).CrossRefGoogle Scholar
Tong, G., Liu, F., Wu, W., Du, F., and Guan, J.: Rambutanlike Ni/MWCNT heterostructures: Easy synthesis, formation mechanism, and controlled static magnetic and microwave electromagnetic characteristics. J. Mater. Chem. A 2, 7373 (2014) DOI: 10.1039/c4ta00117f.CrossRefGoogle Scholar
Tong, G., Hu, Q., Wu, W., Li, W., Qian, H., and Liang, Y.: Submicrometer-sized NiO octahedra: Facile one-pot solid synthesis, formation mechanism, and chemical conversion into Ni octahedra with excellent microwave-absorbing properties. J. Mater. Chem. 22, 17494 (2012).CrossRefGoogle Scholar
Sun, G., Dong, B., Cao, M., Wei, B., and Hu, C.: Hierarchical dendrite-like magnetic materials of Fe3O4, γ-Fe2O3, and Fe with high performance of microwave absorption. Chem. Mater. 23, 1587 (2011).CrossRefGoogle Scholar
Gao, B., Qiao, L., Wang, J., Liu, Q., Li, F., Feng, J., and Xue, D.: Microwave absorption properties of the Ni nanowires composite. J. Phys. D: Appl. Phys. 41, 235005 (2008).CrossRefGoogle Scholar
Wang, Z., Zou, J., Ding, Z., Wu, J., Wang, P., Jin, S., and Bi, H.: Magnetic and microwave absorption properties of Ni microcrystals with hierarchical branch-like and flowers-like shapes. Mater. Chem. Phys. 142, 119 (2013).CrossRefGoogle Scholar
Liu, T., Zhou, P., Xie, J., and Deng, L.: Electromagnetic and absorption properties of urchinlike Ni composites at microwave frequencies. J. Appl. Phys. 111, 093905 (2012).CrossRefGoogle Scholar
Ni, X., Zhao, Q., Zheng, H., Li, B., Song, J., Zhang, D., and Zhang, X.: A novel chemical reduction route towards the synthesis of crystalline nickel nanoflowers from a mixed source. Eur. J. Inorg. Chem. 2005, 4788 (2005).CrossRefGoogle Scholar
Carenco, S., Boissière, C., Nicole, L., Sanchez, C., Le Floch, P., and Mézailles, N.: Controlled design of size-tunable monodisperse nickel nanoparticles. Chem. Mater. 22, 1340 (2010).CrossRefGoogle Scholar
Chen, T., Deng, F., Zhu, J., Chen, C., Sun, G., Ma, S., and Yang, X.: Hexagonal and cubic Ni nanocrystals grown on graphene: Phase-controlled synthesis, characterization and their enhanced microwave absorption properties. J. Mater. Chem. 22, 15190 (2012).CrossRefGoogle Scholar
Wang, H., Jiao, X., and Chen, D.: Monodispersed nickel nanoparticles with tunable phase and size: Synthesis, characterization, and magnetic properties. J. Phys. Chem. C 112, 18793 (2008).CrossRefGoogle Scholar
An, Z., Pan, S., and Zhang, J.: Synthesis and tunable assembly of spear-like nickel nanocrystallites: From urchin-like particles to prickly chains. J. Phys. Chem. C 113, 1346 (2009).CrossRefGoogle Scholar
Guan, J., Liu, L., Xu, L., Sun, Z., and Zhang, Y.: Nickel flower-like nanostructures composed of nanoplates: One-pot synthesis, stepwise growth mechanism and enhanced ferromagnetic properties. CrystEngComm 13, 2636 (2011).CrossRefGoogle Scholar
Zhao, L., Zhang, H., Xing, Y., Song, S., Yu, S., Shi, W., Guo, X., Yang, J., Lei, Y., and Cao, F.: Morphology-controlled synthesis of magnetites with nanoporous structures and excellent magnetic properties. Chem. Mater. 20, 198 (2007).CrossRefGoogle Scholar
Ni, X., Zhang, Y., Song, J., and Zheng, H.: Solvent mediated assembly of nickel crystallites: From chains to isolated spheres. J. Cryst. Growth 299, 365 (2007).CrossRefGoogle Scholar
Joseyphus, R.J., Matsumoto, T., Takahashi, H., Kodama, D., Tohji, K., and Jeyadevan, B.: Designed synthesis of cobalt and its alloys by polyol process. J. Solid State Chem. 180, 3008 (2007).CrossRefGoogle Scholar
Ung, D., Viau, G., Ricolleau, C., Warmont, F., Gredin, P., and Fiévet, F.: CoNi nanowires synthesized by heterogeneous nucleation in liquid polyol. Adv. Mater. 17, 338 (2005).CrossRefGoogle Scholar
Ni, X., Zhao, Q., Zhang, D., Zhang, X., and Zheng, H.: Novel hierarchical nanostructures of nickel: Self-assembly of hexagonal nanoplatelets. J. Phys. Chem. C 111, 601 (2006).CrossRefGoogle Scholar
Zhou, W., Hu, X., Bai, X., Zhou, S., Sun, C., Yan, J., and Chen, P.: Synthesis and electromagnetic, microwave absorbing properties of core–shell Fe3O4–poly(3, 4-ethylenedioxythiophene) microspheres. ACS Appl. Mat. Interfaces 3, 3839 (2011).CrossRefGoogle ScholarPubMed
Deng, Y., Liu, X., Shen, B., Liu, L., and Hu, W.: Preparation and microwave characterization of submicrometer-sized hollow nickel spheres. J. Magn. Magn. Mater. 303, 181 (2006).CrossRefGoogle Scholar
Chen, Y-J., Gao, P., Wang, R-X., Zhu, C-L., Wang, L-J., Cao, M-S., and Jin, H-B.: Porous Fe3O4/SnO2 core/shell nanorods: Synthesis and electromagnetic properties. J. Phys. Chem. C 113, 10061 (2009).CrossRefGoogle Scholar
Xu, P., Han, X., Wang, C., Zhou, D., Lv, Z., Wen, A., Wang, X., and Zhang, B.: Synthesis of electromagnetic functionalized nickel/polypyrrole core/shell composites. J. Phys. Chem. B 112, 10443 (2008).CrossRefGoogle ScholarPubMed
Fang, P.H.: Cole–Cole diagram and the distribution of relaxation times. J. Chem. Phys. 42, 3411 (1965).CrossRefGoogle Scholar
Pinna, N., Grancharov, S., Beato, P., Bonville, P., Antonietti, M., and Niederberger, M.: Magnetite nanocrystals: Nonaqueous synthesis, characterization, and solubility. Chem. Mater. 17, 3044 (2005).CrossRefGoogle Scholar
Wu, M., Zhang, Y.D., Hui, S., Xiao, T.D., Ge, S., Hines, W.A., Budnick, J.I., and Taylor, G.W.: Microwave magnetic properties of Co50/(SiO2)50 nanoparticles. Appl. Phys. Lett. 80, 4404 (2002).CrossRefGoogle Scholar
Gangopadhyay, S., Hadjipanayis, G.C., Dale, B., Sorensen, C.M., Klabunde, K.J., Papaefthymiou, V., and Kostikas, A.: Magnetic properties of ultrafine iron particles. Phys. Rev. B 45, 9778 (1992).CrossRefGoogle ScholarPubMed
Guo, J., Wang, X., Miao, P., Liao, X., Zhang, W., and Shi, B.: One-step seeding growth of controllable Ag@Ni core-shell nanoparticles on skin collagen fiber with introduction of plant tannin and their application in high-performance microwave absorption. J. Mater. Chem. 22, 11933 (2012).CrossRefGoogle Scholar
Marín, P., Cortina, D., and Hernando, A.: Electromagnetic wave absorbing material based on magnetic microwires. IEEE Trans. Magn. 44, 3934 (2008).CrossRefGoogle Scholar
Gorriti, A., Marín, P., Cortina, D., and Hernando, A.: Microwave attenuation with composite of copper microwires. J. Magn. Magn. Mater. 322, 1505 (2010).CrossRefGoogle Scholar
Han, M., Liang, D., and Deng, L.: Fabrication and electromagnetic wave absorption properties of amorphous Fe79Si16B5 microwires. Appl. Phys. Lett. 99, 082503 (2011).Google Scholar
Marín, P., Cortina, D., and Hernando, A.: High frequency magnetic behavior of magnetic microwires. J. Magn. Magn. Mater. 290291, 1957 (2005).Google Scholar
Zhuo, R.F., Feng, H.T., Chen, J.T., Yan, D., Feng, J.J., Li, H.J., Geng, B.S., Cheng, S., Xu, X.Y., and Yan, P.X.: Multistep synthesis, growth mechanism, optical, and microwave absorption properties of ZnO dendritic nanostructures. J. Phys. Chem. C 112, 11767 (2008).CrossRefGoogle Scholar
Zhuo, R.F., Qiao, L., Feng, H.T., Chen, J.T., Yan, D., Wu, Z.G., and Yan, P.X.: Microwave absorption properties and the isotropic antenna mechanism of ZnO nanotrees. J. Appl. Phys. 104, 094101 (2008).CrossRefGoogle Scholar
Wang, C., Han, X., Xu, P., Wang, J., Du, Y., Wang, X., Qin, W., and Zhang, T.: Controlled synthesis of hierarchical nickel and morphology-dependent electromagnetic properties. J. Phys. Chem. C 114, 3196 (2010).CrossRefGoogle Scholar

Full text views

Full text views reflects PDF downloads, PDFs sent to Google Drive, Dropbox and Kindle and HTML full text views.

Total number of HTML views: 20
Total number of PDF views: 44 *
View data table for this chart

* Views captured on Cambridge Core between September 2016 - 20th April 2021. This data will be updated every 24 hours.

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Solvothermal synthesis and electromagnetic absorption properties of pyramidal Ni superstructures
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

Solvothermal synthesis and electromagnetic absorption properties of pyramidal Ni superstructures
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

Solvothermal synthesis and electromagnetic absorption properties of pyramidal Ni superstructures
Available formats
×
×

Reply to: Submit a response


Your details


Conflicting interests

Do you have any conflicting interests? *