Introduction

The nucleation, propagation and interaction of cracks are important processes in the behavior of ice under compression (Reference Schulson,Schulson, 1997). At lower deformation rates, cracks nucleate but do not propagate; correspondingly, the material exhibits macroscopically ductile behavior. At higher rates, the cracks grow and interact; macroscopic faults eventually develop and brittle failure ensues.

Grain-boundary sliding has now been identified as an important mechanism of crack nucleation. Following earlier suggestions by Reference Sinha,Sinha (1979, Reference Sinha,1984), recent experiments and calculations (Reference Picu,, Gupta, and Frost,Picu and others, 1994; Reference Nickolayev, and Schulson,Nickolayev and Schulson, 1995; Reference Picu, and Gupta,Picu and Gupta, 1995a, Reference Picu, and Gupta,b; Reference Elvin, and Shyam Sunder,Elvin and Sunder, 1996; Reference Weiss, and Frost,Weiss and others, 1996) point rather conclusively to this mechanism as an effective means for concentrating stress. The experimental evidence is localized decohesion which precedes crack nucleation (Reference Nickolayev, and Schulson,Nickolayev and Schulson, 1995; Reference Picu, and Gupta,Picu and Gupta, 1995b). The decohesion is manifested as sub-millimeter sized zones of opacity which are particularly distinct when columnar-grained ice is loaded along a direction inclined to the long axis of the grains (Reference Nickolayev, and Schulson,Nickolayev and Schulson, 1995). In that case, the sliding nucleates across-column cracks which may then initiate wing cracks along the loading direction. That grain-boundary sliding operates in ice at ambient temperatures is not surprising, given its well-recognized occurrence in hot polycrystalline metals (Reference Zener,Zener, 1948).

The observations noted above were made specifically on fresh-water ice. It is assumed that the conclusions drawn apply also to salt-water ice, for the qualitative aspects of its deformation and the mechanisms invoked to explain its behavior are essentially identical (Reference Smith, and Schulson,Smith and Schulson, 1994; Reference Schulson, and Nickolayev,Schulson and Nickolayev, 1995; Reference Gratz, and Schulson,Gratz and Schulson, 1997. However, the grain boundaries in salt-water ice are somewhat interdigitated, owing to its brine content. The question is whether the interdigitation impedes sliding to the point that crack nucleation is suppressed. This paper addresses this issue.

Procedure

A sheet of S2 saline ice was undirectionally grown in the laboratory in the manner described by Reference Smith, and Schulson,Smith and Schulson (1994). The ice had the same characteristics as described earlier: c axes randomly oriented within the horizontal plane; salinity of 4.3 ± 0.7 ppt; density of 907 ± 3 kg m⁻³ porosity of 4–5%; average column diameter of about 8mm; spacing of 0.5–1 mm between platelet-like arrays of brine pockets. Plate-shaped specimens (100 mm × 50 mm × 6 mm) were cut from the sheet and then compressed at a constant strain rate between stainless-steel platens using a servohydraulic loading frame housed within a cold room. The temperature was −10 ± 0.2°C, and the strain rate was either 1 × 10⁻⁴ s⁻¹ or 3 × 10⁻³ s⁻¹. The long axes of the columnar grains were parallel to the largest faces of the specimens and were inclined at about 45° to the direction of loading. This orientation was selected to maximize the shear stress on the grain boundaries. The ice was observed and photographed (at the lower deformation rate) while shortening.

Salt-water ice is less transparent than fresh-water ice, owing to its porosity. To enhance the detection of grain-boundary decohesion, additional observations were made using thinner specimens (50 mm × 50 mm × 3 mm). These specimens were also deformed at −10° C, at 10⁻⁴ s⁻¹.

Results and Observations

More than a dozen experiments were performed. The results were qualitatively reproducible and may be summarized as follows:

• (i) The ice was macroscopically ductile at the lower rate and brittle at the higher rate. Fig. 1 shows typical stress strain curves.

• (ii) At the lower strain rate, cracks were detected near the peak stress. They occurred in approximately parallel sets Within a set, many of the cracks appeared to traverse a grain and to have both initiated and terminated at the grain boundaries, running more or less perpendicular to them. Fig. 2 shows an example. Although difficult to see owing to the opacity of the ice. the grain boundaries in Fig. 2 are defined by the lines joining the tops and the bottoms of the grain-sized cracks in a set.

• (iii) At the higher strain rate, cracks formed across the grains, as at the lower rate, and then propagated along the direction of loading, splitting the specimen. Fig. 3 shows an example. In the case illustrated, two of us (E.M.S. and S.Q.), while standing beside the deforming specimen, observed the split to extend from the tip of an across-column crack (which had formed during the test) and to run from the top to the bottom of the specimen. A piece of the ice to the left of the crack fell off the specimen along a grain boundary (Fig. 3, top center).

• (iv) Fewer across-column cracks formed at the higher strain rate than at the lower rate. Presumably, they were stabilized against propagation at the lower rate by extensive crack-up creep.

Fig. 1. Stress-strain curves for S2 saline ice compressed uni-axially along a direction at about 45° to the long axis of the columnar grains at −10° C at strain rates of (a) 1 × 10⁻⁴ s⁻¹ and (b) 3 × 10⁻³s⁻¹, The curves indicate ductile and brittle behavior, respectively.

Both the across-column cracks and the axial splits are-almost identical to the features observed in S2 fresh-water ice (Reference Nickolayev, and Schulson,Nickolayev and Schulson, 1995). The difference is that the cracks within the fresh-water material were preceded by the clear development of the decohesive zones on the grain boundaries, easily detectable by the unaided eye. Owing to the opacity of the saline ice, we were unable to discern unambiguously whether localized grain-boundary decohesion also preceded the across-column cracking in this material. However, the deformed boundaries from which sets of across-column cracks emanated were somewhat milkier in appearance after the deformation, a feature more evident in the thinner specimens. This point and the fact that a piece of a specimen deformed at the higher rate broke free along the grain boundary from which an across-column crack nucleated suggest that some grain boundaries truly had lower cohesion after the deformation.

Discussion

We again invoke grain-boundary sliding. In so doing, we assume that the boundaries act like mode-II cracks. Upon sliding, they concentrate stress at microstructural impediments, such as ledges or steps. When the stress there is high enough, the tensile component nucleates cracks which then tend to run across the columns, traversing the grain (presumably) where the stress is more highly concentrated. A relatively regular array of impediments would then account for the more-or-less uniformly spaced cracks within the sets.

The resistance to across-column crack propagation, K _ap, may be estimated as follows. If it is assumed that the cracks propagate when the mode-I stress intensity factor for very short out-of-boundary extensions reaches a critical value, then from Reference Cotterell, and Rice,Cotterell and Rice (1980):

where 2l is the length of the boundary segment between the sliding impediments, τ_a is the applied shear stress on the grain boundary and τ_b, is the intrinsic resistance to sliding. Upon substituting 2l = 3 mm (Fig. 2) and τ_a = 1.4/2 M Pa (Fig. 1) and by assuming that τ_b = 0, we obtain K _ap = 55 k Pa m^½. This value compares roughly with that deduced for fresh-water ice from the same kind of experiment (35 k Pa m^½; Reference Nickolayev, and Schulson,Nickolayev and Schulson, 1995) and is similar to the apparent fracture toughness of sea ice (25–80 k Pa m^½) measured at the same scale but at −2° C (Reference Urabe,, Iwasaki, and Yoshitake,Urabe and others, 1980). However, these values are lower than those obtained in the field on larger specimens where the apparent fracture increases with size and reaches about 250 k Pa m^½ for plates 80 m on edge (Reference Dempsey, and Arsenault,Dempsey, 1996).

Fig. 2. Photograph showing across-column cracks in a specimen shortened 0.2% at 1 × 10⁻⁴ s⁻¹. The load was applied in the vertical direction. Note the sets of cracks which appear to have traversed a grain and to have initiated and terminated at the boundaries. Scale: specimen width = 50 mm.

Fig. 3. Photograph showing an across-column crack and an axial split in a specimen compressed at 3 × 10⁻³ s⁻¹. The load was applied in the vertical direction. The split ran from the top to the bottom of the specimen and appears to have initiated from the across-column crack. A piece of the ice fell off the specimen along a grain boundary (top center). Scale: specimen width = 50 mm.

The reason the across-column cracks stop when they reach the grain boundaries in the more slowly deformed ice, but generate out-of-plane extensions or wings which lengthen into splits in the more rapidly deformed material, is probably related to the rate of crack-tip stress relaxation. The argument and analysis are given elsewhere (Reference Schulson,Schulson, 1990). In essence, once the applied strain rate exceeds a certain level, there is insufficient time for crack-tip creep to reduce the mode-I stress intensity factor of the across-column crack to below its critical value. Wing cracks then sprout and lengthen along the direction of loading with increased applied stress, developing into full axial splits. Fig. 4 sketches the sequence as it applies in the present case. The strain rate at which wing-crack growth occurs marks the ductile-to-brittle transition. For saline ice of the kind examined here, the transition rate at −10° C has been both calculated and measured to the around 1 × 10⁻³ s⁻¹ (Reference Schulson, and Nickolayev,Schulson and Nickolayev, 1995), in agreement with the behavior apparent from the present tests.

Fig. 4. Schematic sketches illustrating the development of an across-column crack (c) and an axial split (e) in columnar ice uniaxially compressed along a direction inclined to the long axis of the columnar grains. Dotted lines indicate grain boundaries: dashed lines indicate decohesion on one of the grain boundaries an across-column crack forms (с): wing cracks initiate from the across-column crack (d) and then develop into axial splits (e);

The resistance to the propagation of the wing crack, K _wp, may be estimated from Reference Ashby, and Hallman,Ashby and Hallams (1986) model of brittle compressive failure. The analysis incorporates frictional sliding of a parent crack which, in this case, is the across-column crack. Accordingly (Reference Schulson,Schulson, 1990):

where σ_f is the fracture stress, μ is the ice/ice-friction coefficient, 2a is the length of the across-column crack and Z is an experimental constant. Upon substituting =σ_f = 1.7 M Pa (Fig. 1), μ = 0.5 (Reference Jones,, Kennedy, and Schulson,Jones and others, 1991), 2a = 10 mm (Fig. 2) and Z = 2 (Reference Schulson,Schulson, 1990) we obtain K _wp = 35 k Pa m^½. Again this estimate is similar to the apparent fracture toughness of small specimens (Reference Urabe,, Iwasaki, and Yoshitake,Urabe and others, 1980).

Conclusions

It is thus concluded:

• (i) that across-column cracks nucleate in relatively small plates of S2 saline ice through along-column grain-boundary sliding, just as in fresh-water ice; and

• (ii) that the across-column cracks initiate wing cracks which develop into axial splits when the strain rate is sufficiently high to suppress stress relaxation at the crack tips.

In other words, the interdigitation of the grain boundaries in S2 saline ice appears not to impede along-column grain-boundary sliding to the point that across-column cracking is suppressed.