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Surface shear viscosity of Gibbs and Langmuir monolayers

Published online by Cambridge University Press:  25 October 1999

CATHERINE BARENTIN
Affiliation:
Institut Charles Sadron (CNRS UPR 022), 6 rue Boussingault, 67083 Strasbourg Cedex, France
CHRISTOPHE YBERT
Affiliation:
Institut Charles Sadron (CNRS UPR 022), 6 rue Boussingault, 67083 Strasbourg Cedex, France Present address: Laboratoire de dynamique des fluides complexes (UMR 7506 ULP–CNRS), Institut de physique, 3 rue de l'Université, 67084 Strasbourg Cedex, France.
JEAN-MARC DI MEGLIO
Affiliation:
Institut Charles Sadron (CNRS UPR 022), 6 rue Boussingault, 67083 Strasbourg Cedex, France
JEAN-FRANÇOIS JOANNY
Affiliation:
Institut Charles Sadron (CNRS UPR 022), 6 rue Boussingault, 67083 Strasbourg Cedex, France

Abstract

In this paper, we present a new two-dimensional viscometer, and the hydrodynamic calculations used to obtain the surface viscosities from the measurements. In order to interpret the experiments, performed with solutions of sodium dodecyl sulfate (SDS) and also with monolayers of insoluble surfactants, we develop various hydrodynamic models of soluble Gibbs monolayers and of incompressible Langmuir monolayers, that describe well the experimental results. In the case of SDS solutions, the calculations allow the determination of the surface shear viscosity, and its value is in good agreement with previous studies.

Type
Research Article
Copyright
© 1999 Cambridge University Press

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