The Chianti Mountains is an important sector of an E-verging regional thrust-related fold (the so-called Tuscan Nappe) extending along the whole length of the Northern Apennines. This thrust system involves the Tuscan Sequence superposing the Macigno sandstones onto Cervarola-Falterona sandstones, both of which are sedimented in adjacent foredeep basins. Detailed field mapping and analysis of superposition relations among tectonic structures, as well as correlation between structures and syntectonic deposition, has allowed Chianti Mountain evolution to be interpreted in terms of three main stages of deformation.

The D1 stage resulted in the NE-directed synsedimentary thrusting of the Macigno onto the Cervarola-Falterona sandstones, while large NE to ENE-vergent thrust-related folds developed during the two successive deformation stages (D2 and D3). Fault-propagation folds developed during the D2 stage, and were affected by the Main Chianti Mountains Thrust (MCMT) during the successive D3 stage. In particular, the D3 stage has been correlated to the development, during the Pliocene period, of the hinterland Upper Valdarno Basin, which was previously considered to be an extensional basin. In fact, this continental basin formed along the eastern margin of the Chianti Mountains, ahead of the MCMT that also produced a shortening of the basin fill. With the beginning of the Quaternary period, the tectonic regime switched to extensional, as manifested by the development of a normal fault system on the opposite basin margin.

The data presented here allow us to infer that the Chianti Mountains thrust system (D2 and D3) developed during a time interval spanning from the Late Miocene (∼12 Ma) until the Late Pliocene (∼2 Ma) periods. In the Northern Apennines, polyphase thrusting recorded by cover rocks has been related to the activity of basement thrusts, which have been recently evidenced by geophysical data. In this context, the two latest stages of deformation recognised in the Chianti Mountains have been attributed to the activity of the Abetone–Cetona crustal thrust, the deformational effects of which propagated forward in the sedimentary cover.