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Neutron Diffraction Study of Interlayer Water in Sodium Wyoming Montmorillonite Using a Novel Difference Method

Published online by Cambridge University Press:  28 February 2024

D. Hugh Powell ,
Kowut Tongkhao ,
Shane J. Kennedy  and
Phillip G. Slade
D. Hugh Powell
Affiliation:
Department of Chemistry, University of Adelaide, South Australia 5005, Australia
Kowut Tongkhao
Affiliation:
Department of Chemistry, University of Adelaide, South Australia 5005, Australia
Shane J. Kennedy
Affiliation:
Australian Nuclear Science & Technology Organisation, Menai, New South Wales 2234, Australia
Phillip G. Slade
Affiliation:
CSIRO Division of Soils, Glen Osmond, South Australia 5064, Australia
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Abstract

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Keywords

InterlayerMontmorilloniteNeutron DiffractionStructureWater
Type
Brief Report
Information
Clays and Clay Minerals , Volume 45 , Issue 2 , April 1997 , pp. 290 - 294
Copyright
Copyright © 1997, The Clay Minerals Society

References

Blech, I.A. and Averbach, B.L.. 1965. Multiple scattering of neutrons in vanadium and copper. Phys Rev 137: A1113–1116.CrossRefGoogle Scholar
Boek, E.S., Coveney, P.V. and Skipper, N.T.. 1995. Monte Carlo molecular modeling studies of hydrated Li-, Na-, and K-smectites: Understanding the role of potassium as a clay swelling inhibitor. J Am Chem Soc 117: 12608–12617.CrossRefGoogle Scholar
Chang, F-RC, Skipper, N.T. and Sposito, G.. 1995. Computer simulation of interlayer molecular structure in sodium mont-morillonite hydrates. Langmuir 11: 2734–2741.CrossRefGoogle Scholar
Hawkins, R.K. and Egelstaff, P.A.. 1980. Interfacial water structure in montmorillonite from neutron diffraction experiments. Clays Clay Miner 28: 19–28.CrossRefGoogle Scholar
Hughes, D.J. and Harvey, J.F.. 1955. Neutron cross sections. New York: McGraw-Hill. 328 p.Google Scholar
Karaborni, S., Smit, B., Heidug, W., Urai, J. and van Oort, E.. 1996. The swelling of clays: Molecular simulations of the hydration of montmorillonite. Science 271: 1102–1104.CrossRefGoogle Scholar
Méring, J. and Brindley, G.W.. 1967. X-ray diffraction band profiles of montmorillonite—Influence of hydration and of the exchangeable cations. Clays Clay Miner 15: 51–60.CrossRefGoogle Scholar
Montague, D.G., Gibson, I.P. and Dore, J.C.. 1981. Structural studies of liquid alcohols by neutron diffraction: I. Deuterated methyl alcohol CD3OD. Mol Phys 44: 1355–1367.CrossRefGoogle Scholar
Newman, A.C.D.. 1987. Chemistry of clays and clay minerals. London: Mineral Soc. 480 p.Google Scholar
North, D.M., Enderby, J.E. and Egelstaff, P.A.. 1968. The structure factor for liquid metals. I. The application of neutron diffraction techniques. J Phys C 1: 784–794.CrossRefGoogle Scholar
Paalman, H.H. and Pings, C.J.. 1962. Numerical evaluation of X-ray absorption factors for cylindrical samples and annular cells. J Appl Phys 33: 2635–2639.CrossRefGoogle Scholar
Powell, D.H., Neilson, G.W. and Enderby, J.E.. 1989. A neutron diffraction study of NiCl2 in D2O and H2O. A direct determination of gNiH(r). J Phys: Condens Matter 1: 8721–8733.Google Scholar
Sears, V.F.. 1992. Neutron scattering lengths and cross sections. Neutron News 3: 26–37.CrossRefGoogle Scholar
Skipper, N.T., Smalley, M.V., Williams, G.D., Soper, A.K. and Thompson, C.H.. 1995. Direct measurement of the electrical double-layer structure in hydrated lithium vermiculite clays by neutron diffraction. J Phys Chem 99: 14201–14204.CrossRefGoogle Scholar
Skipper, N.T., Soper, A.K. and McConnell, J.D.C.. 1991. The structure of interlayer water in vermiculite. J Chem Phys 94: 5751–5760.CrossRefGoogle Scholar
Skipper, N.T., Soper, A.K. and Smalley, M.V.. 1994. Neutron diffraction study of calcium vermiculite: Hydration of calcium ions in a confined environment. J Phys Chem 98: 942–945.CrossRefGoogle Scholar
Skipper, N.T., Sposito, G. and Chang, F-RC. 1995. Monte Carlo simulation of interlayer molecular structure in swelling clay minerals: 1. Methodology. Clays Clay Miner 43: 285–293.CrossRefGoogle Scholar
Slade, P.G., Quirk, J.P. and Norrish, K.. 1991. Crystalline swelling of smectite samples in concentrated NaCl solutions in relation to layer charge. Clays Clay Miner 39: 234–238.CrossRefGoogle Scholar
Slade, P.G., Stone, P.A. and Radoslovich, E.W.. 1985. Interlayer structure of the two-layer hydrates of Na- and Ca- vermic-ulites. Clays Clay Miner 33: 51–61.CrossRefGoogle Scholar
Soper, A.K. and Phillips, M.G.. 1986. A new determination of the structure of water at 25°C. Chem Phys 107: 47–60.CrossRefGoogle Scholar
Sposito, G. and Prost, R.. 1982. Structure of water absorbed on smectites. Chem Rev 82: 553–573.CrossRefGoogle Scholar