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Characterization of Expandable Clay Minerals in Lake Baikal Sediments by Thermal Dehydration and Cation Exchange

Published online by Cambridge University Press:  01 January 2024

Tomas Grygar ,
Petr Bezdicka ,
David Hradil ,
Michaela Hruskova ,
Katerina Novotna ,
Jaroslav Kadlec ,
Petr Pruner  and
Hedi Oberhansli
Tomas Grygar*
Affiliation:
Institute of Inorganic Chemistry AS CR, Rez, Czech Republic
Petr Bezdicka
Affiliation:
Institute of Inorganic Chemistry AS CR, Rez, Czech Republic
David Hradil
Affiliation:
Institute of Inorganic Chemistry AS CR, Rez, Czech Republic
Michaela Hruskova
Affiliation:
Institute of Inorganic Chemistry AS CR, Rez, Czech Republic
Katerina Novotna
Affiliation:
Institute of Inorganic Chemistry AS CR, Rez, Czech Republic
Jaroslav Kadlec
Affiliation:
Paleomagnetic Laboratory, Geological Institute AS CR, Prague, Czech Republic
Petr Pruner
Affiliation:
Paleomagnetic Laboratory, Geological Institute AS CR, Prague, Czech Republic
Hedi Oberhansli
Affiliation:
GeoForschungsZentrum, Potsdam, Germany
*
*E-mail address of corresponding author: grygar@iic.cas.cz
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Abstract

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The sedimentary series from Academician Ridge, Lake Baikal, eastern Siberia, was examined using cation exchange capacity (CEC) to estimate the amount of expandable clay minerals (ECM) and high-temperature X-ray diffraction (HT-XRD) to determine their basic classification. The comparison of the magnetic susceptibility (MS) at sub-millennial resolution and the δl8O record of a reference Atlantic core (ODP 980) was used to create an age model. The most closely studied part of the series covered the major part of the last glacial cycle (120–20 ky BP). The HT-XRD analysis is based on monitoring the course of ECM dehydration with 5°C steps between 25 and 250°C and enabled us to improve the discrimination between ECM, chlorite and micas. The CEC obtained at millennial resolution showed that the neoformation of ECM in warmer periods of the last interglacial was either insignificant or fully compensated by their dissolution or dilution. The CEC record was correlated with the main climatic stages in the period studied. Both MS and CEC records reflected the environmental changes at about millennial resolution, including climatic instabilities between 117 and 73 ky BP (late MIS5).

Keywords

Cation Exchange CapacityLake BaikalLake SedimentsPaleoclimateRussiaThermal DehydrationXRD
Type
Research Article
Information
Clays and Clay Minerals , Volume 53 , Issue 4 , August 2005 , pp. 389 - 400
Copyright
Copyright © The Clay Minerals Society 2005

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