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Poly-phase alteration history of the kaolinitized ‘Cava di Caolino’ volcanics (Lipari Island, southern Italy)

  • S. Decrée (a1), A. Bernard (a1), J. Yans (a2) and Th. De Putter (a3)


A 65 m thick altered volcanic profile was studied in the Cava di Caolino (Lipari Island) in order to (1) identify the alteration event(s), (2) model these events, and (3) propose estimates of the degree of chemical alteration (CIA, chemical index of alteration). Two mineral parageneses were identified: one comprising silico-aluminous phases, with well crystallized kaolinite (type 1), and the other comprising sulphates, with kaolinite as fracture infilling (type 2). The geochemistry of fluids analysed from a local hot spring (40°C, pH ≈ 8) allowed modelling of the observed silico-aluminous paragenesis. A later fumarolic event is suggested to be responsible for the sulphate paragenesis. The main stage of hydrothermal alteration lasted for ~50 ky, was marked by an increase in the CIA from the protolith (~52) to the alterites (~98), and resulted in the alteration of a 65 m thick series. Such data could be used to predict the alteration of volcanic rocks around underground nuclear waste repositories.


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Africano, F. & Bernard, A. (2000) Acid alteration in the fumarolic environment of Usu volcano, Hokkaido, Japan. Journal of Volcanology and Geothermal Research, 97, 475495.
Baron, D. & Palmer, C.D. (1996) Solubility of jarosite at 4–35°C. Geochimica et Cosmochimica Ada, 60, 185195.
Bethke, C.M. (1996) Geochemical Reaction Modeling. Oxford University Press, New York, 397 pp.
Brea, L.B. & Cavalier, M. (1991) Isole Eolie, Vulcanologia, Archeologia. Oreste Ragusi Editore, Milan, pp. 78-82.
Bruno, P.P.G., Paolerri, V., Grimaldi, M. & Rappolla, A. (2000) Geophysical exploration for geothermal low enthalpy resources in Lipari Island, Italy. Journal of Volcanology and Geothermal Research, 98, 173188.
Decree, S., (2002) Mineralogie et geochimie des alterations de la ‘Cava di Caolino', Lipari, Italie. Unpublished MSc thesis, Brussels University, 114 pp.
De Putter, Th., Charlet, J.-M. & Quinif, Y. (1999) REE, Y and U concentration at the fluid-iron oxide interface in late Cenozoic cryptodolines from southern Belgium. Chemical Geology, 153, 139150.
De Putter, Th., Bernard, A., Perruchot, A., Nicaise, D. & Dupuis, Ch. (2000) Low-temperature acid weathering in Newhaven, Sussex, United Kingdom, and its application to theoretical modeling in radioactive waste-disposal sites. Clays and Clay Minerals, 48, 238246.
De Putter, Th., André, L., Bernard, A., Dupuis, Ch., Jedwab, J., Nicaise, D. & Perruchot, A. (2002) Trace element (Th, U, Pb, REE) behaviour in a cryptokarstic halloysite and kaolinite deposit from Southern Belgium: importance of « accessory » minerals neoformation for radioactive pollutant trapping. Applied Geochemistry, 17, 13131328.
De Putter, Th., Bernard, A., Perruchot, A., Yans, J., Verbrugghe, Fr. & Dupuis, Ch. (2003) Neoformed mineral parageneses in acid weathering systems: sedimentary vs. volcanic environments. ‘A Clay Odyssey', Proceedings of the 12th International Clay Conference (Bahia Blanca, Argentina. (E.A. Dominguez, G.R. Mas and F. Cravero, editors). Elsevier, Amsterdam, pp. 57-64.
Delmelle, P. & Bernard, A. (1994) Geochemistry, mineralogy, and chemical modeling of the acid crater lake of Kawah Ijen Volcano, Indonesia. Geochimica et Cosmochimica Ada, 58, 2445–2460.
Giese, R.F. Jr. (1988) Kaolin minerals: structures and stabilities. Pp. 29–66 in: Hydrous Phyllosilicate. (S.W. Bailey, editor). Reviews in Mineralogy, 19. Mineralogical Society of America, Washington, D.C.
Gioncada, A., Mazzuoli, R., Bisson, M. & Pareschi, M.T. (2003) Petrology of volcanic products younger than 42 ka on the Lipari-Vulcano complex (Aeolian Islands, Italy): an example of volcanism controlled by tectonics. Journal of Volcanology and Geothermal Research, 122, 191220.
Herbert, R.B. (1997) Properties of goethite and jarosite precipitated from acidic groundwater, Dalarna, Sweden. Clays and Clay Minerals, 45, 261273.
Lo Cascio, P., Pasta, S., Rossi, P.L., Tranne, C.A. & De Luca, M. (2002) Fossili vegetali in depositi vulcanici delle isole Eolie e di Linosa. Quaderno del Centro Studi e Ricerche di Storia e Problemi Eoliani, 42 pp.
Martini, M., Capaccioni, B., Giannini, L., Cellini Legittimo, P. & Piccardi, G. (1988) Past and present influence of volcanic systems on the surface environments: Vulcano and Lipari (Aeolian Islands, Italy). Bollettino Gruppo Nazionale di Volcanologia, 4, 383391.
Miller, W., Alexander, R., Chapman, N., McKinley, I. & Smellie, J. (1994) Natural Analogue Studies in the Geological Disposal of Radioactive Wastes. Elsevier, 395 p.
Nesbitt, H.W. & Markovics, G. (1997) Weathering of granodiorite crust, long-term storage of elements in weathering profiles, and petrogenesis of siliciclastic sediments. Geochimica et Cosmochimica Acta, 61, 16531670.
Nesbitt, H.W. & Young, G.M. (1982) Early Proterozoic climates and plate motion inferred from major element chemistry of lutites. Nature, 299, 715717.
Nicaise, D., De Putter, Th., André, L., Jedwab, J. & Dupuis, Ch. (1996) Néoformation de phosphates nanométriques de terres rares en altération acide de basse temperature: implications pour le piégeage des terres rares, de Puranium et du thorium. Comptes-Rendus de I'Académie des Sciences de Paris (série IIa), 323,1, 13-120.
Nordstrom, D.K. (1982) Aqueous pyrite oxidation and the consequent formation of secondary iron minerals. Pp. 37-55 in: Acid Sulphate Weatherin. (J.A. Kittrick, D.S. Fanning and L.R. Hossner, editors). SSSA Special Publication 10. Soil Science Society of America, Madison, Wisconsin.
Pichler, H. (1980) The island of Lipari. Rendiconti Società Italiana di Mineralogia e Petrologia, 36, 415440.
Raymahashay, B.C. (1968) A geochemical study of rock alteration by hot springs in the Paint Pot Hill area, Yellowstone Park. Geochimica et Cosmochimica Acta, 32, 499522.
Schmitt, J.-M. (1999) Weathering, rainwater and atmosphere chemistry: example and modeling of granite weathering in present conditions, in a CO2-rich, and in an anoxic paleoatmosphere. Pp. 21–41 in: Palaeoweathering, Palaeosurface and Related Continental Deposit. (M. Thiry and R. Simon-Coincon, editors). Special Publication of the International Association of Sedimentologists.
Stumm, W. & Morgan, J.J. (1996) Aquatic Chemistry. Wiley, New York, 1022 pp.
Tardy, Y. & Novikoff, A. (1988) Activité de l'eau et déplacement des équilibres gibbsite-kaolinite dans les profiles latéritiques. Comptes-Rendus de I'Académie des Sciences de Paris, 306, 39–44.
Tardy, Y. & Roquin, C. (1992) Geochemistry and evolution of lateritic landscapes. Pp. 407-443 in: Weathering, Soils and Paleosoil. (I.P. Martini and W. Chesworth, editors). Developments in Earth Surface Processes, vol. 2, Elsevier, Amsterdam.
Tranne, C.A., Calanchi, N., Lucchi, F. & Rossi, P.L. (2000) Geological sketch map of Lipari, Eolian Islands, Ital. (scale 1:15,000).
Trolard, F., Bilong, P., Guillet, B. & Herbillon, A.J. (1990) Halloysite-kaolinite-gibbsite-boehmite: a thermodynamical modelisation of equilibria as function of water and dissolved silica activities. Chemical Geology, 84, 294297.
Van Breemen, N. (1982) Genesis, morphology and classification of acid sulfate soils in coastal plains. Pp. 95-108 in: Acid Sulfate Weatherin. (J.A. Kittrick, D.S. Fanning and L.R. Hossner, editors). SSSA Special Publication 10. Soil Science Society of America, Madison, Wisconsin.
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Clay Minerals
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