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Optimized chemical preconditioning of Philippine natural zeolites

Published online by Cambridge University Press:  12 December 2019

Eleanor M. Olegario
Affiliation:
Department of Mining, Metallurgical, and Materials Engineering, College of Engineering, University of the Philippines Diliman, Quezon City, 1100Philippines
Kathrina Lois M. Taaca*
Affiliation:
Department of Mining, Metallurgical, and Materials Engineering, College of Engineering, University of the Philippines Diliman, Quezon City, 1100Philippines
John Christopher Lawrence Morillo
Affiliation:
Environmental Monitoring Laboratory, National Institute of Geological Sciences, University of the Philippines Diliman, Quezon City, 1100Philippines
Herman D. Mendoza
Affiliation:
Department of Mining, Metallurgical, and Materials Engineering, College of Engineering, University of the Philippines Diliman, Quezon City, 1100Philippines

Abstract

Natural zeolites in the Aksitero sedimentary formation of the western Luzon area of the Philippines were evaluated. The natural washed zeolite (NW-Z) was preconditioned with acid to purify it and increase its surface area. Acid treatment with 3 M HCl for 12 h yielded optimum acid treatment of the NW-Z, causing increases in the Si/Al ratio, the specific surface area by 32.5% and the porosity of the acid-treated zeolite (HC-Z). The HC-Z was washed with 4 M NaCl for 3, 6, 12, 18, 24, 48 and 72 h to improve its cation-exchange capacity for copper. The sodium-treated zeolite (Na-Z) was immersed in 100 ppm CuSO4 solution to test the copper-uptake capacity. Pretreatment of HC-Z with 4 M NaCl for 24 h is optimal for sodium treatment of the preconditioned HC-Z. The preconditioning techniques did not significantly alter the structure and morphology of the zeolite samples. It is suggested that the preconditioned Philippine natural zeolite samples are readily available for further functionalization that will enhance their antibacterial, catalytic and adsorption properties, with various useful applications in the field of catalysis, biomedicine, environmental mitigation and wastewater treatment.

Type
Article
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019

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Footnotes

Guest Associate Editor: M. Wdowin

This paper was submitted for the special issue devoted to the 10th International Conference on the Occurrence, Properties, and Utilization of Natural Zeolites (June 2018, Krakow, Poland).

References

Alberti, A. (1975) The crystal structure of two clinoptilolites locality: Agoura, California, USA, Tschermaks Mineral. Schweizerische Mineralogische und Petrographische Mitteilungen, 22, 2537.CrossRefGoogle Scholar
Arcilla, C., Pascua, C. & Alexander, W. (2011) Hyperalkaline groundwaters and tectonism in the Philippines: significance to natural carbon capture and sequestration. Energy Procedia, 4, 50935101.CrossRefGoogle Scholar
Barola, C., Dusaban, I., Olegario-Sanchez, E. & Mendoza, H. (2019) The effect on the zeta potential of surface modified Philippine natural zeolites (SM-PNZ) for the adsorption of anionic solutions. IOP Conference Series: Materials Science and Engineering, 478, 012039.CrossRefGoogle Scholar
Bedard, R. (2010) Synthesis of zeolites and manufacture of zeolitic catalysts and adsorbents: ion exchange and impregnation. Pp. 6183 in: Zeolites in Industrial Separation and Catalysis (Kulprathipanja, S., editor). Weinheim, Germany, Wiley-VCH.CrossRefGoogle Scholar
Cagomoc, C. & Vasquez, M. Jr (2016) Enhanced chromium adsorption capacity via plasma modification of natural zeolites. Japanese Journal of Applied Physics, 56, 01AF02.CrossRefGoogle Scholar
Cakicioglu-Ozkan, F. (2010) Effect of acid treatment on the structure of clinoptilolite. Pp. 5455 in: Zeolite 2010 – 8th International Conference on the Occurrence, Properties and Utilization of Natural Zeolites. Sofia, Bulgaria: Prof. Marin Drinov Academic Publishing House.Google Scholar
Cakicioglu-Ozkan, F. & Ulku, F. (2005) The effect of HCl treatment on vapour adsorption characteristics of clinoptilolite rich natural zeolite. Microporous and Mesoporous Materials, 77, 4753.CrossRefGoogle Scholar
Cerjan-Stefanović, Š., Ćurković, L. & Filipan, T. (1996) Metal ion exchange by natural zeolites. Croatica Chemica Acta, 69, 281290.Google Scholar
Concepcion-Rosabal, B., Rodriguez-Fuentes, G., Bogdanchikova, N., Bosch, P., Avalos, M. & Lara, V. (2005) Comparative study of natural and synthetic clinoptilolites containing silver in different states. Microporous and Mesoporous Materials, 86, 249255.CrossRefGoogle Scholar
Çoruh, S. (2008) The removal of zinc ions by natural and conditioned clinpilolites. Desalination, 225(1–3), 4157.CrossRefGoogle Scholar
Dignos, E., Gabejan, K., Olegario-Sanchez, E. & Mendoza, H. (2019) The comparison of the alkali-treated and acid-treated naturally mined Philippine zeolite for adsorption of heavy metals in highly polluted waters. IOP Conference Series: Materials Science and Engineering, 478, 012030.CrossRefGoogle Scholar
Doula, M. & Ioannou, A. (2003) The effect of electrolyte anion on Cu adsorption–desorption by clinoptilolite. Microporous and Mesoporous Materials, 58, 115130.CrossRefGoogle Scholar
Garrison, R., Espiritu, E., Horan, L. & Mack, L. (1979) Petrology, sedimentology, and diagenesis of hemi pelagic limestone and tuffaceous turbidites in the Aksitero Formation, Central Luzon, Philippines. United States Geological Survey. Professional Paper, 1112, 16.Google Scholar
Gligor, D., Maicaneanu, A. & Walcarius, A. (2010) Iron-enriched natural zeolite modified carbon paste electrode for H2O2 detection. Electrochimica Acta, 55, 40504056.CrossRefGoogle Scholar
Guerrero, L., Mendoza, J., Ong, K., Olegario-Sanchez, E. & Ferrer, E. (2019) Copper-exchanged Philippine natural zeolite as potential alternative to noble metal catalysts in three-way catalytic converters. Arabian Journal for Science and Engineering, 44, 55815588.CrossRefGoogle Scholar
Hernandez, M. (2014) Nanoporosity and dealuminated zeolites from Mexico. Pp. 9596 in: Zeolite 2014 – 9th International Conference on the Occurrence, Properties and Utilization of Natural Zeolites. Belgrade, Serbia: Institute for Technology of Nuclear and Other Mineral Raw Materials.Google Scholar
Herron, N. & Corbin, D. (1995) Inclusion Chemistry with Zeolites: Nanoscale Materials by Design. Dordrecht, The Netherlands, Kluwer Academic Publishers, 340 pp.CrossRefGoogle Scholar
Koyama, K. & Takeuchi, Y. (1977) Clinoptilolite: the distribution of potassium atoms and its role in thermal stability locality: Agoura, California, USA note: z(O3) corrected. Zeitschrift fur Kristallographie, 145, 216239.Google Scholar
Mamba, B., Nyembe, D. & Mulaba-Bafubiandi, A. (2009) Removal of copper and cobalt from aqueous solutions using natural clinoptilolite. Water SA, 35, 307314.Google Scholar
Mamba, B., Nyembe, D. & Mulaba-Bafubiandi, A. (2010) The effect of conditioning with NaCl, KCl and HCl on the performance of natural clinoptilolite's removal efficiency of Cu2+ and Co2+ from Co/Cu synthetic solutions. Water SA, 36, 437444.CrossRefGoogle Scholar
Munthali, M.W., Elsheikh, M.A., Johan, E. & Matsue, N. (2014) Proton adsorption selectivity of zeolites in aqueous media: effect of Si/Al ratio of zeolites. Molecules, 19, 2046820481.CrossRefGoogle ScholarPubMed
Ndayambaje, G. (2011) Sorption Properties of Natural Zeolites for the Removal of Ammonium and Chromium Ions in Aqueous Solution. Master's thesis. Cape Town, South Africa, University of the Western Cape.Google Scholar
Noda, T., Suzuki, K., Katada, N. & Niwa, M. (2008) Combined study of IRS-TPD measurement of DFT calculation on Bronsted acidity and catalytic cracking activity of cation-exchanged Y zeolites. Journal of Catalysis, 259, 203210.CrossRefGoogle Scholar
Olegario, E.M., Pelicano, C.M.O., Dahonog, L.A. & Nakajima, H. (2019a) Novel ZnO nanostructures on Philippine natural zeolite (PNZ) framework designed via thermal decomposition process of solution-based ZnCl2 precursor. Materials Research Express, 6, 015005.CrossRefGoogle Scholar
Olegario, E.M., Pelicano, C.M.O., Felizco, J.C., Mendoza, H.D. & Nakajima, H. (2019b) Philippine natural zeolite surface engineered with CuO nanowires via a one-step thermal decomposition route. Journal of the Australian Ceramic Society, 10.1007/s41779-019-00401-y.CrossRefGoogle Scholar
Olegario-Sanchez, E. & Pelicano, C. (2017) Characterization of Philippine natural zeolite and its application for heavy metal removal from acid mine drainage (AMD). Key Engineering Materials, 737, 407411.CrossRefGoogle Scholar
Olegario-Sanchez, E & Felizco, J. (2017) Investigation of the structural properties of amorphous Philippine bentonite clay and its potential use for topical applications. Key Engineering Materials, 737, 401406.CrossRefGoogle Scholar
Olegario-Sanchez, E., Tan, M., Mendoza, H. & Balela, M. (2017). Copper-treated Philippine natural zeolites for Escherichia coli inactivation. Materials Science Forum, 890, 150154.CrossRefGoogle Scholar
Osonio, A. & Olegario-Sanchez, E (2017) Hydrophobic surface functionalization of Philippine natural zeolite for a targeted oil remediation application. AIP Conference Proceedings, 1901, 080003.CrossRefGoogle Scholar
Osonio, A. & Vasquez, M. Jr (2018) Plasma-assisted reduction of silver ions impregnated into a natural zeolite framework. Applied Surface Science, 432, 156162.CrossRefGoogle Scholar
Panayotova, M. (2001) Kinetics and thermodynamics of copper ions removal from wastewater by use of zeolite. Waste Management, 21, 671676.CrossRefGoogle ScholarPubMed
Petrov, O. (1995) Cation exchange in clinoptilolite: an X-ray powder diffraction analysis. Pp. 271280 in: Natural Zeolites ’93: Occurrence, Properties, Use (Ming, D. & Mumpton, F., editors). Brockport, NY, USA, International Committee on Natural Zeolites.Google Scholar
Semmens, M. & Martin, W. (1988) The influence of pre-treatment on the capacity and selectivity of clinoptilolite for metal ions. Water Research, 22, 537542.CrossRefGoogle Scholar
Sprynskyy, M., Lebedynets, M., Zbytniewski, R., Namieśnik, J. & Buszewski, B. (2005) Ammonium removal from aqueous solution by natural zeolite, transcarpathian mordenite, kinetics, equilibrium and column tests. Separation and Purification Technology, 46, 155160.CrossRefGoogle Scholar
Taaca, K. & Vasquez, M. Jr (2017) Fabrication of Ag-exchanged zeolite/chitosan composites and effects of plasma treatment. Microporous and Mesoporous Materials, 241, 383391.CrossRefGoogle Scholar
Taaca, K. & Vasquez, M. Jr (2018) Hemocompatibility and cytotoxicity of pristine and plasma-treated silver–zeolite–chitosan composites. Applied Surface Science, 432, 324331.CrossRefGoogle Scholar
Vargas, E., Pascua, C., Arcilla, C., Honrado, M., Alexander, W., Namiki, K., Fujii, N., Yamakawa, M., Sato, T. & McKinley, I.G. (2009) Origin of the Manleluag hyperalkaline hot spring, Philippines. Geochimica et Cosmochimica Acta, Goldschmidt Conference Abstracts, A1375.Google Scholar
Whitehead, K. (2000) The Application of Synthetic Zeolites for the Removal of Heavy Metals from Contaminated Effluents. PhD thesis, Guildford, UK, University of Surrey.Google Scholar
Yumul, G. & Dimalanta, C. (1997) Geology of the Southern Zambales Ophiolite Complex, Philippines: juxtaposed terranes of diverse origin. Journal of Asian Earth Sciences, 15, 45.CrossRefGoogle Scholar