Hostname: page-component-8448b6f56d-wq2xx Total loading time: 0 Render date: 2024-04-24T09:00:21.909Z Has data issue: false hasContentIssue false

Trace Analytical Capabilities of Total-Reflection X-ray Fluorescence Analysis

Published online by Cambridge University Press:  06 March 2019

W. Michaelis
Affiliation:
Institute of Physics, GKSS-Research Centre D-2054 Geesthacht, Federal Republic of Germany
J. Knoth
Affiliation:
Institute of Physics, GKSS-Research Centre D-2054 Geesthacht, Federal Republic of Germany
A. Prange
Affiliation:
Institute of Physics, GKSS-Research Centre D-2054 Geesthacht, Federal Republic of Germany
H. Schwenke
Affiliation:
Institute of Physics, GKSS-Research Centre D-2054 Geesthacht, Federal Republic of Germany
Get access

Abstract

The principle to utilize total reflection of the primary X-rays in fluorescence analysis is known since a lot of years. Nevertheless, analytical chemistry did not profit from the inherent advantages of the method for a long time. The main reason for this failure was the lack of instruments which were easy to use in practice. A few years ago, however, the development of a proper mechanical design and of adapted sample preparation techniques led to commercially available spectrometers which throughout fulfill the demands for routine applications. Since then the utilization of Total-Reflection X-Ray Fluorescence Analysis (TXRF) has increased rapidly. The scope of work is meanwhile widespread over environmental research and monitoring, mineralogy, mineral exploration, oceanography, biology, medicine and biochemistry. Accordingly, numerous matrices have been handled.

Type
III. New Techniques and Instrumentation in XRF
Copyright
Copyright © International Centre for Diffraction Data 1984

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Yoneda, Y., Horiuchi, T., Rev. Sci. Instr., 42:1069 (1971)Google Scholar
2. Aiginger, H., Wobrauschek, P., Nucl. Instr. and Meth. 114:157 (1974).Google Scholar
3. Wobrauschek, P., Aiginger, H., Anal. Chem., 47:852 (1975).Google Scholar
4. Knoth, J., Schwenke, H., Fresenius Z. Anal. Chem., 291:200 (1978).Google Scholar
5. Knoth, J., Schwenke, H., Fresenius Z. Anal. Chem. 301:7 (1980).Google Scholar
6. Schwenke, H., Knoth, J., Michaelis, W., Proc. 4th Int. Conf. on Nuclear Methods in Environmental and Energy Research, April 14—17, 1980, Columbia, M0, USA, CONF-800433, p. 313.Google Scholar
7. Schwenke, H., Knoth, J., Nucl. Instr. and Meth., 193:239 (1982).Google Scholar
8.International patents held by GKSS Research Centre, Geesthacht.Google Scholar
9. Knoth, J., Schwenke, H., Fresenius Z. Anal. Chem., 294:273 (1979).Google Scholar
10. Knöchel, A., Prange, A., Fresenius Z. Anal. Chem., 306:252 (1981).Google Scholar
11. Prange, A., Dissertation, Universität Hamburg, 1983.Google Scholar
12. Prange, A., Knöchel, A., Michaelis, W., Anal. Chim. Acta (submitted for publication).Google Scholar
13.Rich. Seifert & Co., Röntgenwerk, D-2070 Ahrensburg: Extra II (under licence of GKSS Research Centre).Google Scholar
14. Michaelis, W., GKSS 83/E/39.Google Scholar
15. Michaelis, W., Proc. Int. Conf. on Heavy Metals in the Environment, September 6-9, 1983, Heidelberg, Germany, Vol. II, p. 972.Google Scholar
16. Anders, B., Junge, W., Knoth, J., Michaelis, W., Pepelnik, R., Schwenke, H., Proc. 5th Int. Conf. on Nuclear Methods in Environmental and Energy Research, April 2-6, 1984, Mayaguez, Puerto Rico.Google Scholar
17. Michaelis, W., Böddeker, H., Kramer, K., Niedergesäβ, R., Racky, R., Schnier, C., Weiler, K. in: Michaelis, W., Knauth, H.-D. (Eds.): Das Bilanzierungs experiment 1982 auf der Unterelbe - Experimentelle und theoretische Hilfsmittel, Ergebnisse und ihre Bewertung, GKSS (to be published).Google Scholar
18. Research, G.S. Centre, Gewässeranalytische Untersuchungen auf der Unterweser im Herbst 1979, Teil 2: Hochauflösende hydrographische Messungen und Spurenanalytik, GKSS 80/E/27.Google Scholar
19. Research, G.S. Centre, Schadstoffuntersuchungen an ausgewählten Standorten mit Muschelvorkommen im nordfriesischen Wattenmeer.Google Scholar
20. Schneider, B., Weiler, K., Environ. Techn. Lett. (submitted for publication).Google Scholar
21. Fanger, H.-U., Michaelis, W., Tagung der Arbeitsgemeinschaft der Groβ- forschungseinrichtungen (AGF) “Strahlung und Radionuklide in der Umwelt”, 8.-9. November 1984, Bonn - Bad Godesberg.Google Scholar
22. Freitag, K., Knoth, J., Schwenke, H., GKSS 79/E/9.Google Scholar
23. Bartels, B., Diplomarbelt, Universität Hamburg, 1981.Google Scholar
24. Bartels, B., Freitag, K., Rath, R., Forum Städte-Hygiene. 32:220(1981).Google Scholar
25. Ketelsen, P., Dissertation, Universität Hamburg, 1982.Google Scholar
26. Michaelis, W., Böddeker, H., Knoth, J., Schwenke, H., VIth World Congress on Air Quality, May 16-20, 1983, Paris, France, Vol. I, p. 391; GKSS 83/E/33.Google Scholar
27.AFR-Berichte, Elementanalyse von Schwebstäuben, KFK-AFR 006.Google Scholar
28. Ketelsen, P., Knöchel, A., Fresenius Z. Anal. Chem., 317:333 (1984).Google Scholar
29. Junge, W., Knoth, J., Rath, R., Neues Jahrbuch Miner. Abh., 147:169 (1983).Google Scholar
30. Heutschke, U., Junge, W., Rath, K. (to be published).Google Scholar
31. Knöchel, A., Makhraban, R., Prange, A., Marten, R., Michaelis, W., Knoth, J., Schneider, H., GKSS 84/E/32.Google Scholar
32. Knöchel, A., Prange, A., Microchlin. Acta (II):395 (1980).Google Scholar
33. Prange, A., Kremling, K., Marine Chemistry (submitted for publication).Google Scholar
34. Ahlf, W., Dissertation, Universität Hamburg, 1982.Google Scholar
35. Ahlf, W., Weber, A., Environ. Xechn. Techn. Lett., 2:317 (1981).Google Scholar
36. Schmidt, B., Dissertation, Universität Hamburg (to be published).Google Scholar
37. Knoth, J., Schwenke, H., Marten, R., Glauer, J., J. Clin. Chem. Clin. Biochem., 15:557 (1977).Google Scholar
38. Hein, B., Diplomarbeit, Universität Hamburg, 1981.Google Scholar
39. Schneider, K., Cammack, R., H.G. Schlegel, Eur. J. Biochem. (in press).Google Scholar
40. Michaelis, W., Prange, A., Knoth, J., Proc. Symp. on Instrumental Multi-Element Analysis, 2-5 April, 1984, Jülich, Germany; Verlag Chemie, Weinheim (in press).Google Scholar
41. Michaelis, W., Fanger, H.-U., Niedergesäβ, R., Schwenke, H., Proc. Syap. on Instrumental Multi-Element Analysis, 2-5 April, 1984, Jülich, Germany; Verlag Chemie, Weinheim (in press).Google Scholar
42. Nguyen, V.D. (private communication).Google Scholar