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Continuous Determination of Zinc Coating Weights on Steel by X-Ray Fluorescence

  • James A. Dunne (a1)

Abstract

The measurement of the area density of zinc coatings on steel by X-ray fluorescence is considered from an instalment design point of view. Each of the two general approaches, i.e., measurement of the attenuation of the iron emission line by the zinc coating and measurement of the sine emission line has limitations. Calculations indicate that contrast requirements are best satisfied by the iron attenuation technique in the coating weight interval 0.2-1.2 oz/ft2 per side. Experimental data collected on galvanised and zinc foil samples are presented in support of this contention. Conversely, advantages in the application of the zinc emission method to very thin zinc coatings are pointed out. Spectral resolution is discussed in terms of the ultimate precision and range of coating weight measurements. For the iron attenuation method, it is concluded that a black plate to infinite zinc intensity ratio of approximately 500 permits reasonably precise measurement of zinc foil coating weights in the vicinity of 1.2 oz/ft2 per side. This requirement can be met through the use of a LiF monochroraator crystal and 5 in. of effective 0.020-in. flat plate collimation.

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Continuous Determination of Zinc Coating Weights on Steel by X-Ray Fluorescence

  • James A. Dunne (a1)

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